Thermal Physics Flashcards

(45 cards)

1
Q

heat capacity definition

A

amount of energy required to raise temperature of sample by 1 Kelvin

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2
Q

energy required to raise temperature of sample formula

A

energy required to raise temperature of sample = heat capacity (K/J) x difference in temperature (K, °C)
Q = C x ∆T

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3
Q

energy required to raise temperature of specific mass of sample formula

A

energy required to raise temperature of mass of sample (J) = heat capacity (J/K) x mass (kg) x difference in temperature (K, °C)
Q = C x M x ∆T

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4
Q

power definition and formula

A

rate of energy change
power (W) = energy emitted (Q) / time (s)
P = Q / t

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5
Q

how heat flows

A

hotter object to cooler object
greater difference = faster rate of cooling
energy is transferred

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6
Q

melting

A

heat is added
particles given energy
particles are in fixed position and vibrate
adding sufficient heat causes particles to move faster to break bonds holding them (becomes liquid)

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7
Q

boiling

A

liquid heated
particles gain energy, move faster about their container and liquid expands
interactions between particles become weaker as distance between particles increases
addition of sufficient heat results in liquid expanding where particles interact negligibly (gas)

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8
Q

why temperature doesn’t increase during melting or boiling

A

additional energy is used to break/overcome intermolecular forces
instead of supplying particles with more kinetic energy

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9
Q

latent heat definition

A

amount of energy required to change the state of an object from one state to another
addition/subtraction of heat energy without observation of temperature change

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10
Q

latent heat of fusion definition

A

latent heat when converting from solid to liquid or vice versa

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11
Q

latent heat of vaporisation definition

A

latent heat when converting from liquid to gas or vice versa

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12
Q

amount of energy required to convert given mass from one state to another formula

A

amount of energy required to convert given mass of substance from one state to another (J) = mass of substance (kg) x l (kJkg^-1)
Q = m x l

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13
Q

factors affecting rate of condensation

A

temperature
Surface temperature
airflow
density

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14
Q

how temperature affects rate of condensation

A

as it decreases, rate of cond. increases
particles have lower average energy so
easier and more likely to slow down enough to form liquid

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15
Q

how surface temperature affects rate of condensation

A

as it decreases, rate of cond. increases

cold surface will transfer heat away from gas faster, cooling it quicker and forming condensate faster

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16
Q

how airflow affects rate of condensation

A

as it becomes slower, rate of cond. decreases

as conc. of gas will be higher so more cond. will occur on the surface

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17
Q

how density affects rate of condensation

A

as it increases, rate of cond. increases
forces between particles will be stronger so fewer particles will have enough energy to overcome these forces
more likely to form liquid

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18
Q

how condensation occurs

A

Gas changing to liquid
as gas cools, particles move slower and spend longer in close proximity to each other
intermolecular forces increase as temperature drops
once average temperature is below boiling point, gas particles condense into liquid droplets

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19
Q

how evaporation occurs

A

liquid into gas without boiling
occurs despite temperature of liquid below boiling point and average KE of particles being insufficient to do so
some particles with high KE (above average energy) and travelling toward surface of liquid

20
Q

why evaporation leads to cooling

A

evaporation removes particles with highest energy from liquid
remaining liquid has lower average kinetic energy so lower temperature achieved

21
Q

factors affecting rate of evaporation

A

temperature
airflow
density
surface area

22
Q

how temperature affects rate of evap.

A

rate of evap. increases when temp. of liquid increases

higher temp. = average KE = more particles with enough energy to escape from liquid surface

23
Q

how airflow affects rate of evap.

A

rate of evap. increases when airflow over surface of liquid increases
as conc of evap. substance is lower immediately surrounding liquid
air carries gas away and prevents it from condensing back into liquid so higher net evaporation

24
Q

how density affects rate of evap.

A

rate of evap. increases when density lowers
lower density = particles further apart = forces between particles weaker = more particles with enough energy to overcome them and escape liquid

25
how surface area affects rate of evap.
rate of evap. increases as SA increases as more particles nearer the surface, easier to escape liquid
26
conduction of heat definition
process by which vibrating particles pass on their KE to neighbouring particles in a material
27
factors affecting rate of conduction
tighter neighbouring particles = the more they influence each other = more effective conduction material (e.g. metals) state (solid > liquid > gas at due to intermolecular distances) SA (more room for particles to collide) temp. difference (heat moves faster with greater temp. diff) length (longer conductor = longer it takes for heat to pass from one side to another)
28
why metals good heat conductors
ions tightly bound with small distance (so more influence) between neighbouring ions also delocalised electrons can move freely and quickly inside metal and collide with other electrons and ions to transfer energy quickly electrons from hot regions move through structure and collide with ions and electrons at colder parts
29
insulators
no free electrons (can only transfer energy by vibration of neighbouring atoms) liquids and gases poorer conductors as greater intermolecular distances than solids (so less influence)
30
fluid definition
no fixed shape but flows and spreads to fill the shape of the container it occupies
31
convection definition
method of transporting heat through a fluid due to particle movement
32
convection mechanism
when heated from the bottom, particles gain KE move more quickly so collide more regularly and move further apart take up more volume, decreases density less dense regions of fluids rise and displace colder, denser regions colder denser fluids sink to bottom and be heated, cycle continues
33
convection current definition
currents of moving fluids
34
how you stay warm with jumper/blanket
body heats fixed amount of air around you warm air trapped by blanket without blanket, convection carries away warm air, replaced by colder air
35
heat radiation definition
emission of electromagnetic waves from warm bodies | doesn’t require a medium to travel through
36
heat radiation features
doesn’t require a medium to travel through
37
surfaces and absorbing and emitting infrared radiation
dark matt surfaces > bright glossy surfaces | best absorbers and emitters of infrared radiation as black absorbs all colours and matt surfaces reflect light less
38
why objects become hotter/colder
emit more/less radiation than it absorbs | proportional to how hot it is
39
reducing heat transfers in vacuum flask
vacuum between container and flask prevents convection and conduction since both need medium to occur inside and outside of liquid container are shiny (not black) so heat radiation from outside of bottle reflected back out and radiation from liquid reflected back into liquid bottle supported by insulating foam (conducted little heat to outside as possible) stopped (made out of insulator) prevents heat transfer by convection by trapping air above liquid
40
biology of heat exchange
heat regulated to conserve energy and resources when cold, hair in mammals skin pull upright to trap layer of insulting air around body (reduced her loss by convection) also blood vessels constrict around extremities to reduce blood flow there due to high SA:V ratio, more susceptible to heat loss via radiation opposite occurs when hot + body sweats for heat loss via evaporation
41
animal adaptations in extreme conditions
cold: fur traps insulating air thick layer insulating blubber to reduce heat transfer away from body smaller ears hot: thin layers of fur large ears (higher SA so heat dispersed more effectively by passing blood through dilated blood vessels near surface)
42
density definition and formula
measure of mass of a substance per unit volume density = mass / volume p = M/V
43
how buoyancy depends on density
objects denser then the liquid they are in sink and vice versa
44
how to measure volume of irregular shaped object
place object into beaker of water | find volume of displaced water
45
density and states of matter
solid > liquid > gas | except for water