Test 1 Flashcards
Stratosphere
10-50km
T increases as altitude increases
Ozone =15-25km
Mesosphere
50-85km
T decreases as altitude increases
Thermosphere
85-500km
T increases as altitude increases
X-rays
Ultraviolet
50-400
UV-C = 200 UV-B = 280 HV-A = 320
Visible
400-750nm
Infrared
750-10^5
Troposphere
0-16 km
T decrease as altitude increases
Bond Energies N2 OH-H O2 CH3-H CH3-Cl O=N-O CH3-Br OH-OH O=O-O
945 498 497 435 351 305 293 213 107
Ozone layer
Stratosphere
O2 + UV-C –> 2O*
O + O2 + M –> O3 + M*
At bottom of troposphere
Decrease in O = lower O2
Density higher so O2(bottom)»_space; O2(top)
Catalysis
Substance for ozone destruction is not present
Partial pressure
Pressure which gas would have if it alone occupied the volume
Vapor pressure
Pressure of vapor in equilibrium with its non vapor phases
Chloroflourocarbons (CFC’s)
replaced nasty chemicals in refrigerants such as SO2 and NH3
Increase P at RT = condense
Release P at RT = expansion
Replacing CFC’s
Hydrochloroflourocarbons (HCFC’s)
Hydroflourocarbons (HFC’s)
Halons (used in fire extinguishers)
Antarctic Winter
1) vortex isolates air within from mixing
2) cold temp forms PSC’s concentrating condensing E substances
3) at end of winter sunlight triggers photochemical reactions
Particulates
General term for something that exists as minute separate particles
Smoke
First widely recognized form of air pollution
Air pollution
Aerosols Dust Fly ashes Fumes Smokes Spot
Atmospheric Particles
100micrometers to 0.001 micrometers
Aitken particles
Radii less than 0.1 micrometers scatter light deducting visibility an can enter the innermost regions of the lungs
Spot particle
Incomplete combustion of car onerous material
Components of photochemical smog
NOx (NO + NO2)
Sunlight
VOC’s
O2
Smog prevention
Reduce fuel evaporation
Reduce reactivity of fuel with OH
Improve efficiency of fuel carbon oxidation