Test 1 Flashcards

1
Q

Which functional group has dispersion forces as their dominant IMF?

A

The Alkyl functional group, common makeup CH

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2
Q

Which functional group has hydrogen bonding as its dominant IMF?

A

The Alcohol functional group, common makeup OH

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3
Q

Which functional group has dipole-dipole as its dominant IMF?

A

The Ketone function group, common makeup CO

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4
Q

Which functional group also has a dipole-dipole IMF?

A

The alkyl halide functional group, Common makeup a carbon bound to a halide (CCl)

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5
Q

Why does surface tension occur?

A

Liquid molecules obey closest packing and are pulled from the surface toward the liquid

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6
Q

Explain Capillary action

A

Capillary action happens due to cohesion and adhesion, if there is cohesion a dip will form on the water’s surface and if there is adhesion a bulge will form.

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7
Q

does viscosity increase or decrease with increasing IMFs?

A

Increase, the molecules will want to resist flow more

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8
Q

does vapor pressure increase or decrease with increasing IMFs?

A

decrease, fewer molecules will be able to overcome the IMFs to get to the gas phase.

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9
Q

What is the Clausius Clapeyron equation?

A

ln⁡(𝑃2/𝑃1 )=(∆𝐻𝑣𝑎𝑝)/𝑅∗(1/𝑇1 −1/𝑇2 )

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10
Q

Does Solubility increase or decrease with lower temperatures?

A

decreses

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11
Q

What is Raoult’s law

A

𝑃_𝑠𝑜𝑙𝑣𝑒𝑛𝑡=𝑥_𝑖∗𝑃_𝑠𝑜𝑙𝑣𝑒𝑛𝑡^0

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12
Q

If a solute is added to a solvent, does the temperature at which the solvent freezes (increase or decrease)?

A

decrease

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13
Q

What is the osmotic pressure equation?

A

𝜋=𝑖∗𝑀∗𝑅∗𝑇

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14
Q

how can you use moles to find molecular weight?

A

mass/moles = molecular weight (remember MW is in g/mole).

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15
Q

what is a colloid?

A

a heterogeneous mixture consisting of particles of one substance dispersed in another

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16
Q

what is the defining quality of amorphous solids?

A

they lack long-range order

17
Q

what is the defining quality of crystalline solids?

A

they have long-range order and have a repeating unit cell

18
Q

what is a unit cell?

A

a single repeating unit of atoms

19
Q

what is a lattice point?

A

a unique position within each unit cell

20
Q

what are the 7 basic unit cell types?

A

simple cubic, tetragonal, orthorhombic, rhombohedral, monoclinic, triclinic, and hexagonal

21
Q

define a simple cubic unit cell

A

a=b=c, all angles 90⁰

22
Q

Define a tetragonal unit cell

A

a=b, all angles 90⁰

23
Q

define an orthorhombic unit cell

A

all angles 90⁰

24
Q

define a rhombohedral unit cell

A

a=b=c, none of the angles are 90⁰

25
Q

define a monoclinic unit cell

A

only two angles are 90⁰

26
Q

define a triclinic unit cell

A

no angle is 90⁰

27
Q

define a hexagonal unit cell

A

a=b, only 2 angles are 90⁰, the other is 120⁰

28
Q

what is the density formula for primitive unit cells

A

𝜌_𝑃=1/(2𝑟)^3 ∗((10^7 𝑛𝑚)/(1 𝑐𝑚))^3∗𝑀𝑊/𝑁𝐴

29
Q

what is the density formula for BCC unit cells

A

𝜌_𝐵𝐶𝐶=2/(16/3 𝑟^2 )^(3/2) ∗((10^7 𝑛𝑚)/(1 𝑐𝑚))^3∗𝑀𝑊/𝑁𝐴

30
Q

what is the density formula for FCC unit cells

A

𝜌_𝐹𝐶𝐶=4/(8𝑟^2 )^(3/2) ∗((10^7 𝑛𝑚)/(1 𝑐𝑚))^3∗𝑀𝑊/𝑁𝐴

31
Q

What are the 4 types of crystals?

A

Ionic, Covalent, Molecular, and Metallic