Thermal Physics - Flashcards
What is absolute temperature ?
The temperature where the particles have no kinetic energy. Given by the value of 0k
How to convert from kelvin to Celsius ?
K - 273 = degrees Celsius
What is the molecular mass ?
The sum of the masses of all the atoms that make up a single molecule- example h2o
21 +116 = 18
2 hydrogen and one oxygen
What is avogadro’s constant ?
The number of molecules within a mole. (Na)
6.023 * 10 ^ 23
(Carbon 12 isotope - number of atoms within exactly 12 grams of an isotope )
What does 1 mole of a substance mean ?
It is a substance containing Na number of atoms.
What is the equation linking the number of atoms and the number of moles ?
N = n* Na
N - number of molecules or atoms
n - number of moles
What is the molar mass ?
It is the mass of 1 mole of a substance = the molecular mass
Give the relationship between the mass of a substance and the number of moles
Given that M is the mass of 1 mole
The mass of the substance (m) = Mn
Give the relationship between the number of moles and the atoms/ particles in the substance .
Number of atoms in the substance (N) = n*Na
Give the relation between the number of atoms in a substance and the mass of the substance.
N (no of atoms ) = (m/n) * Na = n*Na
What are the conditions/assumptions of ideal gases ?
- gas particles are point masses (same mass + spherical )
- average kinetic energy is directly proportional to the absolute temperature
- particles move in constant random motion
- follow newtons laws
- have a negligible volume compared to the container
- the collisions are elastic
- the motion of the particles are straight
What does Boyles law state ?
At a constant temperature the pressure of a fixed mass of gas is inversely proportional to its volume
What is the equation to find a missing value ( boules law ) ?
P1V1 = p2 v2
As p*v = a constant
What does Charles law state ?
At a constant pressure , the volume of a fixed mass of gas is directly proportional to its absolute temperature
What is the equation to find a missing value ( Charles law ) ?
V1 / t1 =v2 / T2
As v/t is a constant
What does the pressure law state ?
At a constant volume, the pressure p of a fixed mass of gas is directly proportional to its absolute temperature
What is the equation to find a missing value ( pressure law ) ?
P1/ T1 = P2 /T2
As p/t is a constant
At a constant temperature why is there greater pressure when the volume decreases ?
- when the volume is decreased the particles are closer together so collide with each other and the walls more frequently with force producing a greater pressure
Why does the volume increase when the temperature increases at a constant pressure ?
As the temperature increases the particles gain more faster / move further apart taking up a greater volume
What is an isobaric change ?
A change where the pressure is kept constant
How can you change the volume of a gas at a constant pressure ?
Work has to be done ( transferring heat energy ) by heating
What is the equation linking the work done and the pressure and volume ?
Work done = pressure times change in volume
Why does the pressure increase as the temperature increase at a constant volume ?
As the temperature increases the kinetic energy of the particles increase causing them to travel at a faster speed colliding more frequently with a greater force producing a greater pressure
What is the equation you get from combining the three gas laws ?
PV/ T = R ( one mole )
Pv = nRT (n moles )