Thermal Flashcards

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1
Q

zeroth law of thermodynamics

A

If C is initially in thermal equilibrium with both A and B then A and B are also in thermal equilibrium with eachother

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2
Q

First law of thermodynamics

A

delta U = Q + W

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3
Q

Internal energy of an ideal gas

A

depends only on its temperature not on its pressure or volume

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4
Q

Heat capacity of an ideal gas

A

Cp=Cv+R

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5
Q

Cp

A

molar heat capacity at constant pressure

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6
Q

Cv

A

molar heat capacity at constant volume

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7
Q

relationship between Cp and Cv

A

gamma = Cp/Cv

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8
Q

Adiabatic process for an ideal gas

A
PV^gamma = constant
TV^(gamma-1) = constant
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9
Q

kinetic theory of gases

A

PV=1/3Nm

PV=2/3N

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10
Q

u

A

total internal energy

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11
Q

PV for monatomic gas

A

PV = 2/3 U

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12
Q

PV gamma relation

A

PV=(gamma-1)U

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13
Q

Clausius 2

A

It is impossible to construct a cyclical machine whose sole effect is to transfer energy continuously by heat from one object at a higher temperature without the input of energy by work.

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14
Q

Kelvin-Planck

A

it is impossible to construct a heat engine that, operating in a cycle produces no effect other than the input of energy by heat from a reservoir and the performance and an equal amount of wor

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15
Q

efficiency equation

A

e=W/Qh

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16
Q

efficiency equation

A

e=W/Qh = (Qh-Qc)/Qc = 1-Qc/Qh

17
Q

adiabatic QU

A

Q=0

delta U = W

18
Q

Isothermal QUW

A

delta U =0 Q=-!

19
Q

four stages of an ideal carnot engine

A

isothermal expansion
adiabatic expansion
isothermal compression
adiabatic compression

20
Q

entropy equation

A

Q1/T1 = S = Q2/S2

21
Q

Change in entropy in isothermal expansion

A

increase in entropy S = Qh/Th

22
Q

change in entropy in isothermal compression

A

decrease in entropy S=Qc/Tc

23
Q

Reversible process

A
  • the intermediate steps are known
  • the system is never far from equilibrium
  • the system can be returned to its original state
24
Q

irreversible process

A
  • the intermediate steps are not known
  • non-equilibrium states are involved
  • it is not possible to run backwards, occurs naturally in one direction only.
25
Q

What is the enclosed part of a Carnot cycle graph

A

The work done