Thermochemistry Flashcards

1
Q

Thermodynamics Introduction

Heat

A
  • speed or Energy of particles
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2
Q

Thermodynamics Introduction

Energy

A

Capacity to do work

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3
Q

Thermodynamics Introduction

Work

A

Action of Force through ∆x

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4
Q

Thermodynamics Introduction

Total Energy of object

A
  • KE: E associated with motion ==> Thermal Energy
  • PE: (bond energy); energy associated with position or composition
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5
Q

Energy Units

1 L*atm

A

101.325 J

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6
Q

Energy Transfer

Energy Transfer between system and surroundings

A
  • Sys decrease(-) = Increase surroundings(+)
  • Sys increase(+) = Decrease surroundings(-)
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7
Q

Definition of Specific Heat(c)

A
  • Amount of energy required to raise 1 gram by 1 C
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8
Q

Exothermic vs Endothermic

Exothermic

A
  • Graph increases then ends lower than starting level(∆ PE = -)
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9
Q

Exothermic vs Endothermic

Endothermic

A
  • Graph increases then ends higher than starting level(∆ PE = +)
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10
Q

Types of Systems

Open

A
  • matter and Energy exchanged with surroundings
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11
Q

Types of Systems

Closed

A
  • Only Energy may exchange with surroundings but not matter
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12
Q

Type of System

Insulated

A
  • No energy or matter exchanged with surroudings
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13
Q

Transfer between system and surroundings

Energy Transfer with work and heat

A
  • E = q + w
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14
Q

Transfer between system and surroundings

Heat/Q

A
  • Driving Force = ∆T
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15
Q

Transfer between system and surroundings

Work/W

A
  • Driving Force = - P * ∆V
  • W= Fd
  • Compression = (+)
  • Expansion = (-)
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16
Q

Heat

Heat Capacity

A
  • C
  • q=C∆T
  • slope of Q and ∆T
  • units = J/C
  • Extensive: Depends on mass
17
Q

Heat

Specific Heat

A
  • c
  • c = Q/m/∆T
18
Q

Calorimeter

Bomb

A
  • Constant Volume
  • qcal=Ccal* ∆T
  • qcal = qrxn = ∆Erxn
19
Q

Calorimeter

Coffee-Cup

A
  • Constant Pressure
  • qcal=Ccal* ∆T
  • qcal = qrxn = ∆Erxn
20
Q

Standard Enthalpy of Formation

Standard State

A
  • State of Pure Substance at l atm P and Temp of Interest(25 C)
21
Q

Standard Enthalpy of Formation

Standard Enthalpy of change

A
  • ∆H^o
  • ∆H of reactants and products
22
Q

Standard Enthalpy of Formation

Standard Enthalpy of Formation

A
  • ∆H when 1 mol substance formed from compund standard state elements
23
Q

Standard Enthalpy of Formation

Standard Enthalpy of Formation Equation

A
  • ΔHoreaction=ΣΔHof(p)−ΣΔHof(r)
24
Q

Hess’ Law

Hess’ Law

A
  • If equation can be explained as sum of 2+ equations, ∆ H for desired equation = ∆ H sum of other equation
25
Q

Phase Changes

Heat absorbed into system

A
  • q > 0
  • melting, vaporization, sublimation
26
Q

Phase Changes

Heat released into system

A
  • q < 0
  • freezing, condensation, deposition