the equilibrium constant- Kc Flashcards
what is the Kc equation?
concentration of products / concentration of reactants
what does it mean if Kc is higher than 1?
there is a higher product concentration than reactant concentration so equilibrium lies to the right (products)
what does it mean if Kc is lower than 1?
there is a higher reactant concentration than product concentration so equilibrium lies to the left (reactants)
why do we need to be careful with heterogenous reactions in the Kc equation?
liquid/solid concentrations remain constant so are left out of the equation
what do you do if a Kc calculation gives you the equilibrium concentrations?
substitute into the equation
what do you do if a Kc calculation gives you the equilibrium moles and the volume?
moles / volume to work out concentrations
then substitute into equation
what do you do if a Kc calculation gives you the initial moles and equilibrium moles of either a product or reactant?
use an ICE table
describe how an ICE table works
- use equilibrium moles and 0 initial moles to work out change
- use this to work out the change of the other products/reactants (remember to divide / multiply based on big numbers)
- use changes to work out all moles at equilibrium
- moles / volume to work out concentrations
- substitute into equation
what factor affects the value of Kc?
temperature
what happens to the value of Kc if temperature is increased in an EXOTHERMIC reaction? why?
decreases
- concentrations need to change to establish a lower equilibrium
- products decrease, reactants increase
- equilibrium shifts left (in endothermic direction)
what happens to the value of Kc if temperature is increased in an ENDOTHERMIC reaction? why?
increases
- concentrations need to change to establish a higher equilibrium
- products increase, reactants decrease
- equilibrium shifts right (in endothermic direction)
what happens to the POSITION OF EQUILIBRIUM if the concentration of reactants increases?
shifts right
- increases product conc
- decreases reactant conc
what happens to the POSITION OF EQUILIBRIUM if the concentration of products increases?
shifts left
- decreases product conc
- increases reactant conc