Thermo Flashcards

1
Q

PV =

A

PV = mRT

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2
Q

R =

A

Rbar/M

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3
Q

PV/T (1) =

A

PV/T (1) = PV/T (2)

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4
Q

x =

A

x = mg/ (mg + mf)
or
x = (v - vf) / (vg-vf)

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5
Q

1-x =

A

1-x = mf / m

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6
Q

v =

A

v = vf + x vfg;
h = xfhf + xghg
or
v = V/m

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7
Q

Cv =

A

du/dt = Cp/k

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8
Q

Cp =

A

Cp = dh/dt; and Cp = Cv + R (ideal gases)

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9
Q

Power =

A

Work/time = KJ/s

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10
Q

Work =

A

Work = Pdv; Fdx; KJ

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11
Q

Enthalpy (h)

A

h = u + Pvfg)
Energy to vapourise (h)
Internal energy (u)
Energy to expand (Pvfg)

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12
Q

E =

A

U + Pe + Ke; = Q-W

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13
Q

Internal energy

dU =

A
dH = mCpdT
Const pressure (Cp)
dU = mCvdT
Const vol (Cv)

OR

dU = U2-U1; U = mfuf+mgug; m = V/v

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14
Q

dS (entropy) > 0 =?

A

An irreversible process

=0; reversible

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15
Q

Control Volume equation:

A

Q̇− Ẇ= ∑out ṁ (ℎ+Pe +ke)− ∑in ṁ(ℎ+Pe+ke)

=m ̇(dℎ+dpe +dke) (single stream)

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16
Q

Heat engine COP

A

η= 1 − QL/QH

Can sub q for T

17
Q

Heat pump COP

A

B′= 1/η

18
Q

Refrigerator COP

A

B=

1 /
(QH/QL) −1

19
Q

Define an adiabatic system.

A

No heat or mass transfer across system boundary

20
Q

Define a closed system.

A

No mass transfer. Energy transfer only.

Control mass method.

21
Q

Define an open system.

A

Mass and energy transfer.

Control volume method.

22
Q

What are 3 forms of energy?

A

Kinetic - movement of mass;

Potential - position of mass;

Internal energy: molecularmotion, latent (intermolecular forces and phase change) and chemical (bonds within a molecule).

23
Q

First Law:

A

Energy can be transformed, not created or destroyed. E = Q-W

24
Q

mass = (in terms of Vol)

A

m = V/v

25
Q

What is the difference between the energy equation for a non-flowing fluid and a flowing fluid.

A
Nonflowing: e = u + ke + pe
Flowing: e = (u+Pv) + ke + pe
Pv = flow energy
h = u+Pv
e = h + ke + pe
26
Q

What is the Kelvin Planck statement?

A

It is impossible to operate in a cycle and produce no effect other than work and heat exchange with a single reservoir.
e.g to do work you need a change in temp

27
Q

Clausius statement:

A

It is impossible to transfer heat without work