Thermochemistry Flashcards

1
Q

What is thermodynamics?

A

Study of heat due to force or force due to heat

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2
Q

What is energy?

A

Ability to do work or transfer heat

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3
Q

What is thermochemistry?

A

Study of energy and heat associated with chemical reactions and of physical transformations

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4
Q

What is heat?

A

Energy used to cause increase in temperature

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5
Q

What is work?

A

Energy used to cause one object that has mass to move.

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6
Q

What is the equation for work?

A

Work = force * distance

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7
Q

What is a system?
What is a surrounding?

A

Part of universe which undergoes thermodynamic study.
Everything else

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8
Q

What is an open, isolated, and closed system?

A

Open- matter and energy can be exchanged to surrounding
Isolated- Neither matter nor heat can be exchanged with surrounding
Closed- Exchange energy not matter with surrounding

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9
Q

What is internal energy? What is the equation?

A

Sum of a system, is sum of all kinetic and potential energies within system
E.E. = Efinal-Einitial

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10
Q

What is enthalpy change?

A

Difference in energy between the reactants and products is the amount of heat energy transferred to surroundings.

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11
Q

What is enthalpy?

A

Heat content of a substance at a constant temperature

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12
Q

What is the equation for enthalpy?

A

H = internal energy + (pressure)(volume)

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13
Q

What is Heat Capacity?

A

Amount of heat it takes to raise something by 1 degrees celsius

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14
Q

What is specific heat capacity?

A

Amount of heat it takes to raise 1 gram of a substance by 1 degrees Celsius

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15
Q

What is the calculation for heat gained?

A

q or h = (Mass)(Specific Heat Capacity)(Change in temperature)

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16
Q

What is the equation for the change in temperature?

A

Change in Temperature = Final Temp - Initial Temp

17
Q

What is a catalyst?

A

Substance that causes reaction to go faster by reducing activation energy but without being consumed.

18
Q

What is the equation for heat enthalpy change?

A

Heat enthalpy change = (-mass)(specific heat capacity)(change in temperature)

19
Q

How do you calculate total mass?

A

Total volume * Density

20
Q

What are the energy laws?

A
  1. Energy is neither created nor destroyed
  2. Entropy (disorder) of the universe is always increasing
  3. Perfectly crystalline solid at absolute zero has an entropy of zero.
21
Q

What is Gibbs Free Energy and what is equation?

A

Tells us about spontaneity of a process
Gibbs Free Energy = Change in Enthalpy - (temperature * change in entropy)

22
Q

How to convert Celsius to Kelvin?

A

Kelvin = Celsius + 273.15

23
Q

Based on Hess’s law, how do you find the change in enthalpy?

A

Change in enthalpy = Sum of standard heats of products - sum of standard heats of reactions