Thermal Flashcards

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1
Q

energy, specific heat capacity

A

ΔQ = mcθ

where Q is heat
c is shc
θ is temp

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2
Q

find specific heat capacity of iron

A

heater and thermometer in iron block
circuit with voltmeter and ammeter connected to heater

since E = ItV
and c = E/mθ

so c = ItV/mθ

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3
Q

latent heat of fusion

A

energy needed to melt 1kg of substance

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4
Q

latent heat of vaporization

A

energy needed to vaporize 1kg of substance

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5
Q

general equation for specific latent heat

A

l = E/m

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6
Q

energy needed for change in temp of substance when there is a change of state involved

A

E = mcΔT + ml

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7
Q

ice in juice equation
energy as they go equilibrium temp
juice is 20, ice is -5

A

E = mc(20-T) = mc(T-(-5)) + ml

where T is final temp
20-T is temp taken
T-(-5) is temp given
ml is melting of ice

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8
Q

Boyles law

A

P ∝ 1/V
at constant temp

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9
Q

Charles’s law

A

V ∝ T
at constant pressure
(KELVIN)

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10
Q

Gay Lussac law

A

P ∝ T
at constant vol
(KELVIN)

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11
Q

Ideal gas law
(2 forms)

A

pV = NkT

where N is number of molecules
k is Boltzmann’s constant

pV = nRT

where n is number of moles
R = 8.31 (gas constant)

KELVIN

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12
Q

pressure, vol, moles, temp before and after

A

P1V1/n1T1 = P2V2/n2T2

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13
Q

isothermic
isobaric

A

isothermic - T constant
isobaric - P constant

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14
Q

Ideal gas rules

A
  • motion is random
  • volume of particles negligible
  • no internal forces
  • collisions elastic
  • duration of collisions negligible
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15
Q

Kinetic theory of gasses equation

A

P = 1/3 (Nm(Crms)^2/V)

where N is number of molecules
Crms^2 is root mean squared speed

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16
Q

average KE of particle

A

Ek = 3/2 kT

where k is boltzmans constant
KELVIN

17
Q

1st law of thermodynamics

A

Q = ΔU + W

where Q is heat given/taken
ΔU is change in internal energy
W is work done on or by

18
Q

Isothermic process
1st law of T.d

A
  • internal energy of gas not changing
    Q = W
    P1V1 = P2V2
19
Q

adiobatic process
1st law of T.d

A
  • no heat lost or gained
    Q = 0
    ΔU = -W
20
Q

work done by/on gas result

A

Volume changes

21
Q

area under PV graph

A

energy

22
Q

gas compressing vs expanding work done

A

gas compressing - work done on gas
gas expanding - work done by gas

23
Q

PV graphs

A

straight line up: no work done, Q = ΔU

straight horizontal line: W = pΔV (area under graph)

arrow going towards y axis: work done ON

24
Q

2nd law of thermodynamics

A

for a spontaneous process, entropy of the universe increases

25
Q

3rd law of thermodynamics

A

a perfect crystal at 0K has 0 entropy

26
Q

0th law

A

if 2 systems are in equilibrium with a third system, the two systems are in equilibrium with each other