thermal Flashcards
1 mole
the amount of material so the number of basic particles is 6*10^23 (avogadro’s constant)
molar mass
mass of 1 mole of a substance
kinetic model of an ideal gas
the volume of particles negligible compared to volume occupied by gas
forces between particles 0 except during collisions
negligible time in collisions compared to between
random movement
obey newton’s laws (constant velocity between)
elastic collisions (no energy lost)
ideal gas equation
PV=nRT (Pressure, Volume by gas, n moles, R gas constant, T temperature in K
pressure
force per unit area
brownian motion
evidence for the behaviour of an ideal gas
particles are seen to be moving randomly, the change in momentum after collisions with the wall shows a force acting (Newton 2), collisions experienced as an average pressure
macroscopic concepts of thermal physics
temperature, internal energy and thermal energy
thermal energy
transfer of random kinetic energy between objects as a result of a difference in temperature (energy leaking into/out of objects)
result of collisions of molecules
kinetic energy is shared out by collisions averaging the thermal energy
temperature
measure of heat, depends on the kinetic energy of particles
determines the direction of thermal energy transfers
internal energy
total potential(due to attractive forces) and random kinetic energy added up over all the individual molecules of an object depends on substance, temperature, pressure and state of the material
phase changes
happens when the particle bonds change
when the bonds break, they immediately reform but with different particles
the higher the temperature, the faster the particles vibrate, and more often that one breaks
boiling vs evaporating
evaporation is at the surface when individual particles have enough energy to separate (causes cooling, at greatest rate at larger surface areas, high temp and low surrounding humidity)
boiling is when it happens to large numbers of particles
temperature not changing in a phase change
since temperature is the measure of average kinetic energy, at the boiling point the energy supplied does not increase the Ek, but only increases the Ep (distance) between the molecules
thermal capacity
the heat required to change the temp of a body by 1K
C=Q/ΔT
specific heat capacity
heat needed to raise the temp of 1 kg of material by 1K
Q=mcΔT