Thermo chemistry Flashcards

1
Q

Kinetic energy

A

energy of motion of an object

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2
Q

Thermal Energy

A

Kinetic energy of molecules

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3
Q

Potential Energy

A

Stored energy due to position of composition

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4
Q

Units of energy

A

Joules (work or energy)
Calories (1cal is 4.184 kj)
Nutritional Calorie

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5
Q

1 calorie =

A

1000cal = 1 Kcal

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6
Q

Open system

A

can exchange matter and energy with the surroundings

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7
Q

Closed system

A

Can only exchange energy with the surroundings

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8
Q

Isolated system

A

Neither energy or matter are exchanged with the surroundings

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9
Q

Heat (q) is

A

Energy transferred from hot to cold until equilibrium is reached

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10
Q

Work (w)

A

Move an object or squash gas by applying force

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11
Q

Work is defined as

A

w=force X distance

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12
Q

First law of thermodynamics

A

energy is neither created or destroyed

And energy lost by a system is gained by the surroundings

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13
Q

Internal energy is

A

Sum of the kinetic/potential energy of all the parts of the system USE (U)

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14
Q

Determining the change in internal energy by

A

DELTA (U) = U final- U initial

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15
Q

What is a exothermic rxn

A

Heat is released during the reaction

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16
Q

What is a endothermic RXN

A

Heat is absorbed during the reaction.

17
Q

Define state function

A

value depends only on the present state of the system and the conditions and does not depend on how that stat was achieved

18
Q

Hess’s law

A

The enthalpy change of an overall process is the sum of the enthalpy changes of it individual steps

19
Q

Heat capacity

A

Amount of heat required to raise the temperature of a object by 1 Kelvin

20
Q

Specific heat

A

defined for 1 gram of a substance to be raised by 1 kelvin .

21
Q

Difference between system and surroundings

A

System is part of the universe that we are studying

The surroundings is everything outside of our system

22
Q

What is part of a state function

A

Temperature, internal energy, entropy

23
Q

what is the 2nd law of thermodynamics

A

Entropy increases in a spontaneous process

24
Q

What is the 3rd law of thermodynamics

A

Entropy is zero is a perfect crystal at 0 K

25
Q

What is meant by a spontaneous process in thermodynamics

A

One that requires no continuing input of energy to proceed

26
Q

The expression for Delta D in term of changes in entropy and enthalpy

A

DeltaG=DeltaH-TDeltaS

27
Q

What is Lechateliers Principle

A

If a change is made to a system in equilibrium is will counteract to bring the equilibrium back to equal