Term Symbols Flashcards
1
Q
Spin angular momentum
A
S = total spin angular momentum, electrons in same orbital paired (Pauli) therefore S = 0, 2S+1 possible projections
2
Q
Closed shell
A
All electrons paired
3
Q
Term symbol of closed shell molecules
A
Totally symmetric irreducible representation
4
Q
Orbital angular momentum
A
Electron in σ orbital has λ =0
Electron in π orbital has λ =+-1
Two electrons in same π orbital have same λ
Sum all individual λ for all electrons to get total projection along inter nuclear axes of total angular momentum, Λ