Thermodynamics Flashcards
What is the equation for the change in internal energy?
ΔE = q + w
Change in internal energy = heat + work
What is the PV work equation?
w = -PₑₓₜΔV
Work = external pressure * change in volume
What is the equation for Enthalpy?
ΔH = qₚ
Enthalpy = heat at constant pressure
What does ΔH > 0 mean?
The reaction is Endothermic, sucking up heat.
What does ΔH < 0 mean?
The reaction is Exothermic, giving off heat.
What is the ΔH when 2H₂(g) + O₂(g) → 2H₂O(ℓ)
ΔHᵣₓₙ = -572KJ
What is the phase change from Solids to Liquids called? Endothermic or Exothermic?
Melting/Fusion
ΔH > 0, Endothermic
What is the phase change from Liquids to Gases called? Endothermic or Exothermic?
Boiling/Vaporization
ΔH > 0, Endothermic
What is the phase change from Solids to Gases called? Endothermic or Exothermic?
Sublimation
ΔH > 0, Endothermic
What is the phase change from Gases to Liquids called? Endothermic or Exothermic?
Condensation
ΔH < 0, Exothermic
What is the phase change from Liquids to Solids called? Endothermic or Exothermic?
Freezing/Crystallization
ΔH < 0, Exothermic
What is the phase change from Gases to Solids called? Endothermic or Exothermic?
Deposition/Vapor Deposition
ΔH < 0, Exothermic