Thermo Exam Definitions Flashcards
In 35 words or less, define or explain Enthalpy
Enthalpy is a combination property, H = U + pV.
U is microscopic internal energy.
The pV term has the sense of work and relates to flow work.
In 35 words or less, define or explain Closed System
A system in which there is a control mass.
Mass cannot cross the system boundary, but energy in the form of heat or work can cross the boundary.
In 35 words or less, define or explain Open System
A system in which there is a control volume.
Both mass and energy can cross the system boundary.
In 35 words or less, define or explain Property of State.
This is a characteristic of the system that depends only on, and determines, the current equilibrium state of the system.
In 35 words or less, define or explain Reversible Process.
The system can be transformed from state 1 to state 2 and back with no trace left on the surroundings.
In 35 words or less, define or explain Isentropic Process.
A process in which there is no change in entropy. It is a reversible, adiabatic process.
An isentropic process is adiabatic and frictionless.
In 35 words or less, define or explain Thermodynamic Temperature Scale.
A temperature scale that is not dependent on a thermometric material.
It has an absolute zero.
It is defined by thermodynamics.
In 35 words or less, define or explain Cyclic Process.
The end state is identical to the start state.
In 35 words or less, define or explain Stationary System.
This is a system that exhibits minimal change in kinetic energy or potential energy during a process.
In 35 words or less, define or explain The First Law of Thermodynamics
During a cyclic process, the net heat addition to a system is proportional to the net work produced, and vice versa.
In 35 words or less, define or explain Internal Energy
Comprised of all microscopic forms of energy in a process.
A property of state following from the first corollary of the first law.
In 35 words or less, define or explain Entropy
A Property of State and indication of disorder.
It is defined by dS = dQrev/T, and follows as a corollary of the Second Law of Thermodynamics.
In 35 words or less, define or explain System Boundary.
The real or imaginary surface separating the system from its surroundings.
Defined so as to identify the flow of mass, heat and work of interest in system analysis.
In 35 words or less, define or explain System.
A collection of entities that interest us. Can be a fluid sample of a machine.
Defined by system boundary.
In 35 words or less, define or explain Carnot Efficiency.
The Highest Efficiency a heat engine can have when operating between two thermal energy reservoirs at temperatures TL and TH ; n = 1 - TL / TH
In 35 words or less, define or explain Equilibrium
Implies a state of balance.
No net force or heat flow acts on the system.
A system in equilibrium experiences no changes when it is isolated from its surroundings.
In 35 words or less, define or explain the Clausius Statement of the 2nd Law of Thermodynamics
It is impossible to construct a machine which in itself will cause heat to pass from a cold reservoir to a hot reservoir with no other effect.
In 35 words or less, define or explain Polytropic Process
A process in which pressure and volume are often related by pVn = C, where C and n are constant, during expansion and compression processes of real gases.
In 35 words or less, define or explain Isobaric
Indicates constant pressure.
An isobaric process is a process in which the pressure remains constant.
In 35 words or less, define or explain Intensive Property
Intensive Properties are those that are independent of the size of a system and are obtained by dividing by the mass of the fluid.
Intensive properties are not additive.
In 35 words or less, define or explain Process
Any change that a system undergoes from one equilibrium state to another.
In 35 words or less, define or explain Thermodynamics
The science of the relationship between heat and mechanical work.
Also known as the science of energy.
In 35 words or less, define or explain Thermal Equilibrium.
A state of balance, in which the temperature is the same throughout the system.
In 35 words or less, define or explain Specific Heat Capacity at Constant Volume (cv)
A measure of the energy required to raise the temperature of a unit mass of substance by one degree as the volume is maintained constant.