Thermochemistry 1/14 Flashcards

1
Q

What is thermochemistry?

A

Thermochemistry is the study of the heat energy involved in chemical reactions and changes of state.

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2
Q

What is the unit of heat in the metric system?

A

The unit of heat in the metric system is the joule (J).

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3
Q

True or False: A calorie is defined as the amount of heat needed to raise the temperature of 1 gram of water by 1 degree Celsius.

A

True.

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4
Q

How many joules are in one calorie?

A

One calorie is approximately 4.184 joules.

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5
Q

What is specific heat capacity?

A

Specific heat capacity is the amount of heat required to raise the temperature of 1 kilogram of a substance by 1 degree Celsius.

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6
Q

Fill in the blank: The formula for calculating heat (q) is q = _____ x m x ΔT.

A

c

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7
Q

What does the symbol ΔT represent in thermochemical equations?

A

ΔT represents the change in temperature.

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8
Q

What is the specific heat capacity of water?

A

The specific heat capacity of water is approximately 4.18 J/g°C.

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9
Q

True or False: The heat capacity of a substance depends on the amount of substance present.

A

True.

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10
Q

What is the difference between heat and temperature?

A

Heat is the energy transferred between substances, while temperature is a measure of the average kinetic energy of the particles in a substance.

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11
Q

What is the equation for calculating the heat absorbed or released during a phase change?

A

q = n * ΔH, where n is the number of moles and ΔH is the enthalpy of the phase change.

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12
Q

Fill in the blank: The enthalpy change associated with a chemical reaction at constant pressure is represented by _____ (ΔH).

A

enthalpy change

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13
Q

What is the calorimeter used for?

A

A calorimeter is used to measure the heat of chemical reactions or physical changes.

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14
Q

What is the heat of reaction?

A

The heat of reaction is the amount of heat released or absorbed during a chemical reaction.

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15
Q

True or False: Thermochemistry only deals with exothermic reactions.

A

False.

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16
Q

What does the term ‘exothermic’ mean?

A

Exothermic refers to a reaction that releases heat to the surroundings.

17
Q

What does the term ‘endothermic’ mean?

A

Endothermic refers to a reaction that absorbs heat from the surroundings.

18
Q

What is the standard heat of formation?

A

The standard heat of formation is the change in enthalpy when one mole of a compound is formed from its elements in their standard states.

19
Q

Fill in the blank: The law of conservation of energy states that energy cannot be _____ or _____; it can only be transformed from one form to another.

A

created, destroyed

20
Q

What is the equation for calculating work done by a gas during expansion?

A

W = -PΔV, where W is work, P is pressure, and ΔV is the change in volume.

21
Q

What is the significance of the Gibbs free energy?

A

Gibbs free energy determines the spontaneity of a process; a negative Gibbs free energy indicates a spontaneous process.

22
Q

What is the heat capacity at constant volume represented by?

A

The heat capacity at constant volume is represented by Cv.

23
Q

What is the heat capacity at constant pressure represented by?

A

The heat capacity at constant pressure is represented by Cp.

24
Q

True or False: Heat capacity is an extensive property.

25
What is the relationship between heat capacity and specific heat?
Specific heat is the heat capacity per unit mass of a substance.
26
What is the calorific value of a fuel?
The calorific value is the amount of energy produced per unit mass or volume of fuel when it is burned.