TEST 2 RXNS Flashcards by Brooke Birdwell

Q

ketone. NH3, H+

A

imine

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Q

ketone. NHR2, H+

A

enamine

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Q

alkene and ketone. H2, Pd

A

alkane and alcohol

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Q

ketone. 1. LiALH4, heat 2. H3O+

A

alcohol

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Q

ketone and alkene. H2, Rh

A

ketone and alkene

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Q

ketone. Zn(Hg), HCl - clemmenson

A

alkane

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Q

ketone. H2NNH2, diol - wolff

A

alkane

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Q

alcohol and aldehyde. K2Cr2O7, H2SO4, H2O

A

carb acid and carb acid

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Q

alcohol and aldehyde. HCLO2.

A

alcohol and carb acid

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Q

ketone. Br2, CH3COOH

A

ketone with one Br added on alpha H

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Q

ketone. Br2/KOH

A

ketone and Br added on all alpha Hs

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Q

ketone. 1. Br2, NaOH, H20 2. H3O+

A

carb acid

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Q

carb acid. MeOH, H+

A

ester (fischer)

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Q

ketone and carb acid (beta ketoacid). NaBH4, ROH/ H2, Pd

A

ketone to alcohol, carb acid stays

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Q

carb acid. SOCL2

A

acid chloride

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Q

ketone and carb acid (beta ketoacid). heat

A

ketone and CO2

Q

duel ended carb acids. heat

A

carb acid and CO2

Q

acid chloride. H2O

A

carb acid

Q

anhydride. H2O

A

two carb acids

Q

ester. H2O/ NaOH

A

deprotonated carb acid and alcohol ion

Q

amide. H2O, heat / NaOH

A

deprotonated carb. acid

Q

nitrile. HCl, heat/ H2O

A

carb acid

Q

nitrile. H2O, heat/ NaOH

A

deprotonated carb acid

Q

acid chloride. EtOH/ Py

A

ester

anhydride. ROH

ester and carb acid

anhydride. 2 equ. NH2R

amide

acid chloride. 2 equ. NH2R

amide

ester. 2 equ. NH2R

amide

acid chloride. 1. 2 equ. RMgBr 2. H3O+

alcohol + 2 grignard groups

acid chloride. 1. (R)2 CuLi 2. H2O

1 equ. of R from gilman

ester. 1. LAH 2. H3O+

alcohol

ester. 1.DIBALH 2. H3O+

aldehyde

amide. 1. LAH 2. H3O+

removes ketone and keeps NR2 as amine

nitrile 1. LAH 2. H3O+

amine

ketone. NaOH

more substituted enolate // thermodynamic

ketone. LDA

less substituted enolate // kinetic

ketone and alcohol with 2 diff R groups. KOH, heat

alkene from alcohol, ketone stays

ester. 1. NaOEt, EtOH 2. HCl, H2O

one ketone one ester