Test 1 Flashcards

1
Q

All conventional ionic compounds have the following properties

A
  1. crystals of ionic compounds are hard and brittle
  2. ionic compounds have high melting points
  3. when heated to molten state, ionic compounds conduct electricity
  4. many ionic compounds dissolve in high-polarity solvents
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2
Q

(T/F) The conversion of many atoms to ions results in a significant change in size.

A

True

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3
Q

If the cation has multiple charge, then the ionic radius becomes ______.

A

smaller

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4
Q

If the anion has multiple charge, then the ionic radius becomes _______.

A

larger

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5
Q

(T/F) It is generally true that metal cations are smaller than nonmetal anions.

A

True

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6
Q

Both anions and cations increase in radius _____ down a group.

A

down

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7
Q

The ______ the ion, the shorter the interionic distance; hence the stronger the ________ attraction and the ______ the melting point.

A

smaller, electrostatic, higher

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8
Q

The ______ the charge, the higher the melting point.

A

higher

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9
Q

A cation will be more ______ if it is small and highly positively charged.

A

polarizing

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10
Q

An anion will be more easily polarized if its _______ and highly negatively charged.

A

large

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11
Q

Polarization is favored by ________ that do not have noble gas configurations.

A

cations

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12
Q

As cation charge _______ the probability of covalent behavior increases.

A

increases

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13
Q

Melting points of ________ are larger than melting points of _______.

A

ionic compounds

small covalent compounds

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14
Q

+1

A

ionic, except some lithium compounds

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15
Q

+2

A

ionic, except some magnesium and beryllium compounds

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16
Q

+3

A

usually covalent

17
Q

+4, +5

A

usually covalent

18
Q

+6

A

covalent

19
Q

+7, +8

A

covalent

20
Q

(T/F) Ions try to surround themselves with as many ions of the opposite charge as possible and as closely as possible.

A

True

21
Q

r+/r- = 0.732 to 0.9999

A

Cubic

CN = 8

22
Q

r+/r- = 0.414 to 0.732

A

Octahedral

CN = 6

23
Q

r+/r- = 0.225 to 0.414

A

Tetrahedral

CN = 4

24
Q

CsCl packing arrangment

A
  • simple cubic packing of cations in a simple cubic anion array
  • each unit cell contains 1 Cs and 1 Cl atom
  • CN = 8
25
Q

CaFl2 packing arrangement

A
  • alternate simple cubic packing of cations in sc anion array
  • CN = 8 for cation, CN = 4 for anions
26
Q

Li2O packing arrangment

A
  • cation tetrahedral CN = 4
  • anion cubic CN = 8
  • alternate scp of anion in sc cation array
27
Q

sphalerite

A

1/2 tetrahedral packing of cations in a fcc anion array

CN = 4

28
Q

wurtzite

A

1/2 tetrahedral packing of cations in a hcp anion array

CN = 4

29
Q

Rutile (TiO2)

A

octahedral packing of anions of a distorted bcc cation array

  • cation CN = 6
  • anion CN = 3 (trigonal geometry)
30
Q

BCC

A

CN = 8

2 atoms

31
Q

FCC

A

CN = 12

4 atoms

32
Q

HCP

A

CN = 12

6 atoms