Thermodynamics Flashcards

1
Q

What is the equation for the change in internal energy?

A

ΔE = q + w

Change in internal energy = heat + work

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2
Q

What is the PV work equation?

A

w = -PₑₓₜΔV

Work = external pressure * change in volume

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3
Q

What is the equation for Enthalpy?

A

ΔH = qₚ

Enthalpy = heat at constant pressure

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4
Q

What does ΔH > 0 mean?

A

The reaction is Endothermic, sucking up heat.

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5
Q

What does ΔH < 0 mean?

A

The reaction is Exothermic, giving off heat.

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6
Q

What is the ΔH when 2H₂(g) + O₂(g) → 2H₂O(ℓ)

A

ΔHᵣₓₙ = -572KJ

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7
Q

What is the phase change from Solids to Liquids called? Endothermic or Exothermic?

A

Melting/Fusion

ΔH > 0, Endothermic

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8
Q

What is the phase change from Liquids to Gases called? Endothermic or Exothermic?

A

Boiling/Vaporization

ΔH > 0, Endothermic

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9
Q

What is the phase change from Solids to Gases called? Endothermic or Exothermic?

A

Sublimation

ΔH > 0, Endothermic

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10
Q

What is the phase change from Gases to Liquids called? Endothermic or Exothermic?

A

Condensation

ΔH < 0, Exothermic

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11
Q

What is the phase change from Liquids to Solids called? Endothermic or Exothermic?

A

Freezing/Crystallization

ΔH < 0, Exothermic

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12
Q

What is the phase change from Gases to Solids called? Endothermic or Exothermic?

A

Deposition/Vapor Deposition

ΔH < 0, Exothermic

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