the equilibrium constant- Kc Flashcards

1
Q

what is the Kc equation?

A

concentration of products / concentration of reactants

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2
Q

what does it mean if Kc is higher than 1?

A

there is a higher product concentration than reactant concentration so equilibrium lies to the right (products)

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3
Q

what does it mean if Kc is lower than 1?

A

there is a higher reactant concentration than product concentration so equilibrium lies to the left (reactants)

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4
Q

why do we need to be careful with heterogenous reactions in the Kc equation?

A

liquid/solid concentrations remain constant so are left out of the equation

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5
Q

what do you do if a Kc calculation gives you the equilibrium concentrations?

A

substitute into the equation

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6
Q

what do you do if a Kc calculation gives you the equilibrium moles and the volume?

A

moles / volume to work out concentrations
then substitute into equation

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7
Q

what do you do if a Kc calculation gives you the initial moles and equilibrium moles of either a product or reactant?

A

use an ICE table

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8
Q

describe how an ICE table works

A
  1. use equilibrium moles and 0 initial moles to work out change
  2. use this to work out the change of the other products/reactants (remember to divide / multiply based on big numbers)
  3. use changes to work out all moles at equilibrium
  4. moles / volume to work out concentrations
  5. substitute into equation
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9
Q

what factor affects the value of Kc?

A

temperature

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10
Q

what happens to the value of Kc if temperature is increased in an EXOTHERMIC reaction? why?

A

decreases
- concentrations need to change to establish a lower equilibrium
- products decrease, reactants increase
- equilibrium shifts left (in endothermic direction)

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11
Q

what happens to the value of Kc if temperature is increased in an ENDOTHERMIC reaction? why?

A

increases
- concentrations need to change to establish a higher equilibrium
- products increase, reactants decrease
- equilibrium shifts right (in endothermic direction)

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12
Q

what happens to the POSITION OF EQUILIBRIUM if the concentration of reactants increases?

A

shifts right
- increases product conc
- decreases reactant conc

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13
Q

what happens to the POSITION OF EQUILIBRIUM if the concentration of products increases?

A

shifts left
- decreases product conc
- increases reactant conc

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