Tests for ions Flashcards
Test for Carbonates
react with dilute acid (nitric)
positive= bubbles of gas produced (CO2)
COULD: bubble gas produced through limewater: goes cloudy
Test for sulfates
Barium nitrate
Positive: formation of white precipitate
avoid using barium chloride to administer barium
what type of reaction is the test for sulfates
precipitation reaction: precipitate formed from reaction between 2 solutions
Test for halide ions
Silver nitrate to form a precipitate:
Cl= white, soluble in dilute NH3
Br= Cream, soluble in concentrated NH3
I= yellow, INsoluble in NH3
Add NH3 to distinguish between similar colours
Order of testing for negative ions
- Carbonate
- Sulfate
- Halides
Why can we test for sulfates before carbonate
Carbonate ions -if present- react with barium nitrate to form white barium carbonate precipitate: masks
why cant we test for halides before sulfates or carbonates
bc sulfate/carbonate ions react with silver nitrate to give white precipitates: masks
Test for NH4+ ions
Add aqueous NaOH and heat gently, should release ammonia gas
Test gas released with moist pH paper, should turn blue
What colour with NH3 gas turn moist pH paper
blue bc it is alkaline
why must the ammonium solution be heated gently
bc the ammonia gas produced is very soluble so would not bubble out and rather dissolve in the solution if heated vigorously