Synthetic Routes Aliphatic Compounds Flashcards by Izzy Lipington

Q

Alkene —> Alkane

A

H2/Ni

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Q

Alkene —> Haloalkane

A

Hydrogen halide

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Q

Alkene —> Alcohol

A

H2O/H3PO4

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Q

Alkane —> Haloalkane

A

Halogen/UV

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Q

Haloalkane —> Alcohol

A

NaOH (aq)

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Q

Alcohol —> Haloalkane

A

Sodium halide/ H2SO4

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Q

Alcohol —> Alkene

A

H3PO4 or H2SO4/heat

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Q

Haloalkane —> Nitrile

A

CN-/ethanol

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Q

Haloalkane —> Amine

A

NH3/ethanol

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Q

Nitril —> Amine

A

H2/Ni

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Q

Alcohol —> Ester

A

Carboxylic acid/conc H2SO4 or acid anhydride

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Q

Primary alcohol —> Carboxylic acid

A

K2Cr2O7/H2SO4 reflux

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Q

Secondary alcohol —> ketone

A

K2Cr2O7/H2SO4 reflux

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Q

Primary alcohol —> Aldehyde

A

K2Cr2O7/H2SO4 distillation

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Q

Aldehyde —> Primary alcohol

A

NaBH4

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Q

Ketone —> Secondary alcohol

A

NaBH4

Q

Ketone —> Hydroxynitrile

A

NaCN (aq)/H+ (aq)

Q

Hydroxynitrile —> Amine

A

H2/Ni

Q

Aldehyde —> hydroxynitrile

A

NaCN (aq)/H+ (aq)

Q

Nitrile —> Carboxylic acid

A

H2O/HCl heat

Q

Hydroxynitrile —> Carboxylic acid

A

H2O/HCl heat

Q

Aldehyde —> Carboxylic acid

A

K2Cr2O7/H2SO4 reflux

Q

Carboxylic acid —> Ester

A

Alcohol/conc. H2SO4

Q

Ester —> Carboxylic acid

A

Dilute acid, heat

Q

Ester —> Carboxylate

A

OH-, heat

Q

Carboxylic acid —> Acyl chloride

A

SOCl2

Q

Acyl chloride —> Carboxylic acid

A

H2O

Q

Acyl chloride —> Ester

A

Alcohol

Q

Acyl chloride —> Primary amide

A

NH3

Q

Acyl chloride —> Secondary amide

A

Primary amine