Test 1 Flashcards

1
Q

Stratosphere

A

10-50km
T increases as altitude increases

Ozone =15-25km

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2
Q

Mesosphere

A

50-85km

T decreases as altitude increases

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3
Q

Thermosphere

A

85-500km

T increases as altitude increases

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4
Q

X-rays

A
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5
Q

Ultraviolet

A

50-400

UV-C = 200
UV-B = 280
HV-A = 320
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6
Q

Visible

A

400-750nm

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7
Q

Infrared

A

750-10^5

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8
Q

Troposphere

A

0-16 km

T decrease as altitude increases

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9
Q
Bond Energies
N2
OH-H
O2
CH3-H
CH3-Cl
O=N-O
CH3-Br
OH-OH
O=O-O
A
945
498
497
435
351
305
293
213
107
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10
Q

Ozone layer

A

Stratosphere

O2 + UV-C –> 2O*

O + O2 + M –> O3 + M*

At bottom of troposphere
Decrease in O = lower O2
Density higher so O2(bottom)&raquo_space; O2(top)

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11
Q

Catalysis

A

Substance for ozone destruction is not present

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12
Q

Partial pressure

A

Pressure which gas would have if it alone occupied the volume

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13
Q

Vapor pressure

A

Pressure of vapor in equilibrium with its non vapor phases

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14
Q

Chloroflourocarbons (CFC’s)

A

replaced nasty chemicals in refrigerants such as SO2 and NH3

Increase P at RT = condense

Release P at RT = expansion

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15
Q

Replacing CFC’s

A

Hydrochloroflourocarbons (HCFC’s)
Hydroflourocarbons (HFC’s)
Halons (used in fire extinguishers)

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16
Q

Antarctic Winter

A

1) vortex isolates air within from mixing
2) cold temp forms PSC’s concentrating condensing E substances
3) at end of winter sunlight triggers photochemical reactions

17
Q

Particulates

A

General term for something that exists as minute separate particles

18
Q

Smoke

A

First widely recognized form of air pollution

19
Q

Air pollution

A
Aerosols
Dust
Fly ashes
Fumes
Smokes
Spot
20
Q

Atmospheric Particles

A

100micrometers to 0.001 micrometers

21
Q

Aitken particles

A

Radii less than 0.1 micrometers scatter light deducting visibility an can enter the innermost regions of the lungs

22
Q

Spot particle

A

Incomplete combustion of car onerous material

23
Q

Components of photochemical smog

A

NOx (NO + NO2)
Sunlight
VOC’s
O2

24
Q

Smog prevention

A

Reduce fuel evaporation
Reduce reactivity of fuel with OH
Improve efficiency of fuel carbon oxidation

25
Catalytic Converters
2 chambers Oxidation = Rh catalyst with honeycomb structure Reduction = Pt and PD catalysts
26
Aerosols
Colloid sized atmospheric particles
27
Condensation aerosols
Form condensation or reaction of vapor
28
Dispersion aerosol
Formed from solids, liquids, or dusts
29
PM index
Concentration of aerosols smaller then specified diameter
30
Inorganics in aerosols
``` Fly ash Mercury Lead Cadmium Arsenic ```
31
Health risk for toxins
Health risks from toxins are greater for indoor air than for outdoor air
32
Indoor Pllutants
``` Environmental tobacco smoke Asbestos & other inorganic dusts Radon daughters Indoor use of pesticides Organic dusts and vapors Biological agents (fungi, mold) *no UV light* ```
33
Causes of Acid Rain
Sources = SO2 & NOx Natural SO2 background Human activity Motivation -scrubbing of SO2 with CaCO3
34
Dry vs wet deposition
Kinetics --> rates of oxidation of NOx and SO2 Nuclear ion and partitioning (dry vs wet deposition)
35
Dry deposition
Deposition of gases and particles
36
Effects of acid rain
``` Direct phototoxicity to plants Indirect phototoxicity Respiration effects on humans and animals Acidification of waters Corrosion of exposed structures ```