Test 1 – Organic Chemistry Flashcards

1
Q

Finite resources are

A

no longer being made or are being made much more slowly then they are being used. This means that they will run out

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
2
Q

Fossil fuels were formed from

A

biomass ( plankton and other living organisms) that sink to the sea flooor when they die. They are compressed over millions of years under layers of sediment and mud and form fossil fuels; coal, oil and natural gas

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
3
Q

feedstock

A

a raw material used to supply or fuel a machine or industrial process

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
4
Q

General formula of alkanes

A

CnH2n+2 where n is the number of carbon atoms in the molecule.

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
5
Q

Crude oil
is

A

a
finite
resource that is found in the Earth’s crust. It is the remains of
organisms
that lived and died millions of years ago - mainly plankton which was buried in mud.

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
6
Q

Crude oil is a ( structure wise)

A

complex
mixture
of hydrocarbons. The carbon atoms in these molecules are joined together in chains and rings

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
7
Q

Crude oil is an important source of:

A

fuels
such as petrol, diesel, kerosene, heavy fuel oil and liquefied petroleum gases

feedstock
for the
petrochemical
industry

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
8
Q

Other useful substances made from compounds found in crude oil include:

A

solvents

lubricants

detergents

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
9
Q

The
alkanes
form a

A

homologous series

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
10
Q

Like all homologous series, the alkanes:

A

have the same
general formula
differ by CH2 in
molecular formulae
from neighbouring
compounds
show a gradual variation in physical
properties
, such as their
boiling points
have similar chemical properties

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
11
Q

homologous series

A

A ‘family’ of organic compounds that have the same functional group and similar chemical properties.

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
12
Q

The alkanes are saturated hydrocarbons:

A

ydrocarbons
, because they are compounds containing hydrogen and carbon only

saturated
, because their carbon atoms are joined by C-C single bonds

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
13
Q

fractional distillation
is used

A

to separate
crude oil
into simpler, more useful
mixtures
. This method can be used because different
hydrocarbons
have different
boiling points
.

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
14
Q

During the fractional distillation of crude oil:

A

heated crude oil enters a tall
fractionating column
, which is hot at the bottom and gets cooler towards the top

vapours
from the oil rise through the column
vapours
condense
when they become cool enough
liquids are led out of the column at different heights

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
15
Q

Naming thing

A

my elephant poos bricks
methane
ethane propane and butane

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
16
Q

key points for small molecules in a fraction-ating column

A

low boiling points
very volatile
flows easily
ignites easily

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
17
Q

key points for big molecules in a fraction-ating column

A

high boiling points
not very volatile
doesnt flows easily
does not ignites easily

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
18
Q

Bitumen is used for

A

roads and roofs

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
19
Q

Heavy fuel oil is used for

A

fuel for some ships and power stations

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
20
Q

Diesel is used for

A

fuel for some cars and trains

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
21
Q

kerosene is used for

A

fuel for some air-crafts

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
22
Q

petrol is used for

A

fuel for cars

23
Q

liquified petroleum gases used for

A

fuel for domestic heating and cooking

24
Q

One way to remember the names of the fractions is:

A

Lazy Penguins Keep Drinking Hot Beer.
liquified petroleum
petrol
kerosene
Diesel
Heavy fuel oil
Bitumen

25
Q

Each crude oil fraction contains a mixture of ————– . The ———- in a fraction are mostly ———- called ———–

A

hydrocarbons repeat
alkanes

26
Q

Alkanes have similiar but not identical :

A

numbers of hydrogen and carbon atoms in their
molecules

boiling points
ease of
ignition

viscosity

27
Q

Hydrocarbon fuels can undergo——– combustion or ——- combustion depending on the amount of ——-available.

A

complete
incomplete
oxygen

28
Q

Complete combustion of a hydrocarbon fuel happens when there is a
andproduces

A

good supply of oxygen in air. Carbon and hydrogen atoms in the fuel react with oxygen in an
exothermic
reaction

fuel+O2-to co2 plus h20

29
Q

In complete combustion of a hydrocarbon fuel :

A

carbon dioxide
and water are produced

the maximum amount of
energy
is given out

30
Q

In a Bunsen burner,complete combustion occurs when

A

the air hole is fully open.

31
Q

complete combustion general word equation

A

hydrocarbon + oxygen → carbon dioxide + water

32
Q

Incomplete combustion happens when the supply of air or oxygen is —–. ——- is still produced, but ————–
and ———- are produced. ——— energy is released than during complete combustion.

In a Bunsen burner, incomplete combustion occurs when —————————

A

poor
water
carbon monoxide
carbon
less
the air hole is closed.

33
Q

Cracking
is a reaction in which

A

larger saturated
hydrocarbon

molecules
are broken down into smaller, more useful hydrocarbon molecules, some of which are unsaturated:

34
Q

explain the starting reactants and products of cracking

A

the original starting hydrocarbons are
alkanes
the products of cracking include alkanes and
alkenes
, members of a different
homologous series

35
Q

Various methods can be used for cracking,;

A

eg catalytic cracking and steam cracking:

36
Q

Catalytic cracking :

A

uses a temperature of approximately 550°C and a
catalyst
known as a zeolite which contains aluminium oxide and silicon oxide

37
Q

Steam cracking

A

uses a higher temperature of over 800°C and no catalyst

38
Q

Reasons for cracking
Cracking is important for two main reasons:

A
  1. It helps to match the supply of
    fractions
    with the demand for them.
  2. It produces alkenes, which are useful as
    feedstock
    for the
    petrochemical
    industry.
39
Q

The supply is—————————————————————— The demand—————————————————————————Very often of crude oil
produces more of the————— than can be —–, and less of the —————–than ————————————

A

how much of a fraction an oil refinery produces.

is how much of a fraction customers want to buy.

larger hydrocarbons
sold
smaller hydrocarbons
customers want

40
Q

How does cracking solve the supply and demand problem

A

Smaller hydrocarbons are more useful as
fuels
than larger hydrocarbons. Since cracking converts larger hydrocarbons into smaller hydrocarbons, the supply of fuels is improved. This helps to match supply with demand.

40
Q

Alkanes and alkenes both form ————————– of hydrocarbons, but:

A

homologous series
alkanes are saturated their carbon atoms are only joined by C-C single bonds
alkenes are unsaturated they contain at least one C=C double bond

41
Q

alkanes are saturated their carbon atoms are only joined by C-C single bonds
alkenes are unsaturated they contain at least one C=C double bond
as a result :

A

As a result, alkenes are more
reactive than alkanes. Alkenes can take part in reactions that alkanes cannot. For example, ethene molecules can react together to form poly(ethene), a
polymer because alkenes have a double bond which can break

42
Q

What is the order for complicated balancing equation questions?

A

MINHO:

This is the order of how to balance equations that are complicated

M Metals

I Polyatomic Ions

N Non Metals

H Hydrogen

O Oxygen

43
Q

Combustion of alkenes

A
  • burn with a smokier, yellow (luminous) flame than alkanes
  • Incomplete combustion is more common with alkenes
    -less energy efficient than alkanes, so do not make such good fuels
  • do burn completely too
44
Q

viscosity

A

(how easily it flows) increases as the chain length increases-flows less easily

45
Q

Flammability

A

(how easily it burns) increases as chain length increases

46
Q

Test for unsaturation explained

A

if there is as an alkene there will be a positive test for unsaturation because the water will turn from colourless to orange showing that the unsaturated alkene has bonded with the bromine
if there is an alkane there will be a negative test for unsaturation because the water will remain colourless because the alkane is already saturated and thus cannot bond with the bromine water

47
Q

Thermal decomposition

A

is a chemical reaction that happens when a compound breaks down when heated.

48
Q

Thermal decomposition reactions usually occur at—————–this —— breaks the ——– down into —————————

A

very high temperatures , heat, substance, two or more substances

49
Q

thermal decomposition is an example of an ——— reaction this means that it ————————-
so ————– must constantly be supplied ———– reaction ——-

A

endothermic

gains energy from the surroundings
thermal energy
to keep
going

50
Q

naming thing for polymerisation

A

put the word poly in front of the monomers namr

51
Q

testing for alkenes

A

bromine turns from orange- to colourless

52
Q

why is carbon monoxide bad

A

toxic gas that binds to red blood cells oxygen cant reach around the body

53
Q

viscosity and flammabiity

A

first increases as chain length increases
second decreases