Thermal physics Flashcards

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1
Q

Define internal energy

A

The sum of the potential and kinetic energy of the molecules or atoms

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2
Q

What are the two components of internal energy

A

Kinetic and Potential energy

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3
Q

What are the three components of kinetic energy

A

Translational motion
Rotational motion
Vibrational motion

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4
Q

What causes Potential energy

A

Intermolecular forces

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5
Q

When energy is transferred to or from a system it can take two forms, what are they.

A

Heat
Work
Also it is impossible to tell which form it took.

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6
Q

Define Heat energy

A

The energy which flows by conduction, convection or radiation from one body to another due to the temperature not being in equilibrium.

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7
Q

Flow Heat, Q is …

A

the energy in transit and not contained within the system

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8
Q

Heat will always flow from the body in … temperatures to the body in … temperatures.
Until both bodies are in …

A

Higher
Lower
Equilibrium

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9
Q

Define Work

A

Work is the energy that is transferred from one system to another by a force moving its point of applications in its own direction.

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10
Q

If heat is introduced to a gas where the set-up is such that the pressure remains constant, what will happen to the gas?

A

The gas will do work

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11
Q

What is the work done always equal to in indicator diagrams

A

the area under the p-V graph (indicator diagram)

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12
Q

What is the first law of equilibrium in words

A

Heat given to a system = increase in internal energy of the system + work done by the system

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13
Q

What is the equation related to the first law of equilibrium

A

Q = ΔU + W

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14
Q

If Q is positive Heat is …… the gas

A

Supplied to

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15
Q

If Q is negative Heat is …… the gas

A

Transferred from

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16
Q

If W is positive … work is …… the gas (…)

A

External
Done by
Expanding

17
Q

If W is negative work is …… the gas (…)

A

Done on
Compressing

18
Q

If ΔU is positive the internal energy …

A

Increases

19
Q

If ΔU is negative the internal energy …

A

Decreases

20
Q

If ΔV = 0 then W = …

A

0

21
Q

What is the equation for Q when pressure is constant

A

Q = ΔU +pΔV

22
Q

What is the equation for Q when temperature is constant

A

Q = W, since if the process is completed very slowly, any decrease in temperature will cause the heat to flow into maintain thermal equilibrium.

23
Q

What is the equation for Q when the volume is constant

A

Q = ΔU, since ΔV = 0 so W = 0

24
Q

What is the equation for ΔU when there is no heat flow, Q = 0

A

ΔU = - W

25
Q

What is the equation for Q for liquids and solids

A

Q = ΔU, since volume barely changes.

26
Q

What is the equation for specific heat capacity

A

Q = mcΔθ

27
Q

Define Specific Heat capacity

A

The heat required, per kilogram per degree kelvin to raise the temperature of a substance

28
Q

Describe Absolute Zero in terms of internal energy

A

It is the temperature of a system when it has minimum internal energy