test for negative ions Flashcards
What happens to the carbon dioxide in limewater?
It reacts with calcium hydroxide to form a white precipitate of calcium carbonate, which turns the limewater cloudy
How can an unknown compound be tested to see if it has a halide (chloride, bromide or iodide) in it?
First dilute nitric acid is added, and then silver nitrate is added too. If a precipitate forms, there are halide ions present
Why is the nitric acid added before the silver nitrate solution?
It dissolves the compound and removes any carbonate ions, which would interfere with the test by forming a precipitate with the silver ions
In a test for halides, what colour is the precipitate formed for chloride (Cl-) ions?
White
In a test for halides, what colour is the precipitate formed for bromide (Br-) ions?
Cream
In a test for halides, what colour is the precipitate formed for iodide (I-) ions?
Pale yellow
What is the general ionic equation with the test for a carbonate?
2H^+(aq) + CO3^2-(s) —> CO2(g) + H2O(l)
What is the general ionic equation with the test for a halide?
Ag^+(aq) + X^-(aq) —> AgX(s)
How is it possible to test a unknown substance for a carbonate?
If dilute hydrochloric acidic is added to a carbonate, it fizzes and produces carbon dioxide gas
What substances are formed when a negative ion reacts with dilute hydrochloric acid in a test for carbonates?
A metal chloride, water and carbon dioxide
What substances are formed when a negative ion reacts with silver nitrate solution in a test for halides?
A metal nitrate and a silver halide
What substances are formed when a negative ion reacts with barium chloride solution in a test for sulfates?
A metal chloride and barium sulfate
How can a compound be tested for containing sulfate ions?
By adding dilute hydrochloric acid, followed by barium chloride solution
Why is dilute hydrochloric acid added before the barium sulfate solution?
To remove the carbonate ions that would form a precipitate with the barium ions
What forms when sulfate ions are present?
A white precipitate