Tests + Synthetic Routes Flashcards
Test for Alkenes
Add bromine water
Orange to colourless if positive
Test for Haloalkanes
Add silver nitrate
Chloroalkane - white
Bromoalkane - cream
Iodoalkane - Yellow
Test for Phenols
Add sodium hydroxide to test for acid
solid dissolves and colourless sodium salt forms
Add sodium carbonate to test for strong acid
Phenol is a weak acid so nothing happens
Test for Carboxylic acid
Add sodium carbonate
Fizzes (CO2) and turns cloudy (limestone)
Test for Carbonyl groups
Dissolve 2-4 DNP in sulfuric acid, water and methanol
Add solution to unknown
Orange precipitate forms
What are the Carbonyl groups
Ketone and aldehyde
Test for Aldehyde
Test for carbonyl group
If positive add Tollen’s reagent
Silver mirror forms
How to make Tollen’s reagent
silver nitrate solution with sodium hydroxide forms a brown precipitate
Add dilute ammonia solution until brown precipitate fully dissolves
Test for Ketone
Test for carbonyl group
Is positive add Tollen’s reagent
Nothing happens
Test for Primary alcohol
Add acidified potassium dichromate
Turns green
Add Tollen’s reagent - positive
Test for Secondary alcohol
Add acidified potassium dichromate
Turns green
Add Tollen’s reagent - negative
What can alkenes reactions form
Alkanes
Dihaloalkanes
Haloalkanes
Alcohols
What can alkanes reactions form
Haloalkanes
Reactants needed for Alkane to Haloalkane
X2 + UV light
Reactants needed for alkene to alkane
H2 + nickle catalyst + 150c
Reactants needed for alkene to dihaloalkane
X2 + 20c
Reactants needed for alkene to haloalkene
HX + 20c
Reactants needed for alkene to alcohol
Steam + Phosphoric acid (H3PO4) catalyst + 300c
What can alcohols reactions form
Alkenes Esters Aldehyde Ketone Haloalkane
What can Haloalkane reactions form
Alcohols
Amines
Nitrile
What can Ester reactions form
Alcohols
Carboxylic acids
What can aldehyde reactions form
Carboxylic acids
Hydroxynitrile
What can ketone reactions form
Hydroxynitrile
What can Hydroxynitrile reactions form
Amines
Carboxylic acids
What can Nitrile reactions form
Amine
Carboxylic acids
What can Carboxylic acids reactions form
Esters
Acyl chloride
What can Acyl Chloride reactions form
Carboxylic acids
Primary amides
Secondary amides
Reactants needed for Alcohol to alkene
Conc sulfuric acid + 170c
Reactants needed for Alcohol to ester
Carboxylic acid + acid catalyst + heat
Or Acyl Chloride
Reactants needed for Primary alcohol to aldehyde
Acidified Potassium Dichromate + sulfuric acid + distilled
Reactants needed for Secondary alcohol to ketone
Acidified Potassium Dichromate + sulfuric acid + reflux
Reactants needed for Alcohol to Haloalkane
NaX + sulfuric acid + 20c
Reactants needed for Haloalkane to alcohol
NaOH + water + under reflux
Reactants needed for Haloalkane to amine
Excess ethanolic ammonia
Reactants needed for Haloalkane to nitrile
NaCN + ethanol + under reflux
Reactants needed for Ester to alcohol
Dilute acid/alkali + under reflux
Reactants needed for Ester to carboxylic acids
Dilute acid/alkali + under reflux
Reactants needed for Aldehyde to carboxylic acid
Acidified Potassium Dichromate + sulfuric acid + under reflux
Reactants needed for aldehyde to hydroxnitrile
HCN
Reactants needed for Ketone to Hydroxynitrile
HCN
Reactants needed for Hydroxynitrile to amine
LiAlH4 + dilute acid
Or
Na + ethanol + reflux
Reactants needed for Hydroxynitrile to carboxylic acid
Dilute HCl + reflux
Reactants needed for Nitrile to amine
LiAlH4 + dilute acid
Or
Na + ethanol + reflux
Reactants needed for Nitrile to carboxylic acid
Dilute HCl + reflux
Reactants needed for Carboxylic acid to ester
Alcohol + acid catalyst + heat
Reactants needed for Carboxylic acid to Acyl Chloride
SOCl2
Reactants needed for Acyl Chloride to Carboxylic acid
Cold water
Reactants needed for Acyl Chloride to Primary amide
Ammonia + 20c
Reactants needed for Acyl Chloride to Secondary Amide
Amine + 20c