Thermodynamics Flashcards
what is enthalpy change?
the heat energy transferred in a reaction at constant pressure
what are the standard conditions?
100 kPa
298 K
do exothermic reactions have a negative or positive enthalpy change value?
negative
heat energy is given out
do endothermic reactions have a negative or positive enthalpy change value?
positive
heat energy is absorbed
what is lattice formation enthalpy?
the enthalpy change when 1 mole of a solid ionic compound is formed from its gaseous ions
what is lattice dissociation enthalpy?
the enthalpy change when 1 mole of a solid ionic compound is completely dissociated into its gaseous ions
what is enthalpy change of formation?
the enthalpy change when 1 mole of a compound is formed from its elements in their standard states
what is bond dissociation enthalpy?
the enthalpy change when all the bonds of the same type in 1 mole of gaseous molecules are broken
what is enthalpy change of atomisation of an element?
the enthalpy change when 1 mole of gaseous atoms is formed from an element in its standard state
what is enthalpy change of atomisation of a compound?
the enthalpy change when 1 mole of a compound in its standard state is converted to gaseous atoms
what is the first ionisation energy?
the enthalpy change when 1 mole of gaseous 1+ ions is formed from 1 mole of gaseous atoms
what is the second ionisation energy?
the enthalpy change when 1 mole of gaseous of 2+ ions is formed from 1 mole of gaseous 1+ ions
what is first electron affinity?
the enthalpy change when 1 mole of gaseous 1- ions is made from 1 mole of gaseous atoms
what is second electron affinity?
the enthalpy change when 1 mole of gaseous 2- ions is made from 1 mole of gaseous 1- ions
what is enthalpy change of hydration?
the enthalpy change when 1 mole of aqueous ions is formed from gaseous ions