Thermo Exam Definitions Flashcards

1
Q

In 35 words or less, define or explain Enthalpy

A

Enthalpy is a combination property, H = U + pV.

U is microscopic internal energy.

The pV term has the sense of work and relates to flow work.

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2
Q

In 35 words or less, define or explain Closed System

A

A system in which there is a control mass.

Mass cannot cross the system boundary, but energy in the form of heat or work can cross the boundary.

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3
Q

In 35 words or less, define or explain Open System

A

A system in which there is a control volume.

Both mass and energy can cross the system boundary.

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4
Q

In 35 words or less, define or explain Property of State.

A

This is a characteristic of the system that depends only on, and determines, the current equilibrium state of the system.

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5
Q

In 35 words or less, define or explain Reversible Process.

A

The system can be transformed from state 1 to state 2 and back with no trace left on the surroundings.

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6
Q

In 35 words or less, define or explain Isentropic Process.

A

A process in which there is no change in entropy. It is a reversible, adiabatic process.

An isentropic process is adiabatic and frictionless.

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7
Q

In 35 words or less, define or explain Thermodynamic Temperature Scale.

A

A temperature scale that is not dependent on a thermometric material.

It has an absolute zero.

It is defined by thermodynamics.

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8
Q

In 35 words or less, define or explain Cyclic Process.

A

The end state is identical to the start state.

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9
Q

In 35 words or less, define or explain Stationary System.

A

This is a system that exhibits minimal change in kinetic energy or potential energy during a process.

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10
Q

In 35 words or less, define or explain The First Law of Thermodynamics

A

During a cyclic process, the net heat addition to a system is proportional to the net work produced, and vice versa.

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11
Q

In 35 words or less, define or explain Internal Energy

A

Comprised of all microscopic forms of energy in a process.

A property of state following from the first corollary of the first law.

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12
Q

In 35 words or less, define or explain Entropy

A

A Property of State and indication of disorder.

It is defined by dS = dQrev/T, and follows as a corollary of the Second Law of Thermodynamics.

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13
Q

In 35 words or less, define or explain System Boundary.

A

The real or imaginary surface separating the system from its surroundings.

Defined so as to identify the flow of mass, heat and work of interest in system analysis.

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14
Q

In 35 words or less, define or explain System.

A

A collection of entities that interest us. Can be a fluid sample of a machine.

Defined by system boundary.

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15
Q

In 35 words or less, define or explain Carnot Efficiency.

A

The Highest Efficiency a heat engine can have when operating between two thermal energy reservoirs at temperatures TL and TH ; n = 1 - TL / TH

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16
Q

In 35 words or less, define or explain Equilibrium

A

Implies a state of balance.

No net force or heat flow acts on the system.

A system in equilibrium experiences no changes when it is isolated from its surroundings.

17
Q

In 35 words or less, define or explain the Clausius Statement of the 2nd Law of Thermodynamics

A

It is impossible to construct a machine which in itself will cause heat to pass from a cold reservoir to a hot reservoir with no other effect.

18
Q

In 35 words or less, define or explain Polytropic Process

A

A process in which pressure and volume are often related by pVn = C, where C and n are constant, during expansion and compression processes of real gases.

19
Q

In 35 words or less, define or explain Isobaric

A

Indicates constant pressure.

An isobaric process is a process in which the pressure remains constant.

20
Q

In 35 words or less, define or explain Intensive Property

A

Intensive Properties are those that are independent of the size of a system and are obtained by dividing by the mass of the fluid.

Intensive properties are not additive.

21
Q

In 35 words or less, define or explain Process

A

Any change that a system undergoes from one equilibrium state to another.

22
Q

In 35 words or less, define or explain Thermodynamics

A

The science of the relationship between heat and mechanical work.

Also known as the science of energy.

23
Q

In 35 words or less, define or explain Thermal Equilibrium.

A

A state of balance, in which the temperature is the same throughout the system.

24
Q

In 35 words or less, define or explain Specific Heat Capacity at Constant Volume (cv)

A

A measure of the energy required to raise the temperature of a unit mass of substance by one degree as the volume is maintained constant.

25
In 35 words or less, define or explain **Carnot Cycle**
A **cycle** composed of **four reversible processes**, **two isothermal**, **two adiabatic**.
26
In 35 words or less, define or explain **Irreversible Process**
A process that cannot be reversed without leaving a trace on the surroundings.
27
In 35 words or less, define or explain **Kelvin's Statement of the 2nd Law of Thermodynamics**
It is **impossible** for any **device** that **operates on a cycle** to **recieve heat** from a **single reservoir** and **produce** a **net** amount of **work**.
28
In 35 words or less, define or explain **Turbofan Engine**
A large fan driven by the turbine forces air through a cowl surrounding the engine. The fan exhaust leaves at a higher velocity, enhancing the total thrust of the engine.
29
In 35 words or less, define or explain **Pressure**
The force exerted per unit area
30
In 35 words or less, define or explain **Density**
The amount of matter/substance per unit volume
31
In 35 words or less, define or explain **Specific Volume**
The volume of space taken up by one unit of mass.
32
In 35 words or less, define or explain **Adiabatic Process**
A process during which there is **no heat transfer**.
33
In 35 words or less, define or explain **Boundary Work**
(**pdV**) Work associated with expansion or compression of gas in a piston-cylinder.
34
In 35 words or less, define or explain **Isochoric**
(a.k.a. isometric) A process during which the specific volume (-v-) remains constant.
35
In 35 words or less, define or explain **Isolated System**
A closed system in which energy is not allowed to cross the boundary.
36
In 35 words or less, define or explain **Coefficient of Performance (COP)**
The **measure of performance** of **refrigerators** and **heat pumps**.
37
In 35 words or less, define **isentropic efficiency.**
**Isentropic efficiency** is the ratio of **real world work** to **reversible work**. n = W/W' = (h2 - h1) / (h2' - h1)