Terminology and Acronyms Flashcards
Relating to Corrosion
Abrasion Resistance
The ability of material to resist being worn away and to maintain its original appearance and structure when subjected to rubbing, scraping, or wear.
Abrasive
A solid substance that, owing to its hardness, toughness, size shape consistency, or other properties, is suitable for grinding, cutting, roughening, polishing, or cleaning a surface by friction or high-velocity impact.
Abrasive Blast Cleaning
Cleaning and roughening of a surface produced by the high-velocity impact of an abrasive that is propelled by the discharge of pressurized fluid from a blast nozzle or by a mechanical device such as a centrifugal blasting well. [also referred to as ABRASIVE BLASTING]
Abrasive Blasting
See Abrasive Blast Cleaning
Accelerator
A chemical substance that increases the rate at which a chemical reaction (e.g., curing) would otherwise occur.
AC Impedance
See Electrochemical Impedance
Acrylic
Type os resin polymerized from acrylic acid, methacrylic acid, esters of these acids, or acrylonitrile.
Activator
A chemical substance that initiates a chemical reaction (e.g., curing) Heat and radiation may also serve as activators for some chemical reactions.
Active
(1) A State of a metal surface that is corroding without significant influence of reaction product. (2) The negative direction of electrode potential.
Active-passive cell
An electrochemical cell in which the anode is a metal in the active state and the cathode is the same metal in the passive state.
Adduct Curing Agent
A material that is formed by prereacting the curing agent with a portion of the resin component of the coating.
Adhesion
The state in which two surfaces are held together by chemical interfacial forces, mechanical interlocking forces, or both.
Aeration Cell
See Differential Aeration Cell
Aging
(1) The process of exposing materials to an environment of an interval of time. (2) Change in metallurgical properties that generally occurs slowly at room temperature (natural aging) and more rapidly at higher temperature (artificial aging).
Air Drying
Process by which an applied wet coat converts to a dry coating film by evaporation of solvent or reaction with oxygen as a result of simple exposure to air without intentional additional of heat or a curing agent.
Airless Spraying
Process of spraying coating liquids using hydraulic pressure, not air pressure, to atomize.
Alkyd
Type of resin formed bu the reaction of polyhydric alcohols and polybasic acids, part of which is derived from saturated or unsaturated oils or fats.
Alligatoring
Pronounced wide cracking over the surface of a coating, which has the appearance of alligator hide.
Alloy steel
an iron-based alloy containing carbon (usually less than 2.5 mass percent), manganese (usually greater than 0.25 mass percent), and specified minimum quantities of one or more alloying elements other than manganese, silicon, and copper, but does not contain 10.5 mass percent or greater chromium.
Alternate Immersion
Exposure to environmental cycles, each involving immersion in a fluid for a period of time followed bu removal from that fluid or another period of time.
Amphoteric Metal
A metal that is susceptible to corrosion in both acidic and alkaline environments.
Anaerobic
Absence of air or free (molecular) oxygen.
Anchor Pattern
See Surface Profile
Anion
A negatively charged Ion.
Anneal
Heat to and hold at a temperature appropriate for the specific material and then cool at a suitable rate, for such purposes as reducing harness, improving machinability, or obtaining desired properties.
Anode
The electrode of an electrochemical cell at which oxidation occurs. (electrons flow away from the anode in external circuit. It is usually the electrode where corrosion occurs and metal ions enter solution.)
Anode Cap
An electrical insulating material placed over the end of the anode at the lead wire connection.
Anode Corrosion Efficiency
The ration of the actual corrosion (mass loss) of an anode to the theoretical corrosion (mass loss) calculated from the quantity of electricity that has passed between the anode and cathode using Faraday’s law.
Anodic Inhibitor
A corrosion inhibitor whose primary action is to reduce the rate of the anodic reaction, producing a positive shift in corrosion potential.
Anodic Polarization
The change of electrode potential caused by an anodic current flowing across the electrode/electrolyte interface. (2) A forced noble (positive) shift in electrode potential. [See POLARIZATION.]
Anodic Protection
A technique to reduce the corrosion rate of a metal surface by polarizing that surface to a more oxidizing potential.
Anodizing
An electrochemical oxidation process that converts the surface of a metal (such as aluminum or titanium) to an oxide coating.
Anolyte
The electrolyte adjacent to the anode of electrochemical cell
Antifouling
Preventing fouling
Atmospheric Zone
The portion of a marine structure that extends upward from the splash zone and is exposed to sun, wind, water spray, and rain.
Attenuation
Electrical losses in a conductor caused by current flow in the conductor.
Auger Electron Spectroscopy
Analytical technique in which the sample surface is irradiated with low-energy electrons and the energy spectrum of electrons emitted from the surface is measured.
Austenite
The face-centered cubic crystalline phase of iron or iron-based alloys.
Austenitic/Ferritic Stainless Steel
See Duplex Stainless Steel
Austenitizing
Forming Asutenite by heating iron or iron-based alloys to temperature in the transformation range (partial austenitizing) or above the transformation range (complete austenitizing).
Auxiliary Electrode
See Counter Electrode
Backfill
Material placed in a hole to fill the space around the anodes, vent pipe, and buried components of a cathodic protection system.
Barcol Hardness
A hardness value obtained by measuring the resistance of rubbers, plastics, or coatings to indentation by a steel impresser under spring load in accordance with Test Method D2583.
Barrier Coating
(1) A coating that has a high resistance to permeation of liquids and/or gases. (2) a coating that is applied over a previously coated during subsequent handling.
Beach Marks
The characteristic markings on the fracture surfaces produced by fatigue crack propagation. [also known as arrest marks, clamshell marks, and conchoidal marks]
Beta Curve
A plot of dynamic (fluctuating) interference current or related proportional voltage (ordinate) versus the corresponding structure-to-electrolyte potentials at a selected location on the affected structure (abscissa)
Binder
The nonvolatile portion of the vehicle of a formulated coating material.
Bituminous Coating
An asphalt or coal-tar compound used to provide a protective coating for a surface.
Blast Angle
(1) The angle of the blast nozzle with reference to the surface during abrasive blast cleaning. (2) The angle of the abrasive particles propelled from a centrifugal blasting wheel with reference to the surface being abrasive blast cleaned.
Blister
A dome-shaped projection on the surface of a coating resulting from the local loss of adhesion and lifting of the film from an underlying coat of from the base substrate.
Blooming
See Blushing
Blowdown
(1) The injection of air or water under high pressure through a tube to the anode area for the purpose of purging the annular space and possibly correcting high resistance caused by gas blockage. [cathodic protection use] (2) The process of discharging a significant portion of the aqueous solution in order to remove accumulated salts deposits, and other impurities. [boiler or cooling water tower use]
Blushing
Whitening and loss of gloss of a coating, usually organic, caused by moisture. [also known as blooming]
Bracelet Anode
A galvanic anode with geometry suitable for direct attachment around the circumference of a pipeline. This may be half-shell bracelet consisting of two semicircular sections or a segmented bracelet consisting of a large number of individual sections.
Braze
(1) A bond produced as the result of heating an assembly to the brazing temperature greater than 450 °C [840 °F] and less than the solidus temperature of the base metal using a brazing filler metal distributed and retained between the closely fitted facing surfaces of the joint by capillary action. (2) the Act of creating a braze.
Breakdown Potential
The least noble potential at which pitting or crevice corrosion, or both, will initiate and propagate in a specific environment.
Brinell Hardness
Hardness value, measured in accordance with ISO 6506-1 or Test Method E10, normally using a 10 mm diameter tungsten carbide ball and a force of 29.42 kN.
Brittle Fracture
Fracture that occurs with little or no plastic deformation of the material. [contrast with DUCTILE FRACTURE]
Brush-off Blast Cleaned Surface
An abrasive blast cleaned steel surface that is free of all visible contaminants and foreign matter but may have some tightly adherent mill scale, rust, or coating. [See NACE No. 4/SSPC-SP 7 for Detailed specification.]
Burnish
Process of smoothing surfaces using frictional content between the material and some other hard pieces of hard material (e.g., hardened steel balls).
Calcareous Deposit
See Calcareous Coating
Carbon Steel
Allow of carbon and iron containing up to 2 mass percent carbon and up to 1.65 mass percent manganese and residual quantities of other elements, except those intentionally added in specific quantities for deoxidation (usually silicon and/or aluminum)
Carburizing
The absorption and diffusion of carbon in iron or an iron-based alloy in contact with a suitable carbonaceous environment at elevated temperature.
Case Hardening
Hardening a ferrous alloy so that the outer portion, or case, is made substantially harder than the inner portion, or core. Typical processes are carburizing, cyaniding, carbonitriding, nitriding, induction hardening, and flame hardening.
Casein Paint
Water-thinned paint with vehicle derived from milk.
Catalyst
A chemical substance, usually present in small amounts relative to reactants, that increases the rate at which a chemical reaction (e.g., curing) would otherwise occur, but is not consumed in the reaction.
Cathode
The electrode of an electrochemical cell at which reduction is the principal reaction. (Electrons flow toward the cathode in the external circuit.)
Cathodic Corrosion
The conjoint action of cavitation and corrosion.
Cavitation Damage
The degradation of a solid body resulting from its exposure to cavitation. (This may include loss of material, surface deformation, or changes in properties or appearance.)
Cavitation-erosion
The conjoint action of cavitation and erosion.
Cell
See Electrochemical Cell
Cementation
The introduction of one or more elements into the surface layer of a metal or alloy by diffusion at high temperature. (Examples of cementation include carburizing [introduction of carbon], nitriding [introduction of nitrogen], and chroming [introduction of chromium].)
Cementite
Iron carbide (Fe3C) when referred to as a microstructural constituent of steel.
Chalking
The development of loose, removable powder (pigment) at the surface of organic coating, usually caused by weathering.
Checking
The development of slight breaks in a coating that do not penetrate to the underlying surface.
Chemical Conversion Coating
An adherent, reaction-product layer on a metal surface formed in situ by reaction with a suitable chemical, used for protective, decorative, or functional purposes. (It is often used to provide greater corrosion resistance or prepare the surface prior to the application of an organic coating.)
Chevron Pattern
A V-shaped on a fatigue or brittle-fracture surface. The pattern can also be one of straight radial lines on cylindrical specimens.
Chipping
(1) Removing coating and surface contaminants from a substrate by mechanical means. (2) A type of coating failure caused by mechanical damage, loss of adhesion, or both.
Chloride Stress Corrosion Cracking
Cracking of a metal under the combined action of tensile stress and corrosion in the presence of en electrolyte containing dissolved chlorides.
Cleavage Fracture
Fracture that occurs along planes determined by the crystal structure of the material. (It is typically associated with a brittle fracture.)
Coat
One layer of a coating system applied to a surface in a single continuous application to form a uniform film when dry.
Coating
(1) a liquid, liquefiable, or mastic composition that, after application to a surface, is converted into a solid protective, decorative, or functional adherent film. (2) (in a more general sense) A think layer of solid material on a surface that provides improved protective, decorative, or functional properties.
Coating System
The complete number and types of coasts applied to a substrate in a predetermined order. (When used in a broader sense, surface preparation are included.)
Cold Cracking
Cracking of a weld during or after cooling to ambient temperature, sometimes after a considerable time delay. (It usually occurs at temperatures less than 205 °C [400 °F].)
Cold Lap
A linear discontinuity with rounded edges at exposed surfaces that is caused by solidification of the meniscus of a partially cast metal or alloy (e.g., an anode used for cathodic protection) as a result of interrupted flow of the casting stream or the joining of two casting streams at too low a temperature.
Cold Shut
Horizontal surface discontinuity caused by solidification of a portion meniscus during the progressive filling of a mold, which is later covered with more solidifying metal as the molten metal level rises. Cold shuts generally occur at corner remote from the point of pour.
Cold Working
Deforming metal plastically under conditions of temperature and strain rate that induce strain hardening, usually, but not necessarily, performed at room temperature [contract with hot working].
Commercial Blast Cleaned Surface
An abrasive blast cleaned steel surface that is free of all visible contaminants and foreign matter but may have some random staining on no more than 33 percent of the surface area. [See NACE No. 3/SSPC-SP 6 for detailed specification.]
Compressive Strength
The maximum compressive stress a material is capable of withstanding without sustaining permanent deformation.
Concentration Cell
An electrochemical cell, the electromotive force of which is caused by a difference in concentration of some component in the electrolyte. (This difference leads to the formation of discrete cathodic and anodic regions.)
Concentration Polarization
That portion of polarization of an electrochemical cell produced by concentration changes resulting from current flowing through the electrolyte.
Conductive Coating
(1) A coating that conducts electricity. (2) an electrically conductive, mastic-like material used as an impressed current anode on reinforced concrete surfaces.
Conductive Concrete
A highly conductive cement-based moisture containing coarse and fine coke and other materialized as an impressed current anode on reinforced concrete surfaces.
Conductivity
(1) a measure of the ability of a material to conduct an electric charge. (2) the current transferred across a material (e.g., coating) per unit area per unit potential gradient. (Conductivity is the reciprocal of resistivity.)
Contact Corrosion
See Galvanic Corrosion
Continuity Bond
A connection, usually metallic, that provides electrical continuity between structures that can conduct electricity.
Continuous Anode
A single anode with no electrical discontinuities.
Conversion Coating
See Chemical Conversion Coating
Copper Sulfate Test
(1) A test method in which a solution of copper sulfate, and possibly other ingredients, in water is swabbed onto the surface of certain metals to determine the presence of metals more active (anodic) than copper. (2) a spot test method in which a 5 to 1- perfect solution of copper sulfate in water is swabbed onto a steel surface to determine whether mill scale is present. (The appearance of copper indicates that mill scale is not present.)
Corrosion
The deterioration of a material, usually a metal, that results from a chemical or electrochemical reaction with its environment.
Corrosion-Inhibitive Pigment
A Pigment that, when formulated into a liquid a coating material, has the property of reducing corrosion of the metal substrate to which the coating is applied.
Corrosion Fatigue
The process wherein a metal fractures prematurely under conditions of simultaneous corrosion and repeated cyclic loading at lower stress levels or fewer cycles than would be required to cause fatigue of that metal in the absence of the corrosive environment.
Corrosion Fatigue Strength
The maximum repeated stress that can be endured by a metal without fracture under definite conditions of corrosion and cyclic loading for a specific number of stress cycles and a specified period of time.
Corrosion Inhibitor
A chemical substance or combination of substances that, when present in the proper concentration and forms in the environment, reduces the corrosion rate.
Corrosion Potential
(represented by the symbol E-corr) The potential of a corroding surface in an electrolyte measured under open-circuit conditions relative to a reference electrode. [also known as ELECTROCHEMICAL CORROSION POTENTIAL, FREE CORROSION POTENTIAL, OPEN-CIRCUIT POTENTIAL]
Corrosion Rate
The time rate of change of corrosion. (It is typically expressed as mass loss per unit area per unit time, penetration per unit time, etc.)
Corrosion Resistance
Ability of a material, usually a metal, to withstand corrosion in a given environment.
Corrosiveness
The tendency of an environment to cause corrosion.
Counter Electrode
The electrode in an electrochemical cell that I used to transfer current to or from a working electrode.
Counterpoise
A conductor or system of conductors arranged beneath a power line, located on, above, or most frequently, below the surface of the earth and connected to the footings of the towers or poles supporting the power line.
Couple
See Galvanic Couple
Coupon
A portion of a material or sample, usually flat, but occasionally curved or cylindrical, from which one or more specimens can be taken for testing.
Crack
(1) A partial split or break. (2) A split or break in a coating that penetrates to the substrate.
Cracking
Fracture of a material along a path that produces a linear discontinuity (without complete separation).
Crater
(1) A metal surface anomaly consisting of a bowl-shaped cavity with the minimum dimension at the opening greater than the depth. [contrast with PIT] (2) a small, rounded dish or bowl-like depression in a wet-applied coating. [contract with FISH EYE]
Crazing
A network of checks or cracks appearing on the surface of a coating.
Creep
Time-dependent strain occurring under stress.
Creep Strength
That stress which, when applied to a material at a specific temperature, will cause a specified amount of elongation in a specified time.
Crevice Corrosion
Localized corrosion of a metal or alloy surface at, or immediately adjacent to, an area that is shielded from full exposure to the environment because of close proximity of the metal or alloy to the surface of another material or an adjacent surface of the same metal or alloy.
Critical Anodic Current Density
The maximum anodic current density observed int he active region for a metal or alloy electrode that exhibits active-passive behavior in an environment.
Critical Humidity
The relative humidity above which the atmospheric corrosion rate of a specific metal or alloy increases sharply.
Critical Pitting Potential
(represented by the symbol Ep or App) The least noble potential at which pitting corrosion will initiate and propagate in a specific environment. [See breakdown potential.]
Curing
Chemical process of developing the intended properties of a coating or other material (e.g., resin) over a period of time.
Curing Agent
A chemical substance used for curing a coating or other material (*e.g., resin) [also referred to as HARDENER]
Curing Time
The minimum period between application and the time at which the applied material attains its intended physical properties.
Current
(1) a flow of electric charge. (2) the amount of electric charge flowing past a specified circuit point per unit time, measured in the direction of net transport of positive charges. (In a metallic conductor, this is the opposite direction of the electron flow.)
Current Density
The electric current flowing to or from a unit area of an electrode surface.
Current Efficiency
The ration of the electrochemical equivalent current density for a specific reaction to the total applied current density.
DC Decoupling Device
A device used in electrical circuits that allows the flow of alternating current in both directions and stops or substantially reduces the flow of direct current.
Deactivation
The process of prior removal of the active corrosive constituents, usually oxygen, from a corrosive liquid by controlled corrosion of expendable metal or by other chemical means, thereby making the liquid less corrosive.
Dealloying
A corrosion process whereby one constituent of an alloy is preferentially removed, leaving an altered residual structure. [also known as PARTING, SELECTIVE DISSOLUTION, or SELECTIVE LEACHING].
Decomposition Potential
The potential of an electrode surface at which the electrolyte, or a component thereof, decomposes by electrons.
Decomposition Voltage
See Decomposition Potential
Deep Groundbed
One or more anodes installed vertically at a nominal depth of 15 m (50 ft) or more below the earth’s surface in a drilled hole for the purpose of supplying cathodic protection current.
Delamination
(1) Separation of layers in a material. (2) A separation between one or more coats from another coat within a coating system. [contrast with DISBONDMENT] (3) A separation of the concrete (usually in layers) from the reinforcing steel at their interface, usually as a result of corrosion.
Delayed Cracking
(1) Cracking in a metal occurring after plating or pickling, sometimes after a considerable time delay. (2) not a preferred term for COLD CRACKING.
Depolarization
(not a preferred term) The removal of factors resisting the current flow in an electrochemical cell. [See POLARIZATION.]
Deposit Corrosion
Localized corrosion under or around a deposit or collection of material on a metal surface. [also called POULTICE CORROSION] See also CREVICE CORROSION.]
Dezincificaiton
Dealloying that results in the selective removal of zinc from copper-zinc alloys.
Dielectric Coating
A coating that does not conduct electricity.
Dielectric Shield
An electrically nonconductive material, such as a coating, sheet or pipe, that is placed between an node and an adjacent cathode, usually on the cathode, to improve current distribution in a cathodic protection system.
Differential Areation Cell
A concentration cell caused by differences in oxygen concentration along the surface of a metal in an electrolyte. [See CONCENTRATION CELL]
Diffusion-Limited Current Density
The current density that corresponds to the maximum transfer rate that a particular species can sustain because of the limitation of diffusion [often referred to as LIMITING CURRENT DENSITY].
Disbondment
The loss of adhesion between a coating and the substrate.
Discontinutiy
(1) an interruption in the normal physical structure or configuration of a coating such as cracks, laps, seams, inclusion, porosity, or holidays. (A discontinuity does not necessarily affect the usefulness of the coating.) (2) A condition in which the electrical path through a structure is interrupted by a drive that acts as a dielectric or insulating fitting.
Dissimilar Metals
Different metals that could form an anode cathode relationship in an electrolyte when connected by an electron-conducting (usually metallic =) path.
Double Layer
The interface between an electrode or a suspended particle and an electrolyte created by charge-charge integration leading to an alignment of oppositely charged ions at the surface of the electrode or particle. The simplest model is represented bu a parallel plate condenser.
Doubler Plate
An additional plate or thickness of metal used to provide extra strength or thickness to a structure locally (e.g., at the point of anode attachment to an offshore structure).
Drainage
Conduction of electric current from am underground or submerged metallic structure by means of a metallic conductor.
Driving Potential
Difference in potential between the anode and the steel structure.
Dry Film Thickness
The thickness of a dried mild, coating, or membrane.
Dry Spray
A rough, powdery non coherent film produced when atomized coating particles partially dry before reaching the surface.
Dry to Handle
Stage of drying or curing of an applied coating at which time the coated object can be carefully handled without damage.
Dry to Recoat
Stage of drying or curing of an applied coating at which time a subsequent coat can be applied satisfactorily.
Dry to Touch
Stage of drying or curing of an applied coating at which time it no longer adheres to a finger that is lightly touched or rubbed across the surface and does not show a fingerprint at the point of contact.
Drying
The process in which a liquid film is converted to a solid film bu evaporation of volatile components.
Drying Oil
An oil capable of conversion from a liquid to a solid by slow reaction with oxygen in the air.
Drying Time
Minimum time required for an applied coating to reach the desires stage of drying or curing.
Ductile Fracture
Fracture that occurs with appreciable plastic deformation of the material to withstand plastic deformation prior to fracture. (It is usually measured by the permanent elongation or reduction in the cross-sectional are of a fractured tensile test specimen.)
Ductility
The ability of material to withstand plastic deformation prior to fracture. (It is usually measured by the permanent elongation or reduction in the cross sectional area of a fractured tensile test specimen.)
Duplex Stainless Steel
Stainless Steel whose microstructure at room temperature consists primarily of a mixture of austenite and ferrite. [also called AUSTENITIC/FERRITIC STAINLESS STEEL].
Elastic Deformation
Changes of dimensions of a material upon the application of a stress within the elastic range. Following the release of an elastic stress, the material returns to its original dimensions without any permanent deformation.
Elasticity
The property of a material that allows it to recover its original dimensions following deformation by a stress below its elastic limit.
Elastic Limit
The maximum stress to which a material may be subjected without retention of any permanent deformation after the stress is removed.
Electrical Interference
Any electrical disturbance on a metallic structure in contract with an electrolyte caused by stray currents(s)
Electrical Isolation
The condition of being electrically separated from other metallic structures or the environment.
Electrochemical Admittance
The reciprocal of the electrochemical impedance, 🔺I/🔺E.
Electrochemical Cell
(1) An electrochemical reaction involving two half reactions, one of which involves oxidation of the reactant (product) and the other of which involves reduction of the product (reactant). (The equilibrium potential of the electrochemical cell can be calculated from the change in free energy for the overall electrochemical reaction. The equilibrium potential of the electrochemical cell can be measured bu separating the oxidation and reduction half reactions into individual compartments and measuring the voltage that develops between them under conditions that virtually no charge passes between them.) [thermodynamic use] (2) An electrochemical system consisting of anode and cathode in metallic contact immersed in an electrolyte. (The anode and cathode may be different metals or dissimilar areas on the same metal surface.) [common use]
Electrochemical Corrosion Potential
See Corrosion Potential
Electrochemical Equivalent
The mass of element or group of elements oxidized or reduced at 100 percent efficiency by the passage of a unit quantity of charge such as a Faraday (96,485 coulombs), ampere-hour, or coulomb.
Electrochemical Impedance
The frequency dependent, complex valued proportionality factor, 🔺I/🔺E, between the applied potential (or current) and the response current (or potential) in an electrochemical cell. This factor becomes the impedance when the perturbation and response are related linearly (the factor value is independent of the perturbation magnitude) and the response is caused only by the perturbation. The value may be related to the corrosion rate when the measurement is made at the corrosion potential.
Electrochemical Noise
Flactuations of potential or current, or both, originating fro uncontrolled variations in a corrosion process.
Electrochemical Potential
The partial derivate of the total electrochemical free energy of the stem with respect to the number of moles of the constituent in a solution when all other factors are constant. (Analogous to the chemical potential of the constituent except that it includes the electrical as well as the chemical contributions to the free energy.)
Electrode
A material that conducts electrons, us used to establish contact with an electrolyte, and through which current is transferred to or from an electrolyte.
Electrode Potential
The potential of an electrode is an electrolyte as measured against a reference electrode.
Electrokinetic Potential
A potential difference in a solution caused by residual, unbalanced charge distribution in the adjoining solution, producing a double layer. (The electrokinetic potential is different from the electrode potential in that it occurs exclusively in the solution phase. The potential represents the reversible work necessary to bring a unit charge from infinity in the solution up to the interface in question but not through the interface.) [also known as ZETA POTENTIAL]
Electrolysis
Production of chemical changes of the electrolyte by the current flowing through an electrochemical cell.
Electrolytic Cleaning
A process for removing soil, scale, or corrosion products from a metal surface by subjecting the metal as electrode to an electric current in an electrolytic bath.
Electromotive Force Series
A list of elements arranged according to their standard electrode potentials, the sign being positive for elements whose potentials are more noble than hydrogen such as gold and negative for those more active than hydrogen such as zinc. [not to be confused with GALVANIC SERIES]
Electro-osmosis
The migration of water through a semipermeable membrane as a result of a potential difference caused by the flow of electric charge through the membrane.
Ellipsometry
An optical technique wherein place-polarized light is focused on a surface and the reflected beam is analyzed to determine the phase shift of the components of the light to provide information on the properties of films that may be present on the surface.
Embrittlement
Reduction of ductility, or toughness, or both, of a material (usually a metal or alloy.)
EMF Series
See Electromotive Force Series
Enamel
(1) A paint that dries to a hard, glossy, surface (2) A coating that is characterized by an ability to form a smooth, durable film.
End Effect
The more rapid loss of anode material at the end of an anode, compared with other surfaces of the anode, resulting from higher current density.
Endurance Limit
The maximum stress that a material can withstand for an infinitely large number of fatigue cycles.
Environment
The surroundings or conditions (physical, chemical, mechanical) in which material exists.
Environmental Cracking
Cracking of a material wherein an interaction with its environment is a causative factor in conjunction with tensile stress, often resulting in brittle fracture of an otherwise ductile material. [also known as ENVIRONMENTALLY ASSISTED CRACKING]
Environmental Cracking Discussion 1
Environmental cracking is a general term that includes the terms listen below. The definitions of these terms are listed elsewhere in this document: CAUSTIC CRACKING, CHLORIDE STRESS CORROSION CRACKING, CORROSION FATIGUE, HYDROGEN EMBRITTLEMENT, HYDROGEN-INDUCED CRACKING (STEPWISE CRACKING), HYDROGEN STRESS CRACKING, LIQUID METAL CRACKING, STRESS CORROSION CRACKING, SULFIDE STRESS CRACKING.
Environmental Cracking Discussion 2
The following terms have been used in the past in connection with environmental cracking but are now obsolete and should not be used: CAUSTIC EMBRITTLEMENT, delayed cracking, liquid metal embrittlement, SEASON CRACKING, static fatigue, sulfide corrosion cracking, sulfide stress corrosion cracking.
Environmentally Assisted Cracking
See Environmental Cracking
Epoxy
Type of resin formed by the reaction of aliphatic or aromatic polls (such as bisphenol) with epichlorohydrin and characterized by presence of reactive oxidant end groups.
Equilibrium Potential
The potential of an electrode in an electrolyte at which the forward rate of a given reaction is exactly equal to the reverse rate. (The equilibrium potential can only be defined with respect to a specific electrochemical reaction.) [also known as REVERSIBLE POTENTIAL]
Erosion
The progressive loss of material from a solid surface resulting from mechanical interaction between that surface and a fluid, a multicomponent fluid, or solid particles carried with the fluid.
Erosion-Corrosion
A conjoint action involving erosion and corrosion in the presence of a moving corrosive fluid or a material moving through the fluid, leading to accelerated loss of material.
Exchange Current Density
The rate of charge transfer per unit area when an electrode reaches dynamic equilibrium (at its reversible potential) in a solution; that is, the rate of anodic charge transfer (oxidation) is exactly equal to the rate of cathodic charge transfer (reduction).
Exfoliation Corrosion
Subsurface corrosion that proceeds laterally from the sites of initiation along planes parallel to the surface forming corrosion products that force metal away from the body of the material, giving rise to a layered appearance resembling the pages of a book.
External Circuit
The wires, connectors, measuring devices, current sources, etc., that are used to bring about or measure the desired electrical conditions within an electrochemical cell. It is this portion of the cell through which electrons travel.
Fatigue
The process of progressive localized permanent structural change occurring in a material subjected to fluctuating stresses less than the ultimate tensile strength of the material that may culminate in cracks or complete fracture after a sufficient number of fluctuations.
Fatigue Strength
The maximum stress that can be sustained for a specified number of cycles without fracture.
Fault Current
A current that flows from one conductor to ground or to another conductor as a result of an abnormal connection (including an arc) between the two. A fault current flowing to ground may be called a ground fault current.
Feather Edging
See Feathering
Feathering
Reducing the thickness of the edges of an undamaged coating film, such as adjacent to a damaged coating or rusted area, by abrasion or sanding to produce a smoothly tapered transitional area prior to recoating.