Thermodynamics Flashcards

1
Q

Engineering materials

intensive properties and extensive properties

A

are defined as substances which are manufactured and used for various
engineering applications.

these are properties independent to mass of system Ex temp, pressure
(its same at all points of the system)

these are properties dependent on mass
ex. volume, mass
(its the sum of all the values of the property at different point)

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2
Q

what is isothermal, isobaric,
isochoric,
isentropic

A

temp remains constant

pressure remains constant

Volume remains constant

entropy remains constant

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3
Q

Quasi-static or Quasi

and what is a process

A

Equilibrium process during which the course of deviation from thermodynamic equilibrium is negligibly small

when a system undergoes a change of state, it is said to have undergone a process, the values of properties change

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4
Q

what is temperature

equality of temperature

what is thermodynamic equilibrium

A

its the measure of hotness or coldness

two systems or a system and its surroundings are said to have equality if there is no change in observable property when they are bought in thermal contact

when no change in macroscopic property is observed after it is isolated from its surroundings

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5
Q

Zeroth law of thermodynamics

First law of thermodynamics for cyclic process

A

when system A and B are independently in thermal equilibrium with a third system say C, then they are in thermal equilibrium with each other

when a system undergoes a cyclic process, the algebraic sum or cyclic integral, of heat transfers is proportional to, the algebraic sum (or cyclic integral), of work transfers

The first law of thermodynamics states that energy can neither be created nor destroyed, only altered in form
(conservation of energy)

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6
Q

what are the three types of temperature measurement

what is reference system and property

what is thermometric property

A

Reference System and property, Reference points
Formation of Temperature Scales

REFERENCE SYSTEM
referred to as the thermometer and possesses a property that is measurable and changes with temp
THERMOMETRIC PROPERTY
the property that changes with temp increase

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7
Q

what are Reference points

why was two fixed points abandoned

A

they are distinct points and reproducible states at any places on the earth

ex ice melting
steam point etc

2 POINTS ABANDONED:

extreme sensitiveness to change in pressure for steam point

difficulty of achieving equilibrium between pure ice and air saturated water, as ice melts

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8
Q

when is work positive and negative

and

when is heat in a system positive and negative

A

when work is done by the system (+)
when work is done on the system (-)

heat added to a system (+)
heat removed from the system (-)

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9
Q

what is transient phenomena,

Boundary phenomena,

which are path functions

does system possess heat or work or only possesses energy

A

heat and work are observed only there is transfer of energy and hence are transient in nature

heat and work are observed at the system boundary, change of boundary and the form of energy transfers may change from heat or work vice versa

both heat and work are path functions and hence are inexact differentials

it only possesses energy

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10
Q

what two things are not addressed by the first law

what do you mean heat is qualitatively lower than work done

A

process follow a definite direction

heat and work are qualitatively different

all work can be dissipated as heat while heat cannot be converted into work done by any device in a working thermodynamic cycle

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11
Q

heat reservoir
,heat source, heat sink

A

a body of infinite heat capacity, whose temp is not affected by any heat transfer. a body of infinite heat capacity, which can absorb or supply heat without any change in its temperature.

HEAT RESERVOIR and HEAT SINK

is a heat reservoir which can supply heat without any change in its temperature.

is a heat reservoir which can absorb heat without any change in temperature.

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12
Q

what is heat engine

what is reversed heat engine

A

is a device that works in a thermodynamic cycle and produces net positive work while absorbing heat from a source and dissipating heat to a sink.

formula W=Qh-Ql

REVERSED HEAT ENGINE

is a device that operates in a thermodynamic cycle and transfers heat from a low temperature body (sink) to a high temperature body (source) with the aid of external work.
W=Qh-Ql

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13
Q

Clausius Statement

A

It is impossible to construct a device that operates in a thermodynamic cycle and transfers heat from a cold body to a hot body without the input of external energy.

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14
Q

principles of refrigeration

A

The process of cooling or reducing the temperature of a substance below that of the
surrounding atmosphere and maintaining this lower temperature within the boundary of a
given space is called refrigeration.

In order to keep the substance cold, heat must be continuously removed from the given
substance.

According to the law of thermodynamics, heat naturally flows from a hot substance to a cold
substance. But if heat has to flow from a cold substance to a hot substance, some form of work
has to be performed

Refrigeration works on the principle that heat is continuously extracted from the
low temperature substance by performing mechanical work. This heat is then
rejected to the surrounding atmosphere (high temperature level)

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15
Q

mechanical energy definition and shaft, motor formula

A

The mechanical energy is defined as the form of energy that can be converted
to mechanical work completely and directly by an ideal mechanical device such
as an ideal turbine.

npump=mech power increase/mech power OUT

nturbine=mech power OUT/mech power decrease

Nmotor:mech OUT /electric IN
NGenerator: electric power OUT/mechanical power IN

Nturbine=Pshaft/Phydralic(mgh of water flow)

Pshaft=Pelectric/Ngenerator

Npump-motor:
NpumpNmotor/Nmotor
Nturbine-gen:
NturbineNgen/Ngen

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16
Q

what is an engine

two types of engines

classifications of engines (7)

IC engines can be classified into 3 types:

A

An engine is a device which transforms one form of energy into another form.

external(combustion takes place outside the engine.)

internal( combustion takes place within the engine.)
CLASSIFICATION
Number of strokes per cycle
Nature of thermodynamic cycle
Ignition systems
Fuel used
Arrangement of
cylinders
Cooling systems
Fuel supply systems

Otto cycle, Diesel cycle, and Dual cycle engines.

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17
Q

HEAT ENGINE

A

Heat engine is a device which transforms the chemical energy of a fuel
into thermal energy and utilizes this thermal energy to perform useful work. Thus, thermal
energy is converted to mechanical energy in a heat engine

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18
Q

ignition type and its properties

fuel supply system types:

A

spark ignition :

sparking starts at the end of compression stroke from spark plug

compression ignition:
the temperature of the fuel is increased to the self-ignition point by
compressing the air alone and at the end of compression, fuel is injected into the cylinder.

FUEL SUPPLY
Carburetor engine (mix of air and fuel injection)

Air injection engine, and

Airless or solid or Mechanical injection engines. (use a mechanical pump to deliver fuel into the combustion chamber of an engine.)

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19
Q

define cylinder and piston

A

It is a hollow cylindrical structure closed at one end
with the cylinder head

The combustion of the fuel takes place inside the
cylinder.

PISTOM
It is a cylindrical component fitted perfectly inside the
cylinder providing vacuum seal

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20
Q

what is a piston, and how is the piston connected to the connecting rod, and name all the pistion rings

what is connecting rod

A

It is a cylindrical component fitted perfectly inside the
cylinder providing vacuum seal and
connected by the:
the gudgeon pin

ALL rings

compression ring
(upper ring), (compress the air or airfuel mixture )

oil rings (lower rings)
( collect the surplus
lubricating oil on the liner surface.)

to transfer the reciprocating
motion of the piston into rotary motion of the crankshaft.
It connects the piston and the crankshaft

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21
Q

what is crankshaft
in four strokes how many times does the crankshaft rotate

Crankcase

A

It is principal rotating part of the engine which controls the
sequence of reciprocating motion of the pistons.

four strokes
of the piston or two revolutions of the crankshaft.

CRANKCASE
The bottom portion of the cylinder block is called crankcase. A cover
called crankcase which becomes a sump for lubricating oil is fastened
to the bottom of the cylinder block.

22
Q

Flywheel

A

heavy wheel mounted on the crankshaft to minimize the cyclic
variations in speed. It absorbs the energy during the power stroke and
releases it during the non-power stroke.

23
Q

Displacement or Swept Volume (Vs) meaning and formula

Compression Ratio (r)

Clearance Volume (Vc):

A

The nominal volume swept
by the working piston when travelling from one dead centre to the
other is called the (cc).

Vs = A*L = pi/4 d^2L
COMPRESSION RATIO
:It is the ratio of the total cylinder volume
when the piston is at the bottom dead centre, Vt , to the clearance
volume, Vc.

Vt/Vc = Vc+Vs/Vc = 1 + Vs/Vc

The nominal volume of the combustion
chamber above the piston when it is at the top dead centre is the
clearance volume

24
Q

PETROL CYCLE

A

SUCTION
starts when the piston is at the TDC
and about to move downwards. 0→1

The inlet valve is open exhaust valve is
closed
suction created by the motion of the piston towards the
BDC, the charge of fuel-air mixture is
drawn into the cylinder.

BDC the suction stroke
ends and the inlet valve closes instantaneously.

COMPRESSION
The charge taken into the cylinder during the suction stroke is
compressed by the return stroke of the piston 1→2.

both inlet and exhaust valves are closed

The mixture is now compressed the clearance volume.

end of the compression stroke the mixture is ignited with the
spark plug on the cylinder head.

EXPANSION/ POWER STROKE

high pressure of the burnt gases forces the piston towards the
BDC, (stroke 3→4).

Both the valves are in closed position.

power is produced. Both pressure and temperature decrease during expansion.
EXHAUST STROKE

At the end of the expansion stroke the exhaust valve opens instantaneously and the inlet valve remains closed.

The pressure falls to atmospheric level a part of the burnt gases
escape.

The piston starts moving from the bottom dead centre to top dead
centre (stroke 5→0) and sweeps the burnt gases out from the
cylinder almost at atmospheric pressure.
The exhaust valve closes when the piston reaches TDC.

EXHAUST STROKE

end of the expansion stroke ,exhaust valve opens and the inlet valve remains closed.

The pressure falls to atmospheric level a part of the burnt gases
escape.

The piston starts moving from the BDC to TDC (stroke 5→0) and sweeps the burnt gases out from the cylinder almost at atmospheric pressure.
The exhaust valve closes when the piston reaches TDC.

25
Diesel Engine cycle
COMPRESSION during suction stroke, air, instead of a fuel-air mixture higher compression ratios employed, the temp at the end of the compression stroke is sufficiently high to self ignite the fuel which is injected into the combustion chamber. In CI engines, a high pressure fuel pump and an injector are provided to inject the fuel into the combustion chamber. SUCTION STROKE Air alone is inducted Air is compressed into the clearance volume. Both valves remain closed EXPANSION Fuel injection starts nearly at the end of the compression stroke. The rate of injection is such that combustion maintains the pressure constant in spite of the piston movement on its expansion stroke increasing the volume Heat is assumed to have been added at constant pressure. After the injection of fuel is completed (i.e. after cut-off) the products of combustion expand. Both the valves remain closed during the expansion stroke. EXHAUST The piston travelling from BDC to TDC pushes out the products of combustion. The exhaust valve is open and the intake valve is closed during this stroke
26
what is indicated power and brake power how is brake power identified and formula torque formula
IP: The power developed inside the cylinder of the engine BP: It is the net power available at the crank shaft of the engine for performing useful work (BP). It is always less than indicated power since a part of the power developed in the engine cylinder is used to overcome the frictional losses at different moving parts of the engine. The arrangement is known as dynamometer. Usually, rope brake dynamometer a device designed to assess the power of an engine shaft by introducing frictional resistance to the shaft's motion through the use of a rope 2𝜋𝑁𝑇/60×1000 (kW) N=Crank Speed, TORQUE = 𝑇 = (𝑊 − 𝑆) ×(𝐷𝑏+𝑑𝑟)/2 W= weight, S=spring balance Db=diameter of brake drum, dr=diameter of rope
26
formula frictional power Mechanical efficiency indicated thermal efficiency and brake thermal efficiency two specific fuel consumption defintion ways (ISFC), (BSFC)
FP = IP – BP mech = BP/IP Nith = 𝐼𝑃/(𝐶𝑉 × 𝑚f) Nbp = 𝐵𝑃/(𝐶𝑉 × 𝑚𝑓)× 100 CV is the calorific value of the fuel in KJ/kg mf is mass flow rate of the fuel in kg/s. units are in kW Specific fuel consumption ISFC =𝑴𝒂𝒔𝒔 𝒐𝒇 𝒇𝒖𝒆𝒍 𝒄𝒐𝒏𝒔𝒖𝒎𝒆𝒅 𝒊𝒏 (𝒌𝒈/𝒉𝒓)/𝑰𝒏𝒅𝒊𝒄𝒂𝒕𝒆𝒅 𝑷𝒐𝒘𝒆𝒓 𝒊𝒏 𝒌𝑾 BSFC = 𝑴𝒂𝒔𝒔 𝒐𝒇 𝒇𝒖𝒆𝒍 𝒄𝒐𝒏𝒔𝒖𝒎𝒆𝒅 𝒊𝒏 (𝒌𝒈/𝒉𝒓) /𝑩𝒓𝒂𝒌𝒆 𝑷𝒐𝒘𝒆𝒓 𝒊𝒏 𝒌W both mf should be divided by 3600 as it should be per second Specific fuel consumption – It is the mass of fuel consumed per kW of power developed per hour and is a criterion of economical power production Mf= fuel flow(L)*1000*specific gravity fuel flow in default will be in m^3 and should be per/sec Kg/s => L/s divide mf/specific gravity litres should be converted m^3 divided 1000
26
comparsion of diesel and petrol engine evaluating the performance of an engine three factors , and 3 ways to determine them
petrol are lighter engines than diesel, and the are higher speed(rpms) than diesel, diesel has higher compression ratios thus greater thermal efficiency PERFORMANCE OF ENGINE diesel engines are heavier due to higher peak pressures compared to petrol engines Maximum power or torque Specific fuel consumption Reliability and durability By using experimental results obtained from engine tests. By analytical calculation based on theoretical data By doing numerical caluculation using theoretical data
27
MOTOR battery and list the three types of them what is a controller in ev DC/DC converter auxiliary battery Energy Management System
MOTOR high torque electric motor. While braking, it acts like a generator (regenerative braking) and recharges the batteries. BATTERY TYPES Those are lead acid batteries, nickel metal hydride (NiMH) batteries and lithium ion (Li – ion) batteries. CONTROLLER a computerized motor controller. regulates the flow of energy from the power pack to the motor in relation to the pressure applied on the accelerator DC/DC CONVERTER A 12V auxiliary battery in an electric car to power all 12V accessories such as lights, horn etc. by cutting battery pack voltage down to 12V EMS The brain of EVs that monitors and controls all required functions. It is a computer based system that optimizes charging and energy output of batteries to maximize operating range and improve performance.
28
Hybrid Electric Vehicle (HEV) i) Series Architecture
In case of series hybrid system, the mechanical output(IC engine) is first converted into electricity using a generator. The converted electricity either charges the battery or can bypass the battery to propel the wheels via the motor and mechanical transmission.
29
Hybrid Electric Vehicle (HEV) i) Parallel Architecture
The parallel HEV allows both IC engine and electric motor to deliver power to drive the wheels since both IC engine and electic motor aee connected to the shaft via two clutches, the propulsion power may be delivered by IC engine alone, by electric motor alons, or both IC engine and electric motor. The electric motor can be used as a generator by absorbing the battery by regenerative braking or by absorbing power from the IC engine when its output is greater than required for the output for the wheels
30
Hybrid Electric Vehicle (HEV) – Architectures iii) Series - Parallel Architecture what is the advantage of Series - Parallel Architecture
In the series-parallel hybrid, the configuration incorporates the features of both the series and parallel HEVs. However, this configuration needs an additional electric machine and a planetary gear unit making the control complex. ADV:This setup takes advantage of the strengths of both configurations to maximize efficiency, flexibility, and performance under different driving conditions. City driving (low speeds): At low speeds or in stop-and-go traffic, a series hybrid mode is more efficient. At higher speeds, the parallel hybrid mode is more efficient.
31
HYBRID ELECTRIC VEHICLES (HEV) difference between series and parallel hybrid
They have two complementary drive systems: an IC engine with a fuel tank and an electric motor with a battery. HEVs cannot be recharged from the electricity grid – all their energy comes from fuel and from regenerative braking. difference between series and parallel hybrid: parallel mode is used when both the electric motor and internal combustion engine (ICE) can provide power simultaneously, while series mode is used when the electric motor is the only source of mechanical power
32
metal alloys, Steel as an example and alloy steel
ferrous and nonferrous Ferrous alloys, those in which iron is the principal constituent, include steels and cast irons ex: STEEL iron-carbon(less than 2 percent) The nonferrous ones—all alloys that are not iron based. alloy steel Steels which acquire some characteristic properties due to the addition of alloying elements other than Carbon; for specific properties
33
low, medium, high carbon steels
0.25% Carbon Relatively soft and weak Outstanding Ductility and Toughness Very good Machinability and Weldability eg. Mild Steel Least expensive to produce Unresponsive to hardening heat treatment Very low hardenability Automobile body components Structural shapes (I beams, Angle Irons); Sheets used in tin cans, buildings etc. medium carbon steel 0.25% to 0.6 carbon Stronger than Low Carbon Steels Less tougher Best range for adding alloying elements Good mix of ductility and strength Railway wheels and tracks Gears Crankshafts and other machine parts High carbon steels From 0.6% to 1.4% carbon Hardest Strongest Least ductile when compared with Low Carbon and Medium Carbon Steel Best range to make tool steels Cannot be used for operations where ductility and malleability are required Knives ; Razors ; Hacksaw blades ; High strength Wires
34
CAST IRONS, CAST IRONS types distinct limitations, chiefly
alloys having carbon content above 2.1% by weight, most cast irons contain carbon between 3 – 4.5% by weight and in addition Cast Irons are also very brittle. Therefore, casting is the most convenient fabrication technique. 1) Gray Cast Iron 2) Nodular or Ductile Cast Iron 3) White Cast Iron 4) Malleable Cast Iron DIS ADVANTAGES a relatively high density, a comparatively low electrical conductivity, and an inherent susceptibility to corrosion in some common environments.
35
GRAY CAST IRON DUCTILE OR NODULAR CAST IRON white cast iron MALLEABLE CAST IRON
2.5% to 4% Carbon 1% to 3% Silicon Weak and brittle in tension Higher Compressive strength effective in damping vibrations High resistance to wear High fluidity at molten state (This permits casting pieces to have intricate shapes) Low Cost Automotive Engine Blocks Brake discs and drums Base structure of machines and heavy equipments that are exposed to vibrations etc. DUCTILE OR NODULAR CAST IRON 3% to 4% Carbon 1.6% to 2.8% Silicon Highly ductile Very good machinability High Corrosion Resistance Valves Pump bodies Crankshafts Gears and other automotive and machine components etc WHITE CAST IRON 1.8% to 3.2% Carbon 0.3% to 1.8% Silicon Very hard and brittle Highly wear resistant No Ductility and Malleability Not Machinable Liners for Cement Mixers Ball Mill Certain types of Drawing Dies Extrusion Nozzles etc. 1.8% to 3.2% Carbon 0.3% to 1.8% Silicon MALLEABLE CAST IRON Highly Malleable Very good Machinability Good Magnetic properties Wear Resistance Connecting Rods Transmission Gears Flanges Pipe Fittings Differential Cases for Automobiles etc.
36
copper ALUMINIUM MAGNESIUM TITANIUM AND ITS ALLOYS
Copper has - good thermal and electrical conductivity ease of getting cast, machined and brazed - good corrosion resistance Pure copper is mainly used for electrical and thermal applications. ALUMNIUM Low specific gravity, Corrosion resistance , Ease of fabrication, High electrical and thermal conductivity, Aircraft structural parts and other highly stressed applications, Flywheel etc. MAGNESIUM ALLOYS for light weight alloys is relatively soft, and has a low elastic modulus APPLICATIONS: variety of hand-held devices (e.g., chain saws, power tools, hedge clippers), TITANIUM has a relatively low density a high melting point and an high elastic modulus TITANIUM extremely strong; tensile strengths are high the alloys are highly ductile and easily forged and machined. -airplane structures, space vehicles, surgical implants, ,petroleum and chemical industries.
37
CERAMICS
metallic and non – metallic elements with predominantly ‘ionic’ interatomic bonding. turbocharger rotors, aerospace turbine blades, nuclear fuel rods,
38
PLASTICS thermosetting, and thermoplastic thermoplastic vs thermosetting
Plastics are synthetic materials processed by heat and pressure. a solid material consisting of an organic polymer of a long molecular chain and high molecular weight THERMOPLASTIC a polymeric material which softens when heated and hardens upon cooling. THERMOSETTING: a polymeric material, which once having cured or hardened by a chemical reaction does not soften or melt upon subsequent heating. A thermoplastic material has a linear polymer chain while a thermosetting plastic material consists of a cross – linked polymer chain as shown. THERMOSETTING VS THERMOPLASTIC The difference in properties of thermoplastic and thermosetting plastic materials is due to molecular structures of their polymer chains.
39
what are composites
A composite is a structural material that consists of two or more combined constituents that are combined at a macroscopic level and are not soluble in each other. One constituent is called the reinforcing phase and the one in which it is embedded is called the matrix. The reinforcing phase material may be in the form of fibers, particles, or flakes. The matrix phase materials are generally continuous. Examples of composite systems include concrete reinforced with steel and epoxy reinforced with graphite fibers, etc
40
elasticity, plasticity, ductility, Malleability brittleness, fatigue creep hardness, Impact strenght static and cyclic load RESELIENCE TOUGHNESS STIFNESS
the ability of the material to regain its shape and size when the externa forces are removed/when deformation occurs PLASTICITY ability of material to not to take its shape and size when the external forces are removed DUCTILITY ability of the material to be drawn into thin wires when the materials are subjected to tensile MALLEABILITY ability of material to deform into sheets under compression load BRITTLENESS ability of material (% elongation is less than 5%) than its brittle material % elongation (change in L/l)*100 FATIGUE ability of the material to resist deformation due to cyclic loading CREEP it is the function of time and temperature elongated wrt to time changing shape over time HARDNESS ability of the material to resist surface indentation/resistance to penetration = hardness BHN= brinal hardness number VHN=Vekers hardness number RHN=Rockwells Hardness number IMPACT STRENGHT ability of a material to resist the deformation due to sudden load (high magnitude in fraction of time) charpy test rig static: magnitude of load doesnt vary with time, cyclic load varies RESILIENCE V TOUGHNESS (i) Resilience is the ability of the material to absorb energy within elastic limit and release it, whereas toughness is the ability of the material to absorb energy within elastic and plastic range, before fracture. Resilience is essential in spring applications where toughness is required for components subjected to bending, twisting, stretching and impact loads. STIFNESS the resistance of materials to elastic deformation or deflection its called rigidity, how much a material resists deformation in response to an applied force. A material with high stiffness will undergo only slight deformation under load
41
what are smart materials, Key elements of smart system/structure
Smart materials are materials that have to respond to stimuli and environmental changes and to activate their functions according to these changes ELEMENTS OF SMART MATERIALS: Smart materials are thought of as those which produce electric voltages when strained ex: Lead Zirconate Titanate, polyvinylidene fluoride Sensor Actuator Control System Power and Signal Conditioning Electronics Computer
42
PIEZOELECTRIC MATERIALS
By applying mechanical deformations to these crystals, electric dipoles are generated/pd develops vice versa in certain class of anisotropic Voltage and power sources, sensors
43
SHAPE MEMORY ALLOYS one way and 2 way and examples
The recovery of strains imparted to the material at a lower temperature, as a result of heating, alloys shape is fixed/memorised at low temp ex: braces, stents One way: after heating deformation are recovered and cooling = back to same shape two way: remembers shape at both high temp and low temp ,thus can be cycled btw these 2 shapes without the need of external stress
44
RHEOLOGICAL FLUIDS MAGNETOSTRICTIVE MATERIAL ISA(2M)
A special class of fluids exists that change their rheological properties on the application of an electric or a magnetic field. MAGNETOSTRICTIVE materials that change their shape or dimensions in response to an applied magnetic field
45
stress/strain types in normal stress list the 2 types
normal stress (perpendicular): tensile,compression , sheer load(parallel)
46
ISA/ESA 2M plot the graph for mild steel
47
STRESS- STRAIN DIAGRAM IN COMPRESSION
When the material is compressed, it bulges outward on the sides and becomes barrel shaped, because friction between the specimen and the end plates prevents lateral expansion. With increasing load, the specimen is flattened out and offers greatly increased resistance to further shortening Brittle materials loaded in compression typically have an initial linear region the ultimate stresses in compression are much higher than those in tension. brittle materials actually break at the maximum load unlike ductile draw graph
48
all the P and V relation and pdV relation
ISOTHERMAL PV=const, P1V1=P2V2 pdV W=P1V1ln(V2/V1) ADIABATIC PV^a=const, P1V1^a=P2V2^a pdV W=(P1V1-P2V2)/a-1 POLYTROPIC PV^n=const, P1V1^n=P2V2^n pdV W=(P1V1-P2V2)/n-1 ISOCHORIC V=const, dV=0, P1/P2 =T1/T2(Kelvin) pdV W=0 ISOBARIC P=const, dP=0, V1/T1=V2/T2 W=P(V2-V1)