Thermodynamics Flashcards

Thermodynamics

1
Q

Reversible process entropy

A

Entropy remains constant

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2
Q

Irreversible process entropy

A

Entropy of system increases

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3
Q

Boltzman constant same unit as

A

Entropy and boltzman constant equal to R/Na

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4
Q

Triple point of water

A

273.16K

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5
Q

Net entropy is

A

Always positive

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6
Q

Efficiency of carnot engine depends on

A

Temperature of hot and cold reservoirs and is independent of nature of working substance

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7
Q

Efficiency always less than one

A

Cuz absolute temperature not attainanble and no engine is more efficient than carnot engine

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8
Q

Refrigerator is

A

A heat engine operating in reverse order it transfers heat from low temperature compartment to high temperature surroundings with help of external work

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9
Q

The reason for inability to use heat reservoir of oceans and atmosphere

A

There is no reservoir at a temperature lower than any of two

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10
Q

Evaporation and liquefaction perdormed slowly are

A

Practically reversible and isothermal

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11
Q

Changes involving friction and dissipation of energy through convection conduction and radiation are

A

Irreversible

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12
Q

Molar specific heat at constant pressure is ______ than at constant volume

A

More

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13
Q

Adiabat ______ isotherm

A

Lower

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14
Q

At constant pressure

A

Isobaric process

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15
Q

At constant volume

A

Isochoric process

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16
Q

Slow process like evaporation and liquefaction

A

Isothermal

17
Q

Cloud formation

A

Adiabatic process

18
Q

For ideal gas potential energy is

A

Zero thus internal energy only depends on temperature

19
Q

Heat added is

20
Q

Heat lost is

21
Q

Work done by the system is

22
Q

Work done on the system is

23
Q

Both heat and work correspond to

A

Transfer of energy

24
Q

For monoatomic gas the potential energy

25
For diatomic gas
Translational, vibrational and rotational kinetic energy
26
Thermal equilibrium
Same temperature
27
Internal energy can be changed by
Adding heat and doing work on substance
28
Energy in transit
Heat
29
In cyclic process
All heat energy is used to do useful work as there is no change in internal energy