Chapter 9 Bond enthalpies Flashcards
Average bond enthalpy?
The energy required to break one mole of a specified type of bond in a gaseous molecule
what does AVERAGE bond enthalpy describe in comparison to just bond enthalpy
Actual bond enthalpy can vary depending on the chemical environment of the bond:
The same bond can have several bond enthalpies in different compounds,
So a mean can be taken
Is bond breaking endo or exothermic + pos or neg enthalpy
endothermic, positive bond enthalpy
Is bond making exo or endothermic + pos or neg enthalpy
exothermic so enthalpy is neg
What is the overall enthalpy change of a reaction in relation to
Difference in the energy required to break the binds in the reactants vs energy released from making the bonds in the products
Equation for overall enthalpy change of a reaction
sum of bond enthalpies in reactants - sum of bond enthalpies in products
Limitations of using average bond enthalpies in calculation
They are averages not the actual
All species are gaseous, not under standard conditions