The Rate And Extent Of Chemical Change Flashcards
What is a rate of reaction
How fast the reactants are changed into products
Example of slow rate of reaction
-rusting of iron
-chemical weathering
Example of moderate speed reaction
-magnesium reacting with an acid to produce a gentle stream of bubbles
Example of fast rate of reaction
-burning
-explosions
How graphs show rate of reaction
-steep line=fast rate
-flat line=reaction finished
-short steep line is faster
-long steep line means more reactants
What is collision frequency and how does it affect rate
-how often particles collide
-the more collisions, the faster the reaction
4 things that the rate of reaction depends on
- Temperature
- Concentration of solution or pressure of gas
- Surface area
- Presence of a catalyst
How does increasing temperature affect rate
-when temp is increased, the particles move faster
-if they move faster, they collide more frequently
-more faster=more energy=enough energy for reaction to happen
How does increasing concentration affect rate
-more concentrate= more particles colliding in same volume
-if pressure if gas is increased = same number of particles colliding in smaller space
-more collisions
How does increasing surface area affect rate of reaction
-if one reactant is solid, breaking it into smaller pieces will increase its surface area it volume ratio
-same volume of solid=particles will have more area to work on=more collisions
How does using a catalyst increase the rate of reaction
-catalyst is a substance that speeds up a reaction without being used up in the reaction itself
-they work by decreasing the activation energy
-less energy needed for reaction to occur
Formula for rate of reaction
Rate of reaction= amount of reaction used or amount of product formed / time
How to see rate of reaction visually
-if initial solution is transparent and the product is a precipitate which clouds the solution
-you can observe a mark at the bottom of a flask and see how long it takes for the mark to disappear, the faster it disappears, the quicker the reaction
-you can’t plot a reaction graph from these results
Seeing a rate if reaction by change in mass
-measuring the speed of reaction that produces a gas using a mass balance
-as gas is released, the mass will decrease
-the quicker the mass drops, the quicker the reaction
-if you take measurements at regular intervals, you can plot rate if reaction and find rate easily
-this is the most accurate
Seeing rate of reaction based off volume of gas given off
-uses a gas syringe to measure gas given off
-more gas given off in a given time interval, the faster the reaction
Magnesium and HCL reaction experiment
- Add set volume of dilute HCL to conical flask and place on mass balance
- Add magnesium ribbon to acid and quickly plug the flask with cotton wool
- Start stopwatch and record mass on balance at regular intervals
- Plot graph to get rate of reaction used or
Sodium Thiosulfate and HCL reaction experiment
- They’re both clear solutions but they react together to produce a yellow precipitate of sulfur
- Add a set volume of dilute sodium thiosulfate to conical flask
- Place flask on piece of paper with black cross on it
- Add dilute HCL to flask and start a stopwatch
- Time how long it takes for black cross to disappear
- The shorter the time, the faster the reaction
- The higher the concentration, the quicker the reaction
How to find mean rate of reaction
Change in y / total time taken for the reaction
How to find rate of reaction at a specific point
Find gradient of tangent at that point