Testing For Ions Flashcards
Method for testing for CARBONATE ions
- Add equal amounts of HCl and NaCO3 to a tests tube
- Add bung with delivery tube to a test tube
- Delivery tube is connected to test tube with limewater (CaOH)
- CO3(2-) ions react with H+ ions to produce CO2 gas
- CO2 causes limewater to be milky
Method for testing for SULFATE ions
- Add HCl then add BaCl to sample
- BaSO4 will form (white precipitate)
Sulfate Ion
SO4(2-)
Carbonate ion
CO3(2-)
Halide ions
X(-)
Method for testing for HALIDE ions
- Add sample to a test tube.
- Add HNO3 to test tube then add AgNO3
Colours of precipitate of HALIDE test
No precipitate = AgF
White = AgCl
Cream = AgBr
Yellow = AgI
Natural state/colour of CHLORINE at room tempertature
- Gas
- Green
Natural state/colour of FLUORINE at room tempertature?
- Gas
- Yellow
Natural state/colour of BROMINE at room tempertature?
- Liquid
- Brown/Red
Natural state/colour of IODINE at room tempertature?
- Solid
- Grey/Black (shiny)
Method for testing for AMMONIUM IONS
- Add 10 drops of sample to test tube
- Add 10 drops of NaOH to test tube and mix/swirl
- Place the test tube in a water bath and heated gently
- Hold damp red litmus paper near mouth of test tube
- Ammonia gas is produced which causes the red litmus paper to turn blue.
Colour of CHLORINE in WATER and CYCLOHEXANE
Pale Green
Colour of BROMINE in WATER and CYCLOHEXANE
Orange
Colour of IODINE in WATER
Brown
Colour of IODINE in CYCLOHEXANE
Violet
Is ammonia gas (NH3) alkaline or acidic?
Alkaline
Observations of further CHLORIDE test with AMMONIA
White precipitate (AgCl) dissolves in dilute ammonia solution
Observations of further BROMIDE test with AMMONIA
- Cream precipitate (AgBr) is insoluble in dilute ammonia solution
- Dissolves in conc. ammonia solution
Observations of further IODIDE test with AMMONIA
- Yellow precipitate (AgI) is insoluble in dilute ammonia solution AND in conc. ammonia solution
Method of further halide test with AMMONIA
- Add dilute ammonia solution to metal halide solution
- Then add concerntrated ammonia solution
Why is ACID added for the HALIDE test?
- To remove any presence of CO3(2-)
- False positive result of a white ppt of Ag2CO3
would have been formed
Why is HNO3 used as an ACID in the HALIDE?
- HCl contains Cl(-)n ions
- False positive of result of a
white ppt of AgCl - H2SO4 contains SO4(2-) ions
- False positive of result of a
white ppt of Ag2SO4
Ionic Equation for test for AMMONIUM IONS
NH4+ (aq) + OH- (aq) 🡪 NH3 (g) + H2O (l)