Tannins Flashcards
Properties of tannins?
Amorphous (no specific shape)
Possess an acid reaction, puckering taste
Properties of tannins
Soluble in water
Ppty of tannins
Precipitate sol of gelatin albumin and alkaloids
Ppt by sals of copper lead and tin
Readily absorbs oxygen
Form dark blue of greenish black w/ ferric salts
Deep red with KFCN
Ppty of tannins
Yield simple polyhydric phenols
Gallic acid —> pyrogallol (turns blue by Fe+)
Protocatechuic acid —> cathechl (green by fe)
Ellagic acid —> pyragallol nuclei ( green by fe+)
Importance
Employs energy
Source of fruit acids
Antiseptic or prevent damage by insect or fungi
Serves as protectant to the plant
Importance to man
Astringent to GIT and skin abrasions
Tx of burns
Preservative on leather
Deeply colored compound
Reagents for detection og gelatin, al, and proteins
Inactivate alkaloid, for alkaloid poisoning
Condensed tannins
Yields catechol when heated
Yield insoluble red phlobaphenes when boiled hcl
Form ppt with bromine
Form green color
Hamamelis
Witch Hazel Leaves,
Hamamelis virginiana
Gallic acid, bitter, hamamelitanin
Hemostatic, astringent
Krameria
Rhatany
Krameria triandra
Krameric acid, tannin 8-10%
Astringent
Chestnut
Castanea dentate
Tannic acid, mucilage
Astringent
Kino
Indian kino tree
Pterocarpus marsupium
Kinnota nic acid. Kinoin, kino-red
Astringent
Gambir
Pale catechu
Uncaria gambir
Catechutannic acid
Astringent
Ceanothus
NJ Tea, red root
Ceanothus americans
Phlobapenes(redbrown insoluble ppt)
Hemostatic
Oak Bark
English / common oak
Quercus robur
Phlobatannins, ellagintannins, gallic acid
Astringent tanning dyeing
Turkish galls
Turkey galls, galla Dyer's oak. Quercus infectoria Gallotanic acid Tanning dyeing , manufacture of ink