The effect of changes in conditions on equilibrium composition Flashcards

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1
Q

as long as the conditions stay the same, the composition of the reaction mixture will ………………..once equilibrium has been reached

A

not change

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2
Q

when a change in condition is made, then we are said to be

A

changing the position of equilibrium

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3
Q

we can change conditions by: (4 catalysts)

A
  • adding or removing a component
  • changing the temperature
  • changing the pressure
  • using a catalyst
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4
Q

if we increase the concentration of one of the reactants in a system in equilibrium, the rate of the forward reaction will………………..and more………………………………..

A

increase and more products will form

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5
Q

as the concentration of the products increase, the rate of the backwards reaction also increases and eventually a new…………………..is established

A

a new equilibrium

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6
Q

if the concentration of a reactant is increased, then the position of equilibrium will shift

A

to the right

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7
Q

if the concentration of a reactant is decreased then the position of equilibrium shifts

A

left

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8
Q

if you increase the concentration of a product in a system in equilibrium, then the equilibrium shifts

A

left

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9
Q

if the concentration of a product is decreased, the equilibrium shifts

A

right

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10
Q

the effect of changing pressure only affects ……………reaction involving……………..

A

reversible reactions involving gases

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11
Q

at a given temperature, the pressure of a gaseous mixture depends solely on

A

the number of gas molecules in a given volume

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12
Q

the pressure of a gaseous can be changed by: (4 items)

A
  • increasing the volume
  • decreasing the volume
  • increasing the number of gas molecules (more moles)
  • decreasing the number of gas molecules (fewer moles)
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13
Q

the effect of changing pressure can be studies using

A

a gas syringe

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14
Q

if the number of moles of reactant per given volume is greater and the pressure is increased, and the number of moles of product is less, then the position of equilibrium shifts to the

A

right

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15
Q

if the number of moles of reactant per given volume is less and the pressure is increased, and the number of moles of product is greater, then the position of equilibrium shifts to the

A

left

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16
Q

if the number of moles of reactant per given volume is greater and the pressure is decreased, and the number of moles of product is less, then the position of equilibrium shifts to the

A

left

17
Q

if the number of moles of reactant per given volume is less and the pressure is decreased, and the number of moles of product is greater, then the position of equilibrium shifts to the

A

right

18
Q

if the pressure for the following reaction is increased, then the equilibrium shifts to the…………
N2 + 3H2 ⇌ 2NH3

A

right so more ammonia is produced

19
Q

if the temperature of an equilibrium mixture is raised, then

A

the rates of both the forward and the backward reactions will increase

20
Q

if temperature is increased, the rate of the endothermic reaction will be………………..than the increase in the rate of the exothermic reaction

A

greater

21
Q

when the temperature is increased, and the forward reaction is exothermic, the equilibrium change is to the

A

left

22
Q

when the temperature is decreased, and the forward reaction is exothermic, the equilibrium change is to the

A

right

23
Q

when the temperature is increased, and the forward reaction is endothermic, the equilibrium change is to the

A

right

24
Q

when the temperature is decreased, and the forward reaction is endothermic, the equilibrium change is to the

A

left

25
Q

if a catalyst is added to a reaction mixture that is in equilibrium, the rate of

A

both the forward and backward reactions will increase

26
Q

when adding a catalyst the increase in rate is

A

the SAME for both reactions, the position of equilibrium is not altered

27
Q

adding a catalyst at the beginning of a reaction will reduce the time needed to establish

A

equilibrium