Term Symbols Flashcards

1
Q

Spin angular momentum

A

S = total spin angular momentum, electrons in same orbital paired (Pauli) therefore S = 0, 2S+1 possible projections

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2
Q

Closed shell

A

All electrons paired

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3
Q

Term symbol of closed shell molecules

A

Totally symmetric irreducible representation

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4
Q

Orbital angular momentum

A

Electron in σ orbital has λ =0
Electron in π orbital has λ =+-1
Two electrons in same π orbital have same λ
Sum all individual λ for all electrons to get total projection along inter nuclear axes of total angular momentum, Λ

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