Thermal Physics Flashcards
(45 cards)
heat capacity definition
amount of energy required to raise temperature of sample by 1 Kelvin
energy required to raise temperature of sample formula
energy required to raise temperature of sample = heat capacity (K/J) x difference in temperature (K, °C)
Q = C x ∆T
energy required to raise temperature of specific mass of sample formula
energy required to raise temperature of mass of sample (J) = heat capacity (J/K) x mass (kg) x difference in temperature (K, °C)
Q = C x M x ∆T
power definition and formula
rate of energy change
power (W) = energy emitted (Q) / time (s)
P = Q / t
how heat flows
hotter object to cooler object
greater difference = faster rate of cooling
energy is transferred
melting
heat is added
particles given energy
particles are in fixed position and vibrate
adding sufficient heat causes particles to move faster to break bonds holding them (becomes liquid)
boiling
liquid heated
particles gain energy, move faster about their container and liquid expands
interactions between particles become weaker as distance between particles increases
addition of sufficient heat results in liquid expanding where particles interact negligibly (gas)
why temperature doesn’t increase during melting or boiling
additional energy is used to break/overcome intermolecular forces
instead of supplying particles with more kinetic energy
latent heat definition
amount of energy required to change the state of an object from one state to another
addition/subtraction of heat energy without observation of temperature change
latent heat of fusion definition
latent heat when converting from solid to liquid or vice versa
latent heat of vaporisation definition
latent heat when converting from liquid to gas or vice versa
amount of energy required to convert given mass from one state to another formula
amount of energy required to convert given mass of substance from one state to another (J) = mass of substance (kg) x l (kJkg^-1)
Q = m x l
factors affecting rate of condensation
temperature
Surface temperature
airflow
density
how temperature affects rate of condensation
as it decreases, rate of cond. increases
particles have lower average energy so
easier and more likely to slow down enough to form liquid
how surface temperature affects rate of condensation
as it decreases, rate of cond. increases
cold surface will transfer heat away from gas faster, cooling it quicker and forming condensate faster
how airflow affects rate of condensation
as it becomes slower, rate of cond. decreases
as conc. of gas will be higher so more cond. will occur on the surface
how density affects rate of condensation
as it increases, rate of cond. increases
forces between particles will be stronger so fewer particles will have enough energy to overcome these forces
more likely to form liquid
how condensation occurs
Gas changing to liquid
as gas cools, particles move slower and spend longer in close proximity to each other
intermolecular forces increase as temperature drops
once average temperature is below boiling point, gas particles condense into liquid droplets
how evaporation occurs
liquid into gas without boiling
occurs despite temperature of liquid below boiling point and average KE of particles being insufficient to do so
some particles with high KE (above average energy) and travelling toward surface of liquid
why evaporation leads to cooling
evaporation removes particles with highest energy from liquid
remaining liquid has lower average kinetic energy so lower temperature achieved
factors affecting rate of evaporation
temperature
airflow
density
surface area
how temperature affects rate of evap.
rate of evap. increases when temp. of liquid increases
higher temp. = average KE = more particles with enough energy to escape from liquid surface
how airflow affects rate of evap.
rate of evap. increases when airflow over surface of liquid increases
as conc of evap. substance is lower immediately surrounding liquid
air carries gas away and prevents it from condensing back into liquid so higher net evaporation
how density affects rate of evap.
rate of evap. increases when density lowers
lower density = particles further apart = forces between particles weaker = more particles with enough energy to overcome them and escape liquid