Tannins Flashcards

1
Q

Properties of tannins?

A

Amorphous (no specific shape)

Possess an acid reaction, puckering taste

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
2
Q

Properties of tannins

A

Soluble in water

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
3
Q

Ppty of tannins

A

Precipitate sol of gelatin albumin and alkaloids

Ppt by sals of copper lead and tin

Readily absorbs oxygen

Form dark blue of greenish black w/ ferric salts

Deep red with KFCN

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
4
Q

Ppty of tannins

A

Yield simple polyhydric phenols

Gallic acid —> pyrogallol (turns blue by Fe+)

Protocatechuic acid —> cathechl (green by fe)

Ellagic acid —> pyragallol nuclei ( green by fe+)

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
5
Q

Importance

A

Employs energy

Source of fruit acids

Antiseptic or prevent damage by insect or fungi

Serves as protectant to the plant

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
6
Q

Importance to man

A

Astringent to GIT and skin abrasions
Tx of burns
Preservative on leather
Deeply colored compound
Reagents for detection og gelatin, al, and proteins
Inactivate alkaloid, for alkaloid poisoning

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
7
Q

Condensed tannins

A

Yields catechol when heated

Yield insoluble red phlobaphenes when boiled hcl

Form ppt with bromine

Form green color

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
8
Q

Hamamelis

A

Witch Hazel Leaves,

Hamamelis virginiana

Gallic acid, bitter, hamamelitanin

Hemostatic, astringent

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
9
Q

Krameria

A

Rhatany

Krameria triandra

Krameric acid, tannin 8-10%

Astringent

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
10
Q

Chestnut

A

Castanea dentate

Tannic acid, mucilage

Astringent

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
11
Q

Kino

A

Indian kino tree
Pterocarpus marsupium
Kinnota nic acid. Kinoin, kino-red
Astringent

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
12
Q

Gambir

A

Pale catechu
Uncaria gambir
Catechutannic acid
Astringent

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
13
Q

Ceanothus

A

NJ Tea, red root
Ceanothus americans
Phlobapenes(redbrown insoluble ppt)
Hemostatic

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
14
Q

Oak Bark

A

English / common oak
Quercus robur
Phlobatannins, ellagintannins, gallic acid
Astringent tanning dyeing

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
15
Q

Turkish galls

A
Turkey galls, galla
Dyer's oak.
Quercus infectoria
Gallotanic acid
Tanning dyeing , manufacture of ink
How well did you know this?
1
Not at all
2
3
4
5
Perfectly
16
Q

Hydrolysable Tannins!

A

Yield pyrogallol when heated
Yield gallic acid and ellagic acid, hcl
Form

17
Q

Nutgall

A

Quarous infectoria
Tannic, gallic, ellagic
Inks, tanning dyeing, alkaloidal ppt

18
Q

Rose

A

Red / french rose
Rosa gallica
Quercetrin gallic ellagic
Tonic colorant mild astringent

19
Q

Hawthorn

A

Haw may bush /flower
Crataegus monogyna
Procyanidin
Regulate bp, mild cardiotonic, sedative, MI

20
Q

Sangre de gato

A

dragon’s blood, sangre degrase
Proton neckheri
Proanthocyanidin, rapsin
Anti-ox, anti tumor

21
Q

Myrobalan

A

Hala; black talisay
Terminalia cheuula, t. Catappa
Tannins, anthraquinone glycoside
Anti diarrheal, astringent

22
Q

Alchemillia

A

Lady’s mantle
Alchemilla mollis
Tannic acid, gallic, ellagic acid

Topical astringent, regulates mens cycle, reduce cramps

23
Q

Who discovered tannins? And when?

A

Seguin. 1796