Test 1 Flashcards

1
Q

oxidation

A

loss of electrons, addition of oxygen or removal of hydrogen

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
2
Q

reduction

A

gain of electrons, removal of oxygen or addition of hydrogen

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
3
Q

epoxide

A

unstable system, typically polymerizes rapidly and easily, it is used to make something waterproof

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
4
Q

what will make an epoxide

A

peracid with any alkene

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
5
Q

cold vs hot in reactions

A

cold gives the oxidizing agent less reactivity which slows it down, limits the reagent making it less reactive, will control the reaction better

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
6
Q

syn addition

A

adds across double bonds to same side at the same time

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
7
Q

what are aldehydes oxidized to

A

carboxylic acids

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
8
Q

what does heat do to a reaction

A

gives it energy to be more reactive, splits the double and triple bonds to form aldehydes

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
9
Q

What does a ketone get oxidized to

A

nothing, it cannot be oxidized any further

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
10
Q

ozoloysis

A

type of oxidatice cleavgae that uses ozone to add an oxygen to both sides making aldehydes

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
11
Q

degrees of saturation in an alkene

A

1

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
12
Q

degrees of saturation per ring

A

1

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
13
Q

degrees of unsaturation in an alkyne

A

2

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
14
Q

1 unit

A

monomer

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
15
Q

2 units

A

dimer

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
16
Q

3 units

A

trimer

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
17
Q

4 units

A

tetramer

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
18
Q

5 units

A

pentamer

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
19
Q

6-11 units

A

oligimer

20
Q

12 units and greater

A

polymer

21
Q

examples of types of polymers

A

DNA and RNA

22
Q

radical

A

single electron, very unstable, very reactive

23
Q

what is an alcohol

A

alkyl group attached to a hydroxide

24
Q

what forces does an alcohol use

A

hydrogen bonds

25
Q

what forces does an ether use

A

dispersion forces

26
Q

is water an acid or a base

A

both, it depends on what it is reacting with

27
Q

large ka

A

strong acid

28
Q

small Ka

A

weak acid

29
Q

large pKa

A

weak acid

30
Q

small pKa

A

strong acid

31
Q

how does markovnikov reaction add hydorgen

A

to the carbon with the most hydrogens

32
Q

what is syn addition

A

adds to the same side at the same time

33
Q

what is a primary alcohol oxidized to?

A

aldehyde and then a carboxylic acid

34
Q

what is a secondary alcohol reduced to

A

ketone

35
Q

what is a tertiary alcohol reduced to?

A

nothing

36
Q

how is a carboxylic acid reduced?

A

aldehyde–> primary alcohol or ketone –> secondary alcohol

37
Q

IR of an Alkane

A

4 peaks
2 at 28 and 2900 CH
1 at 1470 CH2
1 at 1360 CH3

38
Q

IR of an aromatic compound

A

4 small peaks

1600-2000

39
Q

IR of an alkyne

A

C triple bond C seen at 21-2200

terminal hydrogen at 3300

40
Q

IR of an alcohol

A

32-3600

strong and broad (smoother peak)

41
Q

IR of an amine

A

peaks between 32-3600

2 peaks if 2 hydrogens, 1 peak if 1 hydrogen

42
Q

IR of a ketone

A

C=O at 1650-1750

43
Q

IR of an aldehyde

A

29 and 2700

44
Q

IR of a carboxylic acid

A

hydroxide group at 25-3600
very broad curve
something around 1700

45
Q

IR of an Ester

A

11-1200 C-O

16501750 C=O

46
Q

IR of an Ether

A

11-1200 C-O

Don’t see the carbonyl peak

47
Q

IR of a Nitrile

A

C triple bond N 21-2200