The atmosphere Flashcards
Troposphere (general)
15km: N2, O2, CO2, Ar, H20: molecules & breathing
Stratosphere (general)
50km: N2, O2, O3: ozone
Mesosphere (general)
85km: N2, O2, N2+, O2+, NO, NO+: meteor
Thermosphere (general)
600km: N2, O2, N2+, O2+, N+, O+, NO+, N, O: satellite, shuttle, space station, northern lights
At high altitudes N2 and O2 are subject to
high energy and UV light
Dissociation in Thermosphere reactivity involves:
Breaking O2 bonds with <240nm and breaking N2 bonds with <126nm
Ionization in Thermosphere reactivity involves:
taking Os and deionizing one (Os = <91nm & Ns = <80nm) with 1310KJ/mols remaining
Photochemical Rxn:
It is when a reaction takes a substance into an excited states to help processes occur
Free Radicals in Upper atmosphere help with:
Reactions
How are radicals made?
By the photochemical reactions
Free Radicals - Abstract
The radical attacks the H atom and cleaves it form a molecule
Free Radicals - Fragment
The radical will attack it’s own bond and cleave itself from the molecule
Free Radicals - Multiple Bonds
The Radical will cleave a double bonded atom and attach itself to the molecule
Free Radicals - Recombine/Coupling
Two radicals reacting and combining to create a fully formed molecule
4 steps of a Hydroxy Radical
- Photochemical: making radical
- Making Ozone: O radical + O2
- Excited State: Adding UV/light
- Radical Formation: Remake initial Radical