thermodynamics Flashcards

1
Q

specific heat capacity (c)

A

energy required to increase the temperature of 1kg of a substance by 1k without it changing state

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2
Q

amount of energy required to change the temperature of a metal

A

∆E=mc∆θ

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3
Q

specific latent heat (L)

A

amount if energy required to change the state of 1kg of a substance without it changing temperature

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4
Q

amount of energy required to change the state of a material

A

∆E=∆mL

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5
Q

types of later heat

A

fusion=solid to liquid
vaporisation=liquid to gas

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6
Q

internal energy

A

equal to the sum of all the kinetic energies and potential energies of all its particles. these energies are randomly distributed.
when the state of a substance is changed, its internal energy also changes, this is because the potential energy of the system changes, while the kinetic energy of the system is kept constant

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7
Q

absolute 0

A

-273° or 0k, where particles have no kinetic energy and the volume and pressure of gas is 0

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8
Q

kinetic theory model

A

relates several features of a fixed mass of gas, including its pressure, volume and mean kinetic energy.

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9
Q

kinetic theory assumptions

A

-no intermolecular forces act on the particles
-all molecules are the same
-the time taken for a collision is negligible in comparison to the time between collisions
-the motion of molecules are random
-all collisions are elastic
-particles travel in straight lines

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10
Q
A
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11
Q

ideal gases

A

no interaction other than perfectly elastic collisions between the gas molecules, which shows there are ni intermolecular forces. potential energy is therefore zero as it is related to the intermolecular forces and so the international energy is equal to the sum of kinetic energies of all its particles

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12
Q

derivation

A

do it rn

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13
Q

average kinetic energy of molecules

A

do the derivation rn

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14
Q

black body radiators

A

a perfect emitter and absorber of all EM radiation wavelengths

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15
Q

radiation curves

A

graphs of intensity against wavelength of radiation emitted by objects at different temperatures

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16
Q

stephan-boltzmann law

A

power of blackbody radiator is directly proportional to its surface are and absolute temperature^4

17
Q

wiens law

A

peak wavelength of emitted radiation is inversely proportional to the absolute temperature of the object.
shows that peak wavelength decreases as temperature increases, meaning the frequency increases so the energy of the wave increases

18
Q

0.5xmx<c^2>

A

mean kinetic energy of a gas particle

19
Q

3/2xNxKxT

A

internal energy of the gas, equal to the total kinetic energy of all the particles

20
Q

decrease in volume with constant temp effect on pressure

A

decrease in volume causes an increase in collisions with the wall. as temp is constant the root mean square does not change. there is an increase in rate of change of momentum as t is smaller and so F is bigger. therefore pressure increases.

21
Q

Boyles law

A

pressure is inversely proportional to volume

22
Q

Charles law

A

volume and temperature are proportional

23
Q

pressure law

A

pressure is proportional to temperature

24
Q

if there is a change in temperature and the original pressure is given in a fixed volume, what equation should be used

A

p1/T1=p2/T2. this is because NK/V is a constant