thermodynamic systems Flashcards
what are the type of systems
isolated - no exchange of energy or mass
closed - exchange of energy but no exchange of mass
open - exchange of energy and mass
what are the types of closed systems
isobaric: constant pressure
isothermal: constant temp
isochoric: constant volume
Adiabatic: no heat flows between the system and surroundings
what is the first law of thermodynamics
the internal energy of an isolated system is constant
for first law of thermodynamics where only heat flow and only work occurs what is deltaU equal to
what is deltaIU equal to when both work is done and head flow occurs
only heat flow: combined energy of system and surroundings must be constant, deltaU = q
only work: deltaU= w
DeltaU= q + w
what is the difference between reversible and non-reversible process
Direction of reversible can be changed by making small changes to a variable while for non-reversible a large change is required
what is a state function
a property of system depending on the systems state not on how it got there
what is a path function
a parameter that depends on the way a system changed from one state to another, when talking about changes of path function use dbar