Thermal Physics Flashcards

1
Q

What is Internal Energy

A

The sum of Ek and Ep of the molecules in a system

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2
Q

What can we say about internal energy for a monatomic gas?

A

As there are no forces between molecules, there is no potential energy. So the internal energy is purely kinetic.

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3
Q

State the equations associated with internal energy

A

U=3/2 nRT and U=3/2 NkT

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4
Q

What is absolute zero

A

Absolute zero is the temperature where the internal
energy of a system is at a minimum.

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5
Q

State the direction of flow for heat

A

Heat always flows from hot to cold

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5
Q

How does heat energy flow

A

Heat energy flows by conduction, convection and by radiation. This only applies for energy in transit and not for energy contained within a system

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5
Q

What is thermal equilibrium?

A

The temperature is the same on both sides of the boundary and there is no heat flow between them

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5
Q

Energy can also be transferred by doing what to a system?

A

Work

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5
Q

State the equation for work done by a gas

A

W=pΔv
Δv=change in volume
p= constantpressure

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5
Q

How would you calculate work done for a pressure-volume graph?

A

Area under the graph

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5
Q

Give the equation for the first law of thermodynamics at constant pressure

A

Q=ΔU + pΔV

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5
Q

If a pressure-volume graph has a curved line, what kind of work is this

A

Isothermal change

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5
Q

What does isothermal changes mean

A

When work is done over a long period of time

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5
Q

What does the first law of thermodynamics state?

A

The heat given to a system= increase in internal energy+ Work done by the system

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5
Q

Give the equation for the first law of thermodynamics at constant volume

A

W=0
Q=ΔU

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5
Q

Give the equation for the first law of thermodynamics

A

Q=ΔU+W
Q=heat energy
ΔU= change in internal energy
W=Work done

5
Q

Give the equation for the first law of thermodynamics at constant temperature

A

ΔU=0
Q=W

5
Q

Define specific heat capacity

A

The heat required per kilogram per degree celsius or kelvin to raise the temperature of a substance

5
Q

Give the equation for the first law of thermodynamics when heat enters/leaves the system

A

Q=0
ΔU=-W

5
Q

Give the equation associated with specific heat capacity

A

Q=mcΔθ
Q=heat input
m=mass
c=specific heat capacity
Δθ= Change in temperature