Thermal Physics Flashcards

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1
Q

Thermal equilibrium

A

No net heat flow between objects

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2
Q

Pressure

A

The force applied perpendicular to the surface of an object, per unit area.

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3
Q

Internal energy

A

The sum of the total kinetic energy and potential energy associated with the atoms/molecules of a system

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4
Q

Specific heat capacity

A

The heat energy required to raise the temperature of 1kg of a substance by 1 degree Kelvin.

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5
Q

Specific latent heat of fusion

A

The energy absorbed by 1kg of a substance to change its state from solid to liquid with no change in temperature

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6
Q

Specific latent heat of vaporisation

A

The energy absorbed by 1kg of a substance to change its state from liquid to gas with no change in temperature

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7
Q

Boyle’s law

A

For a fixed mass of gas at a constant temperature the product of pressure and volume is a constant.

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8
Q

Assumptions of an Ideal Gas

A

Collisions between molecules and the container walls are elastic.
Force between molecules is negligible except during collisions.
Time within a collision is negligible compared to time between collisions.
Volume occupied by particles is negligible compared to the volume of the container.

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9
Q

1 mole of a substance…

A

…contains 6.02x10^23 particles

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10
Q

How does a gas exert a pressure on a container wall?

A

Momentum of the molecule changes when it collides with the wall.
Force on the molecule is the rate of change of momentum (by Newton’s 2nd law).
Force on the wall is equal but opposite to the force on the molecule (by Newton’s 3rd law).
Pressure is force per unit area.

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11
Q

Brownian motion

A

Random motion (of smoke particles etc) due to many collisions with very fast, tiny (unseen) molecules which are moving in random directions.

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12
Q

Avogadro’s Constant

A

6.02x10^23 - the number of particles in a system when there is 1 mole present.

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13
Q

What does E = mcΔθ stand for?

A

E is the supplied energy to the substance
m is the mass of the substance
c is the specific heat capacity of the substance
Δθ is the temperature change

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14
Q

What do θ and T stand for?

A

θ is the symbol for temperature on the Celsius scale (units: ‘degrees celsius’)
T is the symbol for temperature on the thermodynamic scale (units: ‘degrees kelvin’)

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15
Q

What does pV = NkT mean?

A
p is pressure
V is volume
N is number of particles
k is Boltzmann constant (1.38x10^-23)
T is temperature in kelvin
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16
Q

What does pV = nRT mean?

A
p is pressure
V is volume
n is number of moles of gas
R is the molar gas constant (8.31)
T is temperature in kelvin
17
Q

What does E = (3/2)kT mean?

A

E is the mean translational kinetic energy of atoms
k is Boltzmann constant (1.38x10^-23)
T is temperature in kelvin

18
Q

How are k and R related?

A

Molar gas constant = Boltzmann constant * Avogadro constant