Thermal Flashcards
zeroth law of thermodynamics
If C is initially in thermal equilibrium with both A and B then A and B are also in thermal equilibrium with eachother
First law of thermodynamics
delta U = Q + W
Internal energy of an ideal gas
depends only on its temperature not on its pressure or volume
Heat capacity of an ideal gas
Cp=Cv+R
Cp
molar heat capacity at constant pressure
Cv
molar heat capacity at constant volume
relationship between Cp and Cv
gamma = Cp/Cv
Adiabatic process for an ideal gas
PV^gamma = constant TV^(gamma-1) = constant
kinetic theory of gases
PV=1/3Nm
PV=2/3N
u
total internal energy
PV for monatomic gas
PV = 2/3 U
PV gamma relation
PV=(gamma-1)U
Clausius 2
It is impossible to construct a cyclical machine whose sole effect is to transfer energy continuously by heat from one object at a higher temperature without the input of energy by work.
Kelvin-Planck
it is impossible to construct a heat engine that, operating in a cycle produces no effect other than the input of energy by heat from a reservoir and the performance and an equal amount of wor
efficiency equation
e=W/Qh