Test For Cations Flashcards

Learn about the respective tests for each cation.

1
Q

What is the chemical equation for the reaction that occurs when testing for ammonium ions?

A

NH4+(aq) + OH-(aq)&raquo_space;> NH3 (g) + H20(l)

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1
Q

What is the first step in the test of ammonium ions?

A

Aqueous NaOH is added to ammonium ion solution.

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2
Q

What is second step in the test for ammonium ions?

A

Ammonia gas produced.

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3
Q

What is the third step in the test for ammonium ions?

A

Warm the mixture, to allow the release of the ammonia gas.

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4
Q

What is the final step in the test for ammonium ions?

A

Use moist pH indicator paper, and as ammonia is alkali, it’s presence will turn the paper blue.

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5
Q

What is the chemical equation for the reaction that occurs when testing for carbonate ions?

A

Na2CO3(aq) + 2HNO3(aq)&raquo_space;> 2NaNO3(aq) + CO2(g) +

H20(l)

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6
Q

What is step one in the test for carbonate ions?

A

In a test tube, add dilute HNO3 to the solid or solution to be tested.

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7
Q

What is step two in the test for carbonate ions?

A

If you see bubbles, the unknown compound could be a carbonate.

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8
Q

What is step three in the test for carbonate ions?

A

To prove that the gas produced is CO2:

  • bubble gas through limewater (saturated aqueous solution of calcium hydroxide Ca(OH)2
  • white precipitate formed, turns lime water cloudy
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9
Q

What is the chemical equation for the reaction between CO2 and limewater?

A

CO2(g) + Ca(OH)2(aq)&raquo_space;> CaCO3(s) +H2O(l)

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10
Q

What sulfate compound is very insoluble?

A

Barium Sulfate (BaSO4)

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11
Q

What is the ionic equation between Ba2+ ions and a solution of SO4(2-)?

A

Ba2+(aq) + SO4(2-)(aq)&raquo_space;> BaSO4(s)

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12
Q

What is the chemical equation for the reaction between silver and any halide ion?

A

Ag+(aq) + X-(aq)&raquo_space;> AgX(s)

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13
Q

What is step one in the test for halide ions?

A

Add aqueous silver nitrate AgNO3 to an aqueous solution of a halide.

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14
Q

What is step two of the test for halide ions ?

A

Identifying the formed precipitates colour:
Silver Chloride - White
Silver Bromide - Cream
Silver Iodide - Yellow

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15
Q

What is the final step in the test for halide ions?

A

Add aqueous ammonia to test solubility of precipitate, this stage is very useful because the three precipitate colours can be difficult to tell apart.