test for negative ions Flashcards

1
Q

What happens to the carbon dioxide in limewater?

A

It reacts with calcium hydroxide to form a white precipitate of calcium carbonate, which turns the limewater cloudy

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2
Q

How can an unknown compound be tested to see if it has a halide (chloride, bromide or iodide) in it?

A

First dilute nitric acid is added, and then silver nitrate is added too. If a precipitate forms, there are halide ions present

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3
Q

Why is the nitric acid added before the silver nitrate solution?

A

It dissolves the compound and removes any carbonate ions, which would interfere with the test by forming a precipitate with the silver ions

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4
Q

In a test for halides, what colour is the precipitate formed for chloride (Cl-) ions?

A

White

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5
Q

In a test for halides, what colour is the precipitate formed for bromide (Br-) ions?

A

Cream

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6
Q

In a test for halides, what colour is the precipitate formed for iodide (I-) ions?

A

Pale yellow

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7
Q

What is the general ionic equation with the test for a carbonate?

A

2H^+(aq) + CO3^2-(s) —> CO2(g) + H2O(l)

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8
Q

What is the general ionic equation with the test for a halide?

A

Ag^+(aq) + X^-(aq) —> AgX(s)

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9
Q

How is it possible to test a unknown substance for a carbonate?

A

If dilute hydrochloric acidic is added to a carbonate, it fizzes and produces carbon dioxide gas

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10
Q

What substances are formed when a negative ion reacts with dilute hydrochloric acid in a test for carbonates?

A

A metal chloride, water and carbon dioxide

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11
Q

What substances are formed when a negative ion reacts with silver nitrate solution in a test for halides?

A

A metal nitrate and a silver halide

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12
Q

What substances are formed when a negative ion reacts with barium chloride solution in a test for sulfates?

A

A metal chloride and barium sulfate

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13
Q

How can a compound be tested for containing sulfate ions?

A

By adding dilute hydrochloric acid, followed by barium chloride solution

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14
Q

Why is dilute hydrochloric acid added before the barium sulfate solution?

A

To remove the carbonate ions that would form a precipitate with the barium ions

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15
Q

What forms when sulfate ions are present?

A

A white precipitate

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16
Q

What is the white precipitate formed in the test for sulfate ions when they are present?

A

Barium sulfate (BaSO4), which is an insoluble salt

17
Q

What is the general ionic equation with the test for a sulfate?

A

Ba^2+(aq) + SO4^2-(aq) —> BaSO4(s)