Thermal Physics Flashcards

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1
Q

What is 0°C in Kelvin?

A

273.15K

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2
Q

How do you calculate internal energy?

A

Internal energy = Σkinetic energies + Σpotential energies
ΔU = ΔQ - ΔW

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3
Q

Describe thermal equilibrium?

A

When there is no net transfer of thermal energy between objects.

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4
Q

What is the 1st Law of Thermodynamics?

A

The change of internal energy of an object is equal to the difference in energy transfer between heating and work done

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5
Q

What is specific heat capacity, c?

A

The energy needed to raise the temperature of 1kg of a substance by 1K without a change of state.

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6
Q

How can you calculate heat energy transferred in an object?

A

ΔQ = mcΔT

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7
Q

What is continuous flow heating?

A

The process of heating a fluid by letting it flow continuously over a heater.

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8
Q

How do you calculate power of a continuous flow heater?

A

P = mcΔT / t

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9
Q

What three things are characteristics of the solid phase?

A

Molecules have little kinetic energy and so don’t move.
Solids maintain their shape, constant volume.
They cannot be easily compressed.

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10
Q

What three things are characteristics of the liquid phase?

A

Molecules have some kinetic energy and are able to slide over one another.
Liquids flow and take the shape of their container.
They cannot be compressed.

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11
Q

What three things are characteristics of the gas phase?

A

Molecules are far apart with lots of kinetic energy allowing them to move freely in space.
Gases take the volume of a container.
They can be easily compressed.

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12
Q

Describe the relationship between the temperature of a pure substance and the energy supplied to it as it changes from solid to gas.

A

Temperature rises proportionally to the energy supplied.
At a definite temperature the substance will change phase at constant temperature.
Once the material has changed phase the temperature will be begin to rise again.

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13
Q

What is the latent heat of a substance?

A

The energy needed to make a substance change phase.

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14
Q

What is pressure?

A

The force per unit area a gas exerts normally to surfaces.

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15
Q

What is Boyle’s Law?

A

The pressure of a given mass of an ideal gas is inversely proportional to its volume at a constant temperature.
P ∝ 1/V

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16
Q

What is Charles’ Law?

A

The volume of an ideal gas at constant pressure is directly proportional to the absolute temperature.
V ∝ T.

17
Q

How do you calculate the work done in compressing a gas?

A

W = pΔV

18
Q

What is the Pressure - Temperature Law?

A

The pressure of an ideal gas at a constant volume is proportional to the absolute temperature.
p ∝ T

19
Q

What is an ideal gas?

A

A real gas that behaves in a way that can be modelled by Boyle’s Law.
Particles can be thought as taking up no volume.
There are no significant forces between particles.
The motion of particles is random.

20
Q

What is Avogadro’s Law?

A

The volume of two ideal gases at the same temperature must contain the same number of particles.

21
Q

What is the molar mass of a substance?

A

The mass of 1 mol of a substance. (kg/mol)

22
Q

What equation uses Boltzman’s constant?

A

pV = NkT
For N molecules of gas.

23
Q

What equation uses the molar gas constant?

A

pV = nRT
For n moles of gas.

24
Q

Explain how increasing temperature, increases pressure?

A

Increased temperature, increases KE of particles.
Increased KE means increased velocity and ∴ greater change in momentum.
This means greater forces and ∴ increased pressure.

25
Q

How does decreasing volume increase pressure?

A

Decreasing volume decreases distance between walls.
∴ increasing the frequency of particle collisions.
This increases the pressure.

26
Q

What 5 assumptions do ideal gases follow? Hint RAVED

A

Random motion of particles
Attraction - non between particles
Volume - can be though of as negligible
Elastic collisions
Duration of collisions is negligible

27
Q

What is Brownian motion?

A

The idea that small (solid) objects move randomly in fluids.
This is due to the random bombardment of molecules in the fluid.
This movement is slightly more on one side so the object is pushed by a force in an instant as the net forces shift direction.
This random motion gives evidence to the existence of atoms.

28
Q

What is internal energy?

A

The sum of the kinetic energy and potential energy of particles in an object.