The production of ethanol Flashcards
to become... epic
What are the conditions needed to make ethanol with fermentation?
- Yeast
- 35°C
- No air
- Aqueous
Why is yeast needed? Give an equation in your answer.
Yeast provides enzymes that catalyse anaerobic respiration (the breakdown of sugar).
C6H12O6(aq) -> 2C2H5OH(aq) +2CO2(g)
Why is a temperature of 35°C chosen?
The temperature needs to be as high as possible to maximise the rate of reaction but if it is too high then the enzymes in yeast are denatured.
Why is air kept out of the fermentation process?
To prevent the oxidation of ethanol to ethanoic acid.
When does the fermentation process stop and why?
When the percentage of ethanol reaches 15% as then the enzymes do not work properly.
How is ethanol extracted after the fermentation process is complete?
Distillation
What are the advantages of the fermentation process over making ethanol from crude oil? (Give two)
- The process can be done with cheap, simple equipment.
- Sugar is a renewable resource
What are the disadvantages of the fermentation process over making ethanol from crude oil? (Give three)
- Fermentation is done in a batch process which needs more manpower and is slow
- Ethanol made is not pure
- Depletes land used for growing food crops
What is the word equation for fermentation?
glucose -> ethanol + carbon dioxide
How is ethene used for the production of ethanol obtained?
The cracking of fractions from crude oil
What kind of reaction happens when ethanol is made from ethene? Give an equation.
Addition/hydration
CH2=CH2 + H2O -> CH3CH2OH
What is the conditions for the hydration of ethene?
- High temperature 300°C
- High pressure 70atm
- H3PO4 catalyst
What are the advantages of producing ethanol via the hydration of ethene over fermentation? (Give three)
- Faster reaction
- More pure products
- Continuous process
What are some disadvantages of producing ethanol via the hydration of ethene over fermentation? (Give three)
- High technology equipment needed
- Ethene is a non-renewable resource
- High energy costs to reach high pressures (70atm)
What is the mechanism for the hydration of ethene.