Summer HW Vocav Flashcards

1
Q

Reflux

A

A lab technique where you heat a chemical reaction mixture for a while. While heating, a condenser cools the vapor that forms, turning it back into liquid and returning it to the container. This method is useful in reactions like when you turn a primary alcohol into a carboxylic acid by oxidation

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2
Q

Distillation

A

This is a method used to separate two liquids that are mixed together. The liquids must have different boiling points. During this process, the mixture is heated. The liquid with the lower boiling point evaporates first. This gas is then cooled down so it turns back into a liquid and can be collected separately from the other liquid

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3
Q

Nucleon

A

particle found in the nucleus of an atom; both protons and neutrons are this

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4
Q

Isotope

A

a variation of an atom from the same element, where the only difference is the number of neutrons in the nucleus. All _____ of an element have the same number of protons but different neutron counts

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5
Q

Mass number

A

the total count of protons and neutrons found in the nucleus of an atom

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6
Q

Relative atomic mass

A

average weight of an element’s atoms compared to a tiny fraction of a carbon-12 atom’s mass

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7
Q

Atomic number

A

the number of protons in the nucleus of an atom

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8
Q

Fragmentation

A

the arrangement of pieces of a molecule that you see in the results from a mass spectrometer

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9
Q

Molecular ion

A

a positively charged ion produced in a mass spectrometer

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10
Q

Emission spectra

A

the specific wavelengths (or colors) of light that are emitted by atoms or molecules when their electrons move from a higher energy level to a lower energy level

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11
Q

Discrete

A

information that can only take certain specific values and not any value in between

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12
Q

Continuous

A

information that can take any value within a range and isn’t limited to specific points

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13
Q

Aufbau principle

A

a scientific principle that states that electrons will occupy the lowest energy levels of an atom before moving to higher ones

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14
Q

Hund’s rule

A

a scientific principle that states that electrons fill degenerate orbitals alone before doubling up

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15
Q

Pauli exclusion principle

A

a scientific principle that states that no two electrons can have exactly the same configuration. Each sub-level can hold two electrons with opposite spins

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16
Q

Heisenberg uncertainty principle

A

a scientific principle that states we cannot know both the exact location and speed of an electron at the same time

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17
Q

Ionization energy

A

the energy required to remove one mole of gaseous atoms to form one mole of gaseous 1+ ions

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18
Q

First ionization energy

A

the energy required to remove one mole of the most loosely held electrons from one mole of gaseous atoms in the ground state

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19
Q

Successive ionisation energies

A

the energies required to remove more and more electrons from an ion that is becoming increasingly positive

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20
Q

Line spectrum

A

the range of frequencies or wavelengths of electromagnetic radiation emitted during an electron transition from a higher to a lower energy level

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21
Q

Continuous spectrum

A

a spectrum that contains all the frequencies (or wavelengths) across a range of electromagnetic radiation.

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22
Q

Convergence limit

A

the point at which the spectral lines converge. Can be used to calculate the ionization energy

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23
Q

Planck’s constant

A

represented by the symbol h; helps scientists understand the relationship between energy and frequency for particles like photons

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24
Q

Molecular formula

A

a type of formula that shows the actual number of atoms of each element in a molecule. (eg. butene; C4H8)

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24
Empirical formula
the simplest whole number ratio of atoms of each element in a substance. (eg. butene; CH2)
24
Avogadro's constant
the number of particles in one mole of substance. Equal to 6.02 × 10^23
25
Standard solution
a solution of known concentration
26
Theoretical yield
the maximum amount of product that could be obtained from a chemical reaction, assuming all reactants are completely converted into products
27
Percent yield
tells us how much of a product we actually make compared to how much we expected to make
28
Limiting reagent/ reactant
the substance which is completely consumed in a chemical reaction and determines the yield of the product formed
29
Atom economy
tells us how efficiently a reaction uses the starting materials to make the desired products
30
Avogadro's law
equal volumes of gases at the same temperature and pressure will contain the same number of gas particles
31
Ideal gas
are assumed to consist of particles that have negligible volume and negligible attractive forces (PV=nRT)
32
Molar volume
tells us how much room a specific amount of gas needs when it's in its standard conditions
33
Ionic bond
electrostatic attraction between oppositely charged ions that holds the ions in close proximity
33
Electron affinity
the amount of energy released when a neutral atom gains an electron to form a negatively charged ion
34
Covalent bond
the electrostatic force of attraction between two positive nuclei and a shared pair of electrons
35
Bond strength
the amount of energy required to break a bond
36
Electronegativity
a measure of how much an atomic nucleus attracts the shared electrons that are involved in a covalent bond
37
Polarity
the separation of electric charge in a molecule or its chemical groups, resulting in a positive and negative end
38
Electron domain
the region in which bonding and non-bonding pairs of electrons are most likely to be found. Non-bonding pairs, single bonds, double bonds and triple bonds each count as one electron domain
39
VSEPR
Valence Shell Electron Pair Repulsion theory: A theory used to explain and predict molecular geometry, based on number of electron domains (bonded and non-bonded electron pairs)
40
Allotrope
alternative forms of an elemental substance. For example, diamond and graphite are allotropes of carbon
41
London dispersion force
the temporary instantaneous dipole formed due to the rapid and random motion of electrons
42
Induced dipole moment
a weak intermolecular force that occurs when a polar molecule gets close to an atom or non-polar molecule and induces a dipole by disrupting the arrangement of its electrons
43
Dipole-dipole interaction
a intermolecular force between two polar molecules that have permanent dipoles. Attractive forces exist between the positive end of one polar molecule and the negative end of another polar molecule
44
Hydrogen bonding
the intermolecular attraction between two molecules which both contain a hydrogen bonded to a highly electronegative element such as oxygen, fluorine or nitrogen
45
Delocalized electron
an electron that is not associated with one specific atom and is free to move within the molecular structure
46
Alloy
homogeneous mixtures of a metal and other metals or non-metals
47
Atomic radius
the distance from an atom's nucleus to the outermost orbital of one of its electrons. Usually measured as the half-distance between the nuclei of two of the same atoms bonded together
48
Ionic radius
the distance between the nucleus of an ion and the outermost shell of the ion
49
Isoelectronic
molecules with the same electron configuration
50
Oxidation state/number
a number assigned to an element showing the number of electrons lost or gained (or even shared) in a compound or ion
51
Homologous series
a series of organic compounds with the same functional group that differ by a common structural unit
52
Structural isomer
compounds with the same molecular formula but different structural arrangements
53
Skeletal formula
a type of formula that only shows the carbon skeleton (or backbone) of an organic compound
54
Functional group
group of atoms present on a molecule that give physical and chemical properties to a compound
55
Enthalpy
measurement of heat energy within a system. It is symbolised in expressions by H
56
Specific heat capacity
the quantity of heat needed to raise the temperature per unit mass
57
Standard enthalpy of reaction
the heat energy transferred within a reaction under standard conditions with all substances present in their standard states
58
Average bond enthalpy
the enthalpy change when one mole of bonds are broken in the gaseous state averaged for the same bond in similar compounds
59
Hess's law
law that states that the total enthalpy change in a chemical reaction is independent of the route by which the chemical reaction takes place, as long as the initial and final conditions are the same
60
Equilibrium constant
ratio between the concentration of products and reactants for a reversible reaction at equilibrium
61
Collision theory
an explanation of how reactions take place, which states that for reactions to happen the particles must collide with a minimum amount of energy and the collisions must have the correct collision geometry
62
Catalyst
a substance that changes the rate of a reaction and is not used up. Although it speeds up a reaction, the catalyst itself is not changed by the reaction. Negative catalysts also exist - substances that slow down the rate of a reaction
63
Dynamic equilibrium
a state in chemistry that occurs when a reversible reaction happens in a closed container at the same rate in both directions. This means that the reactants and products are constantly transitioning between each other at equal rates, resulting in no net change and no observable change in the system's properties
64
Le Chatelier's Principle
a principle used to predict in which direction the equilibrium position will shift when changes are made to a reaction at equilibrium
65
Equilibrium law
the principle that (at chemical equilibrium) in a reversible reaction the ratio of the rate of the forward reaction to the rate of the reverse reaction is a constant for that reaction