thermodynamic systems Flashcards

1
Q

what are the type of systems

A

isolated - no exchange of energy or mass
closed - exchange of energy but no exchange of mass
open - exchange of energy and mass

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2
Q

what are the types of closed systems

A

isobaric: constant pressure
isothermal: constant temp
isochoric: constant volume

Adiabatic: no heat flows between the system and surroundings

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3
Q

what is the first law of thermodynamics

A

the internal energy of an isolated system is constant

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4
Q

for first law of thermodynamics where only heat flow and only work occurs what is deltaU equal to
what is deltaIU equal to when both work is done and head flow occurs

A

only heat flow: combined energy of system and surroundings must be constant, deltaU = q

only work: deltaU= w

DeltaU= q + w

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5
Q

what is the difference between reversible and non-reversible process

A

Direction of reversible can be changed by making small changes to a variable while for non-reversible a large change is required

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6
Q

what is a state function

A

a property of system depending on the systems state not on how it got there

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7
Q

what is a path function

A

a parameter that depends on the way a system changed from one state to another, when talking about changes of path function use dbar

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