The rate and extent of chemical change Flashcards

1
Q

what are the 2 ways of measuring rate of reaction?

A

how fast reactants are used up OR how fast products are being formed

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2
Q

what are the equations for average rate of reaction?

A

quantity of products formed/ time OR quantity of reactants used/ time

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3
Q

what are the factors affecting rate of reaction?

A

temp, concentration/ pressure, surface area, catalyst.

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4
Q

what is collision theory?

A

in order for particles to react, they have to collide with each other with sufficient energy.

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5
Q

what does the rate of collision theory depend on?

A

amount of energy particles have and the frequency of collisions.

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6
Q

why does rate of reaction increase if energy particles have is higher?

A

they have more energy to transfer during collisions.

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7
Q

why is frequency of collisions important for collision theory?

A

the particles will collide more so there will be more successful collisions.

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8
Q

how does temperature increase rate of reaction?

A

as temp increases particles gain more energy which means they move faster, so they collide more frequently. they will also collide with more energy. higher rate of successful collisions

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9
Q

how does increased concentration/ pressure increase rate of reaction?

A

more particles per unit of volume means collisions will be more frequent. this means increased successful collisions

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10
Q

how does increasing the surface area (to volume ratio) increase the rate of reaction?

A

much higher area where collisions can take place meaning collisions frequency would increase.

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11
Q

what is a catalyst?

A

substances that speed up a reaction but are not used up in the reaction themselves.

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12
Q

how does a catalyst increase the rate of reactions?

A

creates an alternative reaction pathway with a smaller activation energy, meaning a higher proportion of successful collisions.

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13
Q

what are the most common catalysts?

A

transition metals (e.g. cobalt and nickel) and enzymes.

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14
Q

what is the equilibrium of reversible reactions?

A

concentrations of reactants used up and products won’t change anymore SO both reactions are still happening but they cancel each other out

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15
Q

how does the position of equilibrium change?

A

when there are more products the equilibrium lies to the right but more reactants and less products it lies to the left.

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16
Q

how does adding heat change the equilibrium?

A

it encourages the forward reaction meaning we will have more products. this means the position of equilibrium will move to the right.

17
Q

what is a closed system?

A

a sealed environment from which none of the reactants or products can escape.

18
Q

are reversible reactions endothermic or exothermic?

A

they are exothermic one way and endothermic the other way.

19
Q

what is le chatelier principle?

A

change in conditions of a reversible reaction then the position of equilibrium will shift to try to counteract the change

20
Q

what 3 factors affect position of equilibrium?

A

temp, concentration and pressure.

21
Q

if there is an increase in pressure which side will the equilibrium move to?

A

smaller number of gas molecules