Thermal Physics-prop,thermo,kinetic theory Flashcards

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1
Q

What is molar specific heat (c)?

A

Heat supplied to raise the temp. of 1 mole of gas by 1°C is called molar specific heat(c).
• C=Q/nΔT

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2
Q

Cv for any gas is equal to

A

fR/2

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3
Q

For cyclic process Q=W.

T/F

A

True.

• ΔU =0 (bcz initial & final positions are same i.e,ΔT=0 )

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4
Q

For any gas, ΔU equals

A

ΔU = fnRT/2

Where f is the degree of freedom of that gas.

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5
Q

State first law of thermodynamics?

A

Q= ΔU + W

Where Q is the heat supplied “into” the system; ΔU is change in internal energy and W is work done “by” the gas.

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6
Q

Under normal conditions, what is the value of f for

a) monoatomic gas
b) diatomic gas
c) triatomic gas

A

Monoatomic, f=3
Diatomic, f=5
Triatomic, f=6 (non-linear)

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7
Q

What is efficiency of a cyclic process?

A

Efficiency (η)= work done/heat input = W/Qi

*heat input=total heat absorbed

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8
Q

Give the relation b/w pressure and volume in case of an adiabatic process?

A

PV^γ =const.

Where γ is Cp/Cv for that gas

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9
Q

Work done in an adiabatic process is given by

A

W = (P1V1 - P2V2)/γ-1

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10
Q

Give day-to-day example of adiabatic processes and other special processes.

A

All fast processes can be considered adiabatic, and other slow processes can be included as isothermal,isobaric,isochoric depending on which one is const.-T,P,V.

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11
Q

Work done in isothermal process is given by

A

W = nRT ln(V2/V1)

= nRT ln(P1/P2)

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12
Q

What is a polytropic process?

A
When PV^N is const.
# Where N is the power to which volume is raised on having PV = const.
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13
Q

Work done for a polytropic process id given by

A

W = (P1V1 - P2V2)/N-1

= - (N R ΔT)/ N-1

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14
Q

Heat supplied for a polytropic process is

A

Q = n ΔT ( Cv - R/N-1)

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15
Q

Molar heat capacity for polytropic process is

A

C = Cv - R/N-1

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