Synthetic Route Conditions Flashcards
1
Q
Two ways to haloalkane
A
- primary alcohol (Sodium halide / H2SO4)
- Alkenes (hydrogen halide )
2
Q
Haloalkane to nitrile
A
NaCN
3
Q
two ways to get to a amine
A
- Haloalkane (NH3/ethanol)
- H2/ni. Reduction
4
Q
Primary alcohol to Alkenes
A
H2SO4
5
Q
3 ways to a primary alcohol
A
- reduction of an aldehyde (NaBH4)
- Alkene (H3PO4/ H20)
- haloalkane. NaOH
6
Q
How to get to an aldehyde
A
Primary alcohol, and k2Cr2O7. (Oxidation)
7
Q
Aldehyde to hydroxy nitrile
A
Add NaCN/H+
8
Q
4 ways to a carboxylic acid
A
- Aldehyde (k2cr2o7)
- nitrile, H2O/HCL HYDROLYSIS
- dilute hydrolysis of ester
- H20 of acyl chloride
9
Q
Acyl chloride
A
SOCl2 to carboxylic acid
10
Q
Ester 2 ways
A
- primary alcohol / carboxylic acid (H2SO4)
- acyl chloride + alcohol