The Rate and Extent of Chemical Change Flashcards

1
Q

How can you calculate the mean rate of reaction?

A

(amount of reactant used) / (time taken)

amount of product formed) / (time taken

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2
Q

How can the concentration of the reactant be calculated?

A

(amount - mol) / (volume of the reaction mixture - dm^2)

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3
Q

How might one measure the amount of reactants used if one of the products is a gas?

A

Measure the mass of the reaction mixture before and after the reaction takes place.

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4
Q

How might one measure the amount of product if the product is a gas?

A

Use a gas syringe and measure the time taken for the reaction to happen.

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5
Q

When do chemical reactions only occur?

A

When reacting particles collide with each other with sufficient energy.

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6
Q

What is activation energy?

A

The minimum amount of energy required to cause a reaction.

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7
Q

What factors affect the rate of reaction?

A

Temperature, concentration, surface area and catalysts,

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8
Q

On a graph showing the rate of reaction, what happens when the line falls flat?

A

One of the reactants has been used up.

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9
Q

How might one find the rate of reaction at a particular time on a rate of reaction graph?

A

By doing the tangent thing.

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10
Q

What is a catalyst?

A

A substance that increases the rate of chemical reaction without being used up in the process.

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11
Q

What does a catalyst do?

A

Reduces the amount of energy needed for a successful collision.
Provides a surface for molecules to attach to, which increases their chances of bumping into each eachother.

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12
Q

When do enzymes act as catalysts?

A

In biological systems.

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13
Q

What are examples of reactions that need different catalysts?

A

Cracking hydrocarbons uses broken pottery.

The manufacture of ammonia uses iron.

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14
Q

What happens in a reversible reaction?

A

The products can react to produce the original reactants.

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15
Q

What are examples of reversible reactions?

A

Solid ammonium chloride decomposes when heated to produce ammonia and hydrogen chloride. Ammonia reacts with hydrogen chloride gas to produce clouds of white ammonium chloride.

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16
Q

How might the direction of reversible reactions be changed?

A

By changing the conditions.

17
Q

What happens in a closed system?

A

No reactants are added and no products are removed.

18
Q

What is equilibrium?

A

When, in a closed system, a reversible reaction is achieved; the rate of forward reaction is the same as the rate of backwards reaction.

19
Q

What is Le Chatelier’s Principle?

A

If a system in equilibrium is subjected to a change in conditions, then the system shifts to resist the change.

20
Q

What happens to the yield in an exothermic reaction if the temperature is raised?

A

It decreases.

21
Q

What happens in an endothermic reaction if the temperature is raised?

A

The yield increases.

22
Q

What happens in an exothermic reaction if the temperature is lowered?

A

The yield increases.

23
Q

In reversible reactions involving gas, what happens if there is an increase of pressure?

A

The reaction that produces the least number of gas molecules is favoured.

24
Q

What happens if the concentration of one of the products or reactants is changed in a reversible reaction?

A

The system is no longer in equilibrium - and then adjusts so it is equilibrium one more (which abides to Le Chatelier’s Principle).