The rate and extent of chemical change Flashcards

1
Q

How can you calculate the rate of reaction?

A

Rate of reaction = amount of reactant used
————————————-
Time

Rate of reaction = amount of product formed
————————————–
Time

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2
Q

What factors affect the rates of chemical reactions?

A

o concentration
o pressure
o surface area
o temperature
o catalysts

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3
Q

What is collision theory?

A

chemical reactions can occur only when reacting particles collide with each other and with sufficient energy.

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4
Q

What is activation energy?

A

The minimum amount of energy that particles must have to react.

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5
Q

What will happen in a chemical reaction if you increase the concentration?

A

Increasing the concentration of reactants in solution, the pressure of reacting gases, and the surface area of solid reactants increases the frequency of
collisions and so increases the rate of reaction.

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6
Q

What will happen in a chemical reaction if you increase the temperature?

A

Increasing the temperature increases the frequency of collisions and makes the collisions more energetic, and so increases the rate of reaction.

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7
Q

What are catalysts?

A

Catalysts are substances that speed up chemical reactions without being changed or used up during the reaction.

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8
Q

What acts a catalysts?

A

Enzymes act as catalysts in biological systems.

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9
Q

How do catalysts speed up the reaction?

A

● Catalysts decrease the activation energy;
this increases the proportion of particles with
energy to react.
● Catalysts provide a different pathway for a
chemical reaction that has a lower activation
energy.

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10
Q

How does the surface area affect the rate of reaction?

A

1) Small pieces of a solid reactant have a large surface area in relation to their volume.
2) More particles are exposed and available for collisions, so there are more collisions and a faster reaction.

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11
Q

What is the sample of the practical of the rate of reaction?

A

MAKE A SKETCH OF THE PRACTICAL FIRST

1) Set up the equipment as shown.
2) Add the hydrochloric acid to the flask and swirl to mix the reactants.
3) Start the timer.
4) Watch the cross through the flask.
5) When the cross is no longer visible stop the timer.
6) Repeat the experiment using hydrochloric acid of a different concentration.

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12
Q

What are the variable for this practical?

A

Independent variable - Concentration of the acid
Dependent variable - The time it takes for the cross to disappear
Control variable - Volume of the acid

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13
Q

When does a reversible reaction occur?

A

When the products of the reaction can react to produce the original reactants.

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14
Q

how can the direction of the reversible reactions be changed?

A

The direction of reversible reactions can be changed by changing the conditions.

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15
Q

When does the same amount of energy be transferred in each case?

A

If a reversible reaction is exothermic in one direction, it is endothermic in the opposite direction. The same amount of energy is transferred in each case.

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16
Q

How do you calculate the concentration of a reactant?

A

Concentration = Mol : Volume (dm^3)

17
Q

What happens to the reactants as the reaction progresses?

A

The reactant gets used up so the amount of reactant decreases.

18
Q

What happens in a closed system?

A

No reactants are added and no products are removed.

19
Q

What happens when a reversible reaction occurs in a closed system?

A

An equilibrium is achieved When the rate of the forward reaction is equal to the rate of the backward reaction.

20
Q

What is Le Chatelier’s Principle?

A

If a system is at equilibrium and a change is made to the conditions, then the system responds to counteract the change.

21
Q

What is the effect on the equilibrium if the concentration of one of the products or reactants is changed?

A

*If the concentration of one of the reactants or products is changed,
the system is no longer at equilibrium and the concentrations of all
the substances will change until equilibrium is reached again.

*If the concentration of a reactant is increased, more products will be
formed until equilibrium is reached again.

*If the concentration of a product is decreased, more reactants will
react until equilibrium is reached again

22
Q

What is the effect on the equilibrium if the temperature is increased?

A
  • The relative amount of products at equilibrium increases for an
    endothermic reaction.
  • The relative amount of products at equilibrium decreases for
    an exothermic reaction.
23
Q

What is the effect on the equilibrium if the temperature decreases?

A

The relative amount of products at equilibrium decreases for
an endothermic reaction

The relative amount of products at equilibrium increases for an
exothermic reaction.

24
Q

What happens to the equilibrium if we increase the pressure in gaseous
reactions?

A

An increase in pressure causes the equilibrium position to shift towards the side with the smaller number of molecules as shown by the symbol equation for that reaction.

25
Q

hat happens to the equilibrium if we increase the pressure in gaseous reactions?

A

A decrease in pressure causes the equilibrium position to shift towards the side with the larger number of molecules as shown by the symbol equation for that reaction.