test Flashcards

1
Q

What are the uses of mass spectrometry?

A

-Identify unknown compounds
-Find relative abundance of each isotope of an elemnt
-Determine structural information

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2
Q

How does a mass spectrometer work

A

-Sample is made into positive ions
-Passes through the apparatus and are separated according to mass to charge ratio
-Computer analyses the data and produces mass spectrum

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3
Q

what is an empirical formula

A

Simplest whole number ratio of atoms of each element present in a compound

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4
Q

orbital definition

A

a region of space around the nucleus where there is a high probability of finding an electron

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5
Q

outline s orbitals

A

-can hold 2 electrons
-have spherical shape

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6
Q

outline p orbitals

A

-can hold 2 electrons
-have dumbbell shape

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7
Q

outline s sub shells

A

-made from 1 s-orbital
-can hold 2 electrons

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8
Q

outline p subshels

A

-made from 3 p-orbitals
-can hold 6 electrons

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9
Q

outline d-orbitals

A

-can hold 2 electrons
-shells 3 and 4 contain

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10
Q

What is the Aufbau Principle

A

Fill in increasing order of energy

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11
Q

What is the Pauli Exclusion Principle

A

Electrons pair with opposite sound to stabilise the atom

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12
Q

What is Hund’s Rule

A

One electron occupies each orbital before pairing up

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13
Q

What produces a giant ionic lattice

A

Electrostatic attraction between the positive and negative ions

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14
Q

What is a giant ionic lattice

A

Generally crystals with straight edges, suggesting ions line up alternatively in repeating straight line.

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15
Q

Why is the melting point of ionic lattices so great?

A

A lot of energy is required to break the bonds so the ions can move apart and change state

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16
Q

What can increase melting and boiling points

A

As charge of the ions increase.

17
Q

Outline the solubility or ionic lattices

A

-Relative strengths of the attractions within the lattice and between the ions and water molecules determine solubility
-An ionic compound where ions have large charges the ionic attraction may be too strong for water to break lattice stricter

18
Q

What is a dative covalent bond

A

Both bonding electrons originate from the same atom

19
Q

Isoelectronic species

A

Have the same electron configuration

20
Q

Covalent molecule

A

Shared pair of electrons between atoms with strong electrostatic attraction between the shared pair of electrons and the nuclei of the bonded atoms

21
Q

Lone pair

A

pair of electrons not involved in bonding

22
Q

Trigonal planar

A

-3 Bond pairs
-120°

23
Q

Linear

A

-2 bond pairs
-180°

24
Q

Tetrahedral

A

-109.5°
-4 bond pairs

25
Q

octahedral

A

-6 bond pairs
-90°

26
Q

Trigonal Pyramidal

A

-5 bond pairs
-90°
-120°

27
Q

Electron pair repulsion theory

A

Electrons exists in pairs in spaces we refer to as orbitals
They are all negatively charged so will repel other pairs if they get too close
Therefore electrons will take up positions as far away from each other as possible to minimise repulsion.

28
Q

Lone pair rule for molecule shapes

A

-Lone pair + lone pair repulsion is greater than lone pair + bond pair repulsion which is greater than bond pair + bond pair repulsion

29
Q

NH3 molecule shape

A

-trigonal pyramidal
-107°

30
Q

H20 molecule shape

A

-non-linear
-104.5°