Thermochem Flashcards
energy:
the ability to do work
potential energy:
stored energy (within the bonds in chem)
kinetic energy:
energy due to motion
enthalpy:
heat absorbed or released through a chemical rxn
thermal enthalpy:
energy generated by heat (ET = Eg + Ek)
temperature:
a measure of avg kinetic energy
(EK ⬆️, temp ⬆️)
- measure w thermometer
heat:
energy transferred from 1 substance to another due to temp difference between them
open system:
exchanges both MATTER and ENERGY w surroundings (ex: open rxn flask)
closed system:
exchanges only ENERGY w surroundings (matter remains fixed)
isolated system:
doesn’t exchange ENERGY NOR MATTER w surroundings
law of conservation of energy:
energy is not created or lost. it is transferred (heat lost by one = heat gained by another)
specific heat capacity
amount of heat required to raise the temp of the unit mass of a given substance by a given amount
endothermic:
rxns that require heat from surroundings (lower in temp)
-if more energy is needed to break reactant bonds compared to the amount of energy released in making new product
exothermic:
rxns that release heat (up in temp)
-if more energy is released in making new product bonds than amount needed to break original reactant bonds
hess’ law
change in enthalpy is equal to sum of each individual rxn
- (no matter the amount of steps or intermediate rxns)